Laboratory studies of the HNCO molecular spectrum for precise spectroscopy of dark clouds

A. V. Lapinov1, G. Yu. Golubiatnikov1, V. N. Markov1, A. Guarnieri2
1Institute of Applied Physics, Russian Academy of Sciences, Nizhni Novgorod, Russia
2Technical Faculty, Christian-Albrechts University, Kiel, Germany

Tóm tắt

Detailed studies of the internal motions of dark clouds using spectral lines of many molecules require a laboratory frequency accuracy of the order of a few m s−1. Based on our laboratory studies of the HNCO rotational spectrum in the ground vibrational state, we have increased significantly the accuracy of frequency calculation in a wide range of quantum numbers. We have achieved an (1σ) uncertainty for rotational transitions in the K a = 0, 1 states recalculated to the Doppler velocity scale ≤2 m s−1 for all frequencies <1.1 THz. This value allows radio-astronomical measurements with an accuracy comparable to that of the highest-precision observations based on spectral lines of other molecules.

Từ khóa


Tài liệu tham khảo

G. Cazzoli, C. Puzzarini, and A. V. Lapinov, Astrophys. J. 592, L95 (2003).

G. Cazzoli, C. Puzzarini, and A. V. Lapinov, Astrophys. J. 611, 615 (2004).

E. Churchwell, D. Wood, P. C. Myers, and R. V. Myers, Astrophys. J. 305, 405 (1986).

L. Fusina, M. Carlotti, and B. Carli, Can. J. Phys. 62, 1452 (1984).

G. Yu. Golubiatnikov and A. F. Krupnov, J. Mol. Spectrosc. 217, 190 (2003).

G. Yu. Golubiatnikov, A. V. Lapinov, A. Guarnieri, and R. Knöchel, J. Mol. Spectrosc. 234, 190 (2005).

S. Green, NASA Technical Memorandum, NASA TM 87 791 (1986); http://data.giss.nasa.gov/mcrates/.

W. H. Hocking, M. C. L. Gerry, and G. Winnewisser, Astrophys. J. 187, L89 (1974).

W. H. Hocking, M. C. L. Gerry, and G. Winnewisser, Can. J. Phys. 53, 1869 (1975).

R. Kewley, K. V. L. N. Sastry, and M. Winnewisser, J. Mol. Spectrosc. 10, 418 (1963).

S. G. Kukolich, A. C. Nelson, and B. S. Yamanashi, J. Am. Chem. Soc. 93, 6769 (1971).

A. V. Lapinov, P. Schilke, M. Juvela, and I. I. Zinchenko, Astron. Astrophys. 336, 1007 (1998).

F. J. Lovas, J. Phys. Chem. Ref. Data 33, 177 (2004).

M. Niedenhoff, K. M. T. Yamada, S. P. Belov, and G. Winnewisser, J. Mol. Spectrosc. 174, 151 (1995).

M. Niedenhoff, K. M. T. Yamada, and G. Winnewisser, J. Mol. Spectrosc. 176, 342 (1996).

H. M. Pickett, R. L. Pointer, E. A. Cohen, et al., J. Quantum Spectrosc. & Radiat. Transfer. 60, 883 (1998).

J. N. Shoolery and A. H. Sharbaugh, Phys. Rev. 82, 95 (1951).

J. N. Shoolery, R. G. Shulman, and D. M. Yost, J. Chem. Phys. 19, 250 (1951).

M. Wang, C. Henkel, Y.-N. Chin, et al., Astron. Astrophys. 422, 883 (2004).

J. K. G. Watson, Vibrational Spectra and Structures, Ed. by J. R. Durig (Elsevier, Amsterdam, 1977), vol. 6, p. 2.

K. J. White and R. L. Cook, J. Chem. Phys. 46, 143 (1967).

G. Winnewisser, S. P. Belov, Th. Klaus, and R. Schieder, J. Mol. Spectrosc. 184, 468 (1997).

G. Winnewisser, W. H. Hocking, and M. C. L. Gerry, J. Phys. Chem. Ref. Data 5, 79 (1976).

K. Yamada, J. Mol. Spectrosc. 79, 323 (1980).

I. Zinchenko, C. Henkel, and R. Q. Mao, Astron. Astrophys. 361, 1079 (2000).