Ion mobility spectra of cyclic and aliphatic hydrocarbons with different substituents
Tóm tắt
We investigated the influence of structural differences on the ionization pathways and drift behavior in ion mobility spectrometry for cyclic and aliphatic hydrocarbons with different functional groups. The sets of cyclic and aliphatic compounds had an identical mass or a mass difference of 2 Da. Therefore, mass effects can be neglected during the investigation of these compounds. Depending on the functional group, considerable differences were found in the detectable concentration ranges and in the number and position of product ion peaks in ion mobility spectra. The spectra of chlorinated compounds and hydrocarbons show no correlation to their calculated collisional cross sections. Differences in collisional cross section between cyclic and aliphatic substances investigated were only found to influence the drift times detected for amines and aliphatic aldehydes while complex ion chemistry was observed for the other substances.
Tài liệu tham khảo
Lopez-Avilia V, Hill HH (1997) Anal Chem 69:289R
Turner RB, Brokenshire JL (1994) Trends in Anal Chem 13:275
Eiceman GA, Stone JA (2004) Anal Chem 76:391A
Sohn H, Steinhanses J (1998) Int J for Ion Mobility Spectrom. 1:1
Eiceman GA, Fleischer ME, Leasure CS (1987) Int J Environ Anal Chem 28:279
Borsdorf H, Raemmler A, Schulze D, Boadu KO, Feist B, Weiss H (2001) Anal Chim Acta 440:63
Keller T, Schneider A, Tutsch-Bauer E, Jaspers J, Aderjan R, Skopp G (1999) Int J for Ion Mobility Spectrom 2:22
Elias L, Lawrence AH (1987) Can J Spectrosc 32:14A
Baumbach JI (2006) Anal Bioanal Chem 384:1059
Limero T (1998) In Recent Developments in Ion Mobility Spectrometry. In: JI Baumbach, J Stach (ed) Int. Society for Ion Mobility Spectrometry, Dortmund, Germany, 1998, ISBN 3-00-003676-8, p 317
Xie Z, Sielmann S, Schmidt H, Li F, Baumbach JI (2002) Anal Bioanal Chem 372:606
Matz LM, Dion HM, Hill HH (2002) J Chrom 946:59
Collins DC, Lee ML (2002) Anal Bioanal Chem 372:66
Baumbach JI, Eiceman GA (1999) Appl Spectrosc 53:388A
Hill HH, Siems WF, Louis RHSt, McMinn DG (1990) Anal Chem 62:1201A
Louis RHSt, Hill HH (1990) Crit Rev Anal Chem 21:321
Stach J (1997) Analytiker Taschenbuch 16:119
Adler J, Arnold G, Döring HR, Starrock V, Wülfling E (1998) in Recent developments in ion mobility spectrometry. Baumbach JI, Stach J (ed) Int. Society for Ion Mobility Spectrometry, Dortmund, Germany, 1998, ISBN 3-00-003676-8, p 110.
Giles K, Grimsrud EP (1992) J Phys Chem 96:6680
Eiceman GA, Karpas Z (2005) Ion Mobility Spectrometry. CRC, Boca Raton
Su T, Bowers MT (1973) J Chem Phys 55:3027
Sennhauser ES, Armstrong DA (1980) Can J Chem 58:231
Lin SN, Griffin GW, Horning EC, Wentworth WE (1974) J Chem Phys 60:4994
Karpas Z, Berant Z, Shahal O (1990) Int J Mass Spectrom Ion Processes 96:291
Connolly L (1985) J Appl Cryst 18:499
Dewar MJS, Zoebisch EG, Healy EF, Steward JJP (1985) J Am Chem Soc 107:3902
von Helden G, Hsu MT, Kemper PR, Bowers MT (1991) J Chem Phys 95:3835
Wyttenbach T, Witt M, Bowers MT (2000) J Am Chem Soc 122:3458
Borsdorf H, Neitsch K, Eiceman GA, Stone JA (2009) Talanta 78:1464
Bell SE, Ewing RG, Eiceman GA, Karpas Z (1994) J Am Soc Mass Spectrom 5:177