Kinetics and mechanism of the decomposition of cumyl hydroperoxide in the presence of 2-mercaptobenzimidazole
Tóm tắt
2-Mercaptobenzimidazole reacts with cumyl hydroperoxide to give radicals. This accounts for the initiating effect of this compound in the autoxidation of isopropylbenzene and ethylbenzene. On the other hand, 2-mercaptobenzimidazole is a weak inhibitor in the low-temperature initiated oxidation of alkylbenzenes.
Tài liệu tham khảo
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