K5[PW11ZnO39].23H2O-catalyzed acylation/ring expansion of ketoaziridines in a single pot: a new regio- and stereo-selective route for the synthesis of oxazolines

Springer Science and Business Media LLC - Tập 12 - Trang 2031-2035 - 2015
Heshmat A. Samimi1, Akram Mostafavi1, Mostafa Riahi Farsani2
1Department of Chemistry, Faculty of Sciences, The University of Shahrekord, Shahrekord, Iran
2Young Researchers and Elite Club, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran

Tóm tắt

A new and one-pot synthesis of oxazolines has been accomplished by K5[PW11ZnO39].23H2O—catalyst acylation followed by C–N ring opening/C–O bond formation in NH ketoaziridines. This regio- and stereo-selective reaction presumably proceeds via a domino sequence resulting in the in situ generation of acyl aziridine which undergoes a ring expansion reaction via an initial C–N rupture of aziridine ring followed by ring closure to the oxazolines. The methodology provided novel one-pot procedure for the synthesis of trans-2,5-diaryl-4-aroyloxazolines.

Tài liệu tham khảo

Y. Hou, L. Xu, M.J. Cichon, S. Lense, K.I. Hardcastle, C.L. Hill, inorg. Chem 4, 4125 (2010) J. Niu, F. Li, J. Zhao, P. Ma, D. Zhang, B. Bassil, U. Kortz, J. Wang, Chem. Eur. J. 20, 9852 (2014) M.R. Farsani, B. Yadollahi, J. Mol. Catal. A: Chem. 392, 8 (2014) F. Jalilian, B. Yadollahi, M.R. Farsani, S. Tangestaninejad, H.A. Rudbari, R. Habibi, Catal. Commun. 66, 107 (2015) R. Andreasch, Monatsh. Chem. 5, 33 (1664) B.F. Bonini, E. Capito, M. Franchini, M. Fochi, A. Ricci, B. Zwanenburg, Tetrahedron Asymmetry 17, 3135 (2006) X. Zhang, W. Lin, L. Gong, A. Mi, X. Cui, Y. Jiang, M.C.K. Choi, A.S.C. Chan, Tetrahedron Lett. 43, 1535 (2002) Z. Chai, X.Y. Liu, X.Y. Wu, G. Zhao, Tetrahedron Asymmetry 17, 2442 (2006) J.I. Garcia, J.A. Mayoral, E. Pires, I. Villalba, Tetrahedron Asymmetry 17, 2270 (2006) H.A. McManus, P.I. Guiry, Chem. Rev. 104, 4151 (2004) S.F. Lu, D.M. Du, S.W. Zhang, J. Xu, Tetrahedron Asymmetry 15, 3433 (2004) D.A. Evans, T. Rovis, M.C. Kozlowski, C.W. Downey, J.S. Tedrow, J. Am. Chem. Soc. 122, 9134 (2000) P. Kisanga, P. Ilankumaran, J.G. Verkade, Tetrahedron Lett. 42, 6263 (2001) G. Cardillo, L. Gentilucci, M. Gianotti, A. Tolomelli, Eur. J. Org. Chem. 2489(2000) (references cited therein) J.S. Panek, C.E. Masse, Angew. Chem. Int. Ed. 38, 1093 (1999) G. Cardillo, L. Gentilucci, M. Gianotti, Tolomelli A. Tetrahedron Asymmetry 1, 563 (2001) B.S. Davidson, Chem. Rev. 93, 1771 (1993) P. Wipf, P.C. Fritch, S.J. Geib, A.M. Selfer, J. Am. Chem. Soc. 120, 4105 (1998) H.A. McManus, P.I. Guiry, Chem. Rev. 104, 4151 (2004) S.