Limiting Electroconductivity and Structure of Molten Chlorides of Alkaline-Earth Metals
Tóm tắt
It is established experimentally that the electroconductivity of individual molten chlorides of calcium, strontium, and barium increases with the electric field strength and reaches limiting values, which are dependent on the salt nature and the temperature. The limiting electroconductivity of molten calcium and strontium chlorides satisfactorily obeys the Nernst–Einstein relationship. The relaxation kinetics of excess conductivity induced by high-voltage pulsed discharges is studied. The relaxation time is equal to about 104 s.
Tài liệu tham khảo
Shabanov, O.M., Rasplavy, 1987, no. 5, p. 66.
Gadzhiev, S.M. and Prisyazhnyi, V.D., Ionnye rasplavy i tverdye elektrolity (Ionic Melts and Solid Electrolytes), Kiev: Naukova Dumka, 1986, p. 21.
Smirnov, M.V., Shabanov, O.M., and Khaimenov, A.P., Elektrokhimiya, 1966, vol. 2, p. 1240.
Smirnov, M.V. and Shabanov, O.M., Tr. Inst. Elektrokhim. Ural. Otd. Akad. Nauk SSSR, 1966, no. 8, p. 55.
Kirillov, S.A., Fiz. Khim. Elektrokhim. Rasplavl. Solei Shlakov, 2001, vol. 1, p. 31.
Shabanov, O.M., Gadzhiev, S.M., and Tagirov, S.M., Elektrokhimiya, 1973, vol. 9, p. 1828.
Gadzhiev, S.M., Shabanov, O.M., Omarov, O.A., Gadzhiev, A.S., and Magomedova, A.O., Rasplavy, 2002, no. 1, p. 34.
Kornyakova, I.D., Rasplavy, 1991, no. 1, p. 90.
Kornyakova, I.D., Khaimenov, A.P., Matlashevskii, V.A., and Kochedykov, V.A., Rasplavy, 1991, no. 4, p. 37.
Smirnov, M.V., Elektrodnye potentsialy v rasplavlennykh khloridakh (Electrode Potentials in Molten Chlorides), Moscow: Nauka, 1973.
Enderby, J.E. and Beggin, S., Adv. Molt. Salts Chem., 1983, no. 5, p. 1.
Trifonov, I.I., Rasplavy, 1993, no. 2, p. 47.
Spedding, P.L., Rev. Pure Appl. Chem., 1971, vol. 21, p. 1.
Shabanov, O.M. and Gadzhiev, S.M., Rasplavy, 1990, no. 2, p. 49.