Kinetics determination of fast exothermic reactions with infrared thermography in a microreactor
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Zhang J, Wang K, Lin X, Lu Y, Luo G (2014) Intensification of fast exothermic reaction by gas agitation in a microchemical system. AICHE J 60(7):2724–2730
Gemoets HP, Su Y, Shang M, Hessel V, Luque R, Noel T (2016) Liquid phase oxidation chemistry in continuous-flow microreactors. Chem Soc Rev 45(1):83–117. https://doi.org/10.1039/c5cs00447k
Zhou F, Zhang B, Yao C, Zhu K, Yang M, Chen G (2016) Cyclization of pseudoionone catalyzed by sulfuric acid in a microreactor. Chem Eng Technol 39(5):849–856. https://doi.org/10.1002/ceat.201500670
Knapkiewicz P, Skowerski K, Jaskólska DE, Barbasiewicz M, Olszewski TK (2012) Nitration under continuous flow conditions: convenient synthesis of 2-isopropoxy-5-nitrobenzaldehyde, an important building block in the preparation of nitro-substituted Hoveyda–Grubbs metathesis catalyst. Org Process Res Dev 16(8):1430–1435. https://doi.org/10.1021/op300116j
Zhang C, Zhang J, Luo G (2016) Kinetic study and intensification of acetyl guaiacol nitration with nitric acid—acetic acid system in a microreactor. J Flow Chem 6(4):309-314. https://doi.org/10.1556/1846.2016.00011
Wang K, Lu YC, Xia Y, Shao HW, Luo GS (2011) Kinetics research on fast exothermic reaction between cyclohexanecarboxylic acid and oleum in microreactor. Chem Eng J 169(1–3):290–298. https://doi.org/10.1016/j.cej.2011.02.072
Schneider MA, Stoessel F (2005) Determination of the kinetic parameters of fast exothermal reactions using a novel microreactor-based calorimeter. Chem Eng J 115(1–2):73–83. https://doi.org/10.1016/j.cej.2005.09.019
Zogg A, Stoessel F, Fischer U, Hungerbühler K (2004) Isothermal reaction calorimetry as a tool for kinetic analysis. Thermochim Acta 419(1–2):1–17. https://doi.org/10.1016/j.tca.2004.01.015
Glotz G, Knoechel DJ, Podmore P, Gruber-Woelfler H, Kappe CO (2017) Reaction calorimetry in microreactor environments—measuring heat of reaction by isothermal heat flux calorimetry. Org Process Res Dev 21(5):763–770. https://doi.org/10.1021/acs.oprd.7b00092
Andreozzi R, Caprio V, Di Somma I, Sanchirico R (2006) Kinetic and safety assessment for salicylic acid nitration by nitric acid/acetic acid system. J Hazard Mater 134(1–3):1–7. https://doi.org/10.1016/j.jhazmat.2005.10.037
McMullen JP, Jensen KF (2011) Rapid determination of reaction kinetics with an automated microfluidic system. Org Process Res Dev 15(2):398–407. https://doi.org/10.1021/op100300p
Reichmann F, Millhoff S, Jirmann Y, Kockmann N (2017) Reaction calorimetry for exothermic reactions in plate-type microreactors using seebeck elements. Chem Eng Technol 40(11):2144–2154. https://doi.org/10.1002/ceat.201700419
Gomez MV, Rodriguez AM, de la Hoz A, Jimenez-Marquez F, Fratila RM, Barneveld PA, Velders AH (2015) Determination of kinetic parameters within a single nonisothermal on-flow experiment by nanoliter NMR spectroscopy. Anal Chem 87(20):10547–10555. https://doi.org/10.1021/acs.analchem.5b02811
Sans V, Cronin L (2016) Towards dial-a-molecule by integrating continuous flow, analytics and self-optimisation. Chem Soc Rev 45(8):2032–2043. https://doi.org/10.1039/c5cs00793c
Halder R, Lawal A, Damavarapu R (2007) Nitration of toluene in a microreactor. Catal Today 125(1–2):74–80. https://doi.org/10.1016/j.cattod.2007.04.002
Zhang J, Burklé-Vitzthum V, Marquaire PM (2012) NO2-promoted oxidation of methane to formaldehyde at very short residence time – part II: kinetic modeling. Chem Eng J 197:123–134. https://doi.org/10.1016/j.cej.2012.05.013
Keybl J, Jensen KF (2011) Microreactor system for high-pressure continuous flow homogeneous catalysis measurements. Ind Eng Chem Res 50(19):11013–11022. https://doi.org/10.1021/ie200936b
Buffone C, Sefiane K (2004) IR measurements of interfacial temperature during phase change in a confined environment. Exp Thermal Fluid Sci 29(1):65–74. https://doi.org/10.1016/j.expthermflusci.2004.02.004
Hetsroni G, Mosyak A, Pogrebnyak E, Rozenblit R (2011) Infrared temperature measurements in micro-channels and micro-fluid systems. Int J Therm Sci 50(6):853–868. https://doi.org/10.1016/j.ijthermalsci.2011.01.006
Ravey C, Pradere C, Regnier N, Batsale J-C (2012) New temperature field processing from IR camera for velocity, thermal diffusivity and calorimetric non-intrusive measurements in microfluidics systems. Quant InfraRed Thermogr J 9(1):79–98. https://doi.org/10.1080/17686733.2012.682878
Haber J, Kashid MN, Borhani N, Thome J, Krtschil U, Renken A, Kiwi-Minsker L (2013) Infrared imaging of temperature profiles in microreactors for fast and exothermic reactions. Chem Eng J 214:97–105. https://doi.org/10.1016/j.cej.2012.10.021
Ravey C, Pradere C, Regnier N, Batsale JC (2015) Study of phase change and Supercooling in micro-channels by infrared thermography. Exp Heat Transfer 29(2):266–283. https://doi.org/10.1080/08916152.2014.973980
Zhang J, Zhang C, Liu G, Luo G (2016) Measuring enthalpy of fast exothermal reaction with infrared thermography in a microreactor. Chem Eng J 295:384–390
Ashauer M, Ende J, Glosch H, Haffner H, Hiltmann K (1997) Thermal characterization of microsystems by means of high-resolution thermography. Microelectron J 28(3):327–335. https://doi.org/10.1016/s0026-2692(96)00036-5
Zhang J, Wang K, Lu Y, Luo G (2010) Characterization and modeling of micromixing performance in micropore dispersion reactors. Chem Eng Process Process Intensif 49(7):740–747
Johnson RE, Biltonen RL (1975) Determination of reaction rate parameters by flow microcalorimetry. J Am Chem Soc 97(9):2349–2355. https://doi.org/10.1021/ja00842a007
Roux A, Perron G, Picker P, Desnoyers JE (1980) Enthalpies of reaction and reaction rates by flow microcalorimetry: Ester hydrolysis in basic medium. J Solut Chem 9(1):59–73. https://doi.org/10.1007/bf00650137
Bamford CH, Tipper CFH (1972) Comprehensive chemical kinetics. Elsevier, Amsterdam