Lattice distortion tuning of the metamagnetic phase transition in tetragonal Cu2Sb-type Mn1.95V0.05Sb alloy
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More V substitution in Mn2Sb alloy leads to increased AFM-FIM transition temperature but reduced maximum of magnetic entropy changes, which are referred from Suppl. Fig. 1 and Fig. 2. Therefore, Mn1.95V0.05Sb with minimum V substitution amount has been used as benchmark alloy.
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If Mn sites in Cu2Sb-type Mn2Sb lattice are occupied by Li, the metamagnetic transition from FIM to AFM during cooling process is suppressed, as seen in Suppl. Fig. 3.