Ir(III)‐Catalyzed C7‐Position‐Selective Oxidative CH Alkenylation of Indolines with Alkenes in Air

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For Ru‐catalyzed carbonylation and Pd‐catalyzed arylation and methylation of the CH bond at the C7‐position of indoline see:

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Under the standard reaction conditions the desired product3 mwas obtained in 10 % yield along with the recovery of substrate.

p‐Methoxystyrene was very reactive under the present reaction conditions and was completely consumed in the absence of indoline1 a.

Non‐1‐ene cyclohexene allylbenzene vinyl acetate andn‐butyl vinyl ether were inappropriate alkenes under the present reaction conditions.