-F. Lu, D.-M. Du, S.-W. Zhang, J. Xu, Tetrahedron Asymmetry 15, 3433 (2004) A. Cwik, Z. Hell, A. Hegedus, Z. Finta, Z. Horvath, Tetrahedron Lett. 43, 3985 (2002) T.G. Gant, A.I. Meyers, Tetrahedron 50, 2297 (1994) (references cited therein) F.N. Gladysheva, A.P. Sineokov, V.S. Etlis, Rus. Chem. Rev 39, 118 (1970) W. McCoull, F.A. Davis, Synthesis 10, 1347 (2000) G. Cardillo, L. Gentiluccu, A. Tolomelli, C.T. Tomasini, Tetrahedron Lett. 38, 6953 (1997) G. Cardillo, L. Gentilucci, A. Tolomelli, Chem. Commun. 167 (1999) G. Cardillo, L. Gentilucci, A. Tolomelli, Tetrahedron 55, 15151 (1999) F.W. Eastwood, P. Perlmutter, Q.J. Yang, Chem. Soc., Perkin. Trans. 1, 35 (1997) F.W. Eastwood, P. Perlmutter, Q. Yang, Tetrahedron Lett. 35, 2039 (1994) J. Legters, J.G.H. Willems, L. Thijs, B. Zwanenburg, Recl. Trav. Chim. Pay-Bas 111, 59 (1992) J. Legters, E. van Dienst, L. Thijs, B. Zwanenburg, Recl. Trav. Chim. Pay-Bas 111, 69 (1992) B. Olofsson, U. Khamrai, P. Somfai, Org. Lett. 2, 4087 (2000) W. McCoull, F.A. Davis, Synthesis 1347 (2000) G. Cardillo, L. Gentilucci, G. PericotMohr, Eur. J. Org. Chem. 3545 (2001) Z. Kainan, C.R. Pramod, L. Janis, Tetrahedron Lett. 49, 4306 (2008) G. Cardillo, L. Gentilucci, A. Tolomelli, Aldrichim Acta 36, 39 (2003) B. Zwanenburg, L. Thijs, Pure Appl. Chem. 68, 735 (1996) F.W. Eastwood, P. Perlmutter, Q. Yang, J. Chem. Soc., Perkin Trans. 1, 35 (1997) B. Kang, A.W. Miller, S. Goyal, S.T. Nguyen, Chem. Commun, 3928 (2009) H.A. Samimi, M. Mamaghani, K. Tabatabaeian, J. Heterocycl. Chem. 45, 1765 (2008) M. Mamaghani, K. Tabatabaeian, H.A. Samimi, Z. Kristallogr, New Cryst. Struct. 223, 390 (2008) H.A. Samimi, Z. Shams, J. Iran. Chem. Soc. 11, 979 (2014) H.A. Samimi, S. Mohammadi, Synlett 24, 223 (2013) H.A. Samimi, S. Mohammadi, J. Iran. Chem. Soc. 11, 69 (2014) H.A. Samimi, H. Kiyani, Z. Shams, J. Chem. Res. 37, 282 (2013) H.A. Samimi, B.M.J. Yamin, J. Chem. Res. 38, 358 (2014) H.A. Samimi, M.Y. Bohari, F. Saberi, Synthesis 47, 129 (2014) M.R. Farsani, F. Jalilian, B. Yadollahi, H. Amiri, Rudbari. Appl. Organomet. Chem. 29, 7 (2015) S. Gabriel, Chem. Ber. 21, 1049 (1888) B.J.S. Johnson, A. Stein, Inorg. Chem. 40, 801 (2001) M.R. Farsani, B. Yadollahi, H. Amiri Rudbari, A. Amini, T. Caradoc-Davis, J.R. Price, Inorg. Chem. Commun. 43, 39 (2014) M.R. Farsani, E. Assady, F. Jalilian, B. Yadollahi, H. Amiri Rudbari, J. Iran Chem. Soc. 12, 1207 (2015) H. Danafar, B. Yadollahi, Catal. Commun. 10, 842 (2009)