Kinetic modelling and techno-economic analysis of biodiesel production from Calophyllum inophyllum oil
Tóm tắt
Calophyllum inophyllum oil, a non-edible renewable resource, was used for the production of biodiesel. In the present study, kinetic analysis was done for the biodiesel production from C. inophyllum oil using alkali and enzymatic method, a non-edible renewable resource with methanol to identify the rate equation and estimate model kinetic parameters. The present model was validated, and the experimental and predicted values were compared. The first-order rate equation represents an alkali transesterification reaction’s kinetic mathematical model under chosen experimental conditions for the estimated parameters. The enzymatic transesterification was carried out at 500 rpm for 8 h in room temperature produced a yield of 97% of FAME (fatty acid methyl ester) for the reaction with 6:1 methanol to oil in molar ratio. The sequential cleavage of fatty acid and reaction with methanol by the enzyme were assumptions used in developing the kinetic model. The transesterification of C. inophyllum oil was simulated with Aspen Plus (V 8.6, Aspen Tech., Inc.). The simulation and economically viable estimation for the comparison of a ceaseless biodiesel production from C. inophyllum oil are formed on the basis of the kinetics of chemical transesterification (base-catalyzed methanolysis) and enzymatic transesterification reactions. The base-catalyzed transesterification requires nearly seven times higher than the enzymatic transesterification Also, the simulation demonstrated that the base-catalyzed transesterification required additional number of process equipment units when related to the enzymatic process.
Tài liệu tham khảo
Huang R, Cheng J, Qiu Y, Li T, Zhou J, Cen K (2015) Using renewable ethanol and isopropanol for lipid transesterification in wet microalgae cells to produce biodiesel with low crystallization temperature. Energy Convers Manag 105:791–797. https://doi.org/10.1016/j.enconman.2015.08.036
Atabani AE, Silitonga AS, Badruddin IA, Mahlia TMI, Masjuki HH, Mekhilef S (2012) A comprehensive review on biodiesel as an alternative energy resource and its characteristics. Renew Sust Energ Rev 16:2070–2093. https://doi.org/10.1016/j.rser.2012.01.003
Sureshkumar K, Velraj R, Ganesan R (2008) Performance and exhaust emission characteristics of a CI engine fueled with Pongamia pinnata methyl ester (PPME) and its blends with diesel. Renew Energy 33:2294–2302. https://doi.org/10.1016/j.renene.2008.01.011
Tacias-Pascacio VG, Virgen-Ortãz JJ, Jiménez-Pérez M et al (2017) Evaluation of different lipase biocatalysts in the production of biodiesel from used cooking oil: critical role of the immobilization support. Fuel 200:1–10. https://doi.org/10.1016/j.fuel.2017.03.054
Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, Chong WT (2013) Characterization and production of Ceiba pentandra biodiesel and its blends. Fuel 108:855–858. https://doi.org/10.1016/j.fuel.2013.02.014
Ozcanli M, Gungor C, Aydin K (2013) Biodiesel fuel specifications: a review. Energ Source Part A 35:635–647. https://doi.org/10.1080/15567036.2010.503229
Arumugam A, Ponnusami V (2014) Biodiesel production from Calophyllum inophyllum oil using lipase producing Rhizopus oryzae cells immobilized within reticulated foams. Renew Energy 64:276–282. https://doi.org/10.1016/j.renene.2013.11.016
Labib TM, Hawash SI, El-Khatib KM et al (2013) Kinetic study and techno-economic indicators for base catalyzed transesterification of Jatropha oil. Egypt J Pet 22:9–16. https://doi.org/10.1016/j.ejpe.2012.06.001
Lisboa P, Rodrigues AR, Martín JL, Simões P, Barreiros S, Paiva A (2014) Economic analysis of a plant for biodiesel production from waste cooking oil via enzymatic transesterification using supercritical carbon dioxide. J Supercrit Fluids 85:31–40. https://doi.org/10.1016/j.supflu.2013.10.018
Kuo C-H, Chen G-J, Chen C-I, Liu YC, Shieh CJ (2014) Kinetics and optimization of lipase-catalyzed synthesis of rose fragrance 2-phenylethyl acetate through transesterification. Process Biochem 49:437–444. https://doi.org/10.1016/j.procbio.2013.12.012
Ren H, Li Y, Du W, Liu D (2012) Free lipase-catalyzed esterification of oleic acid for fatty acid ethyl ester preparation with response surface optimization. J Am Oil Chem Soc 90:73–79. https://doi.org/10.1007/s11746-012-2146-3
Serrano M, Marchetti J-M, Martínez M, Aracil J (2015) Biodiesel production from waste salmon oil: kinetic modeling, properties of methyl esters, and economic feasibility of a low capacity plant. Biofuels Bioprod Biorefin 9:516–528. https://doi.org/10.1002/bbb.1561
Rodriguez-Perez S, Serrano A, Pantión AA, Alonso-Fariñas B (2018) Challenges of scaling-up PHA production from waste streams. A review. J Environ Manag 205:215–230. https://doi.org/10.1016/j.jenvman.2017.09.083
Cheirsilp B, H-Kittikun A, Limkatanyu S (2008) Impact of transesterification mechanisms on the kinetic modeling of biodiesel production by immobilized lipase. Biochem Eng J 42:261–269. https://doi.org/10.1016/j.bej.2008.07.006
Arumugam A, Thulasidharan D, Jegadeesan GB (2018) Process optimization of biodiesel production from Hevea brasiliensis oil using lipase immobilized on spherical silica aerogel. Renew Energy 116:755–761. https://doi.org/10.1016/j.renene.2017.10.021
Arumugam A, Ponnusami V (2013) Synthesis of SBA-15 from low cost silica precursor obtained from sugarcane leaf ash and its application as a support matrix for lipase in biodiesel production. J Sol-Gel Sci Technol 67:244–250. https://doi.org/10.1007/s10971-013-3070-1
Li Z, Deng L, Lu J, Guo X, Yang Z, Tan T (2010) Enzymatic synthesis of fatty acid methyl esters from crude rice bran oil with immobilized Candida sp. 99–125. Chin J Chem Eng 18:870–875. https://doi.org/10.1016/S1004-9541(09)60141-5
Jain S, Sharma MP (2010) Kinetics of acid base catalyzed transesterification of Jatropha curcas oil. Bioresour Technol 101:7701–7706. https://doi.org/10.1016/j.biortech.2010.05.034
Farhat W, Venditti R, Quick A, Taha M, Mignard N, Becquart F, Ayoub A (2017) Hemicellulose extraction and characterization for applications in paper coatings and adhesives. Ind Crop Prod 107:370–377. https://doi.org/10.1016/j.indcrop.2017.05.055
Khamis FS (2013) Use of fatty acid methyl esters as biocomponents for diesel fuels and for preparation of cetane number improvers. Am J Chem Eng 1:65. https://doi.org/10.11648/j.ajche.20130104.11
Pires-Cabral P, da Fonseca MMR, Ferreira-Dias S (2009) Synthesis of ethyl butyrate in organic media catalyzed by Candida rugosa lipase immobilized in polyurethane foams: a kinetic study. Biochem Eng J 43:327–332. https://doi.org/10.1016/j.bej.2008.11.002
Barboza M, Hokka CO, Maugeri F (2002) Continuous cephalosporin C purification: dynamic modelling and parameter validation. Bioprocess Biosyst Eng 25:193–203. https://doi.org/10.1007/s00449-002-0294-9
Keng PS, Basri M, Ariff AB et al (2008) Scale-up synthesis of lipase-catalyzed palm esters in stirred-tank reactor. Bioresour Technol 99:6097–6104. https://doi.org/10.1016/j.biortech.2007.12.049
Sun S, Chen X (2015) Kinetics of enzymatic synthesis of monoferuloyl glycerol and diferuloyl glycerol by transesterification in [BMIM]PF6. Biochem Eng J 97:25–31. https://doi.org/10.1016/j.bej.2015.02.002
Tiwari A, Rajesh VM, Yadav S (2018) Biodiesel production in micro-reactors: a review. Energy Sustain Dev 43:143–161. https://doi.org/10.1016/j.esd.2018.01.002
Verma P, Sharma MP (2016) Comparative analysis of effect of methanol and ethanol on Karanja biodiesel production and its optimisation. Fuel 180:164–174. https://doi.org/10.1016/j.fuel.2016.04.035
Jain S, Sharma MP, Rajvanshi S (2011) Acid base catalyzed transesterification kinetics of waste cooking oil. Fuel Process Technol 92:32–38. https://doi.org/10.1016/j.fuproc.2010.08.017
Kumar R, Tiwari P, Garg S (2013) Alkali transesterification of linseed oil for biodiesel production. Fuel 104:553–560. https://doi.org/10.1016/j.fuel.2012.05.002
Schfflan R (2011) Teach yourself the basics of Aspen plus. Wiley, Hooboeken
Bhoi PR, Huhnke RL, Whiteley JR, Gebreyohannes S, Kumar A (2015) Equilibrium stage based model of a vegetable oil based wet packed bed scrubbing system for removing producer gas tar compounds. Sep Purif Technol 142:196–202. https://doi.org/10.1016/j.seppur.2014.12.044
Simasatitkul L, Arpornwichanop A (2017) Economic evaluation of biodiesel production from palm fatty acid distillate using a reactive distillation. Energy Procedia 105:237–243. https://doi.org/10.1016/j.egypro.2017.03.308
Poddar T, Jagannath A, Almansoori A (2017) Use of reactive distillation in biodiesel production: a simulation-based comparison of energy requirements and profitability indicators. Appl Energy 185:985–997. https://doi.org/10.1016/j.apenergy.2015.12.054
Gutiérrez Ortiz FJ, de Santa-Ana P (2017) Techno-economic assessment of an energy self-sufficient process to produce biodiesel under supercritical conditions. J Supercrit Fluids 128:349–358. https://doi.org/10.1016/j.supflu.2017.03.010
Sajid Z, Zhang Y, Khan F (2016) Process design and probabilistic economic risk analysis of bio-diesel production. Sustain Prod Consum 5:1–15. https://doi.org/10.1016/j.spc.2015.10.003
Song C, Chen G, Ji N, Liu Q, Kansha Y, Tsutsumi A (2015) Biodiesel production process from microalgae oil by waste heat recovery and process integration. Bioresour Technol 193:192–199. https://doi.org/10.1016/j.biortech.2015.06.116
Poddar T, Jagannath A, Almansoori A (2015) Biodiesel production using reactive distillation: a comparative simulation study. Energy Procedia 75:17–22. https://doi.org/10.1016/j.egypro.2015.07.129
Karmee SK, Patria RD, Lin CSK (2015) Techno-economic evaluation of biodiesel production from waste cooking oil—a case study of Hong Kong. Int J Mol Sci 16:4362–4371. https://doi.org/10.3390/ijms16034362
Rincón LE, Jaramillo JJ, Cardona CA (2014) Comparison of feedstocks and technologies for biodiesel production: an environmental and techno-economic evaluation. Renew Energy 69:479–487. https://doi.org/10.1016/j.renene.2014.03.058
Tasić MB, Stamenković OS, Veljković VB (2014) Cost analysis of simulated base-catalyzed biodiesel production processes. Energy Convers Manag 84:405–413. https://doi.org/10.1016/j.enconman.2014.04.044
Yusuf NNAN, Kamarudin SK (2013) Techno-economic analysis of biodiesel production from Jatropha curcas via a supercritical methanol process. Energy Convers Manag 75:710–717. https://doi.org/10.1016/j.enconman.2013.08.017
Chesterfield D, Rogers PL, Al-Zaini E, Adesina AA (2013) Steady-state simulation of a novel extractive reactor for enzymatic biodiesel production. Fuel Process Technol 108:101–111. https://doi.org/10.1016/j.fuproc.2012.05.004
Yun H, Wang M, Feng W, Tan T (2013) Process simulation and energy optimization of the enzyme-catalyzed biodiesel production. Energy 54:84–96. https://doi.org/10.1016/j.energy.2013.01.002
Cho HJ, Kim J-K, Cho H-J, Yeo Y-K (2012) Techno-economic study of a biodiesel production from palm fatty acid distillate. Ind Eng Chem Res:121227123655001. https://doi.org/10.1021/ie301651b
Al-Zuhair S, Almenhali A, Hamad I et al (2011) Enzymatic production of biodiesel from used/waste vegetable oils: design of a pilot plant. Renew Energy 36:2605–2614. https://doi.org/10.1016/j.renene.2010.05.010
Sotoft LF, Rong BG, Christensen KV, Norddahl B (2010) Process simulation and economical evaluation of enzymatic biodiesel production plant. Bioresour Technol 101:5266–5274. https://doi.org/10.1016/j.biortech.2010.01.130
Ye J, Tu S, Sha Y (2010) Investigation to biodiesel production by the two-step homogeneous base-catalyzed transesterification. Bioresour Technol 101:7368–7374. https://doi.org/10.1016/j.biortech.2010.03.148
Apostolakou AA, Kookos IK, Marazioti C, Angelopoulos KC (2009) Techno-economic analysis of a biodiesel production process from vegetable oils. Fuel Process Technol 90:1023–1031. https://doi.org/10.1016/j.fuproc.2009.04.017
West AH, Posarac D, Ellis N (2008) Assessment of four biodiesel production processes using HYSYS. Plant Bioresour Technol 99:6587–6601. https://doi.org/10.1016/j.biortech.2007.11.046
Haas MJ, McAloon AJ, Yee WC, Foglia TA (2006) A process model to estimate biodiesel production costs. Bioresour Technol 97:671–678. https://doi.org/10.1016/j.biortech.2005.03.039
Sakai T, Kawashima A, Koshikawa T (2009) Economic assessment of batch biodiesel production processes using homogeneous and heterogeneous alkali catalysts. Bioresour Technol 100:3268–3276. https://doi.org/10.1016/j.biortech.2009.02.010
Zhang Y, Dubé MA, McLean DD, Kates M (2003) Biodiesel production from waste cooking oil: 1. Process design and technological assessment. Bioresour Technol 89:1–16. https://doi.org/10.1016/S0960-8524(03)00040-3