Ion-Exchange Interaction of Glass-Forming Silicate Melts with Mixed Chloride Melts
Tóm tắt
The ion-exchange interaction of the sodium aluminosilicate and sodium galliumsilicate melts with a mixture of molten Li, Na, K, Rb, Cs, and Ba chlorides is studied. It is established that two alkaline silicate melts are characterized by negative deviations from the ideal behavior, and silicate melts containing alkaline and alkaline-earth cations are characterized by noticeable positive deviations from the ideal behavior.
Tài liệu tham khảo
Takashi, K. and Yoshio, T., Heats of mixing in mixed alkali silicate glasses, J. Soc. Mater. Sci. Jpn., 1977, vol. 26, no. 287, pp. 785–790.
Rogez, J. and Mathieu, J.-C., Entalpic de formation dans le systeme Na2O–K2O–SiO2, Phys. Chem. Liq., 1985, vol. 14, no. 14, pp. