Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride

Chemistry - A European Journal - Tập 14 Số 27 - Trang 8177-8182 - 2008
Michael J. Bojdys1, Jens‐Oliver Müller2, Markus Antonietti3, Arne Thomas4
1Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476 Potsdam/Golm, Germany.
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society
3Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society
4Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society

Tóm tắt

AbstractHerein we report the synthesis of a crystalline graphitic carbon nitride, or g‐C3N4, obtained from the temperature‐induced condensation of dicyandiamide (NH2C(NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g‐C3N4 species is based on sheets of hexagonally arranged s‐heptazine (C6N7) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X‐ray diffractometry and high‐resolution transmission electron microscopy.

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Chemistry - A European Journal

Tập 14 Số 27

8177-8182

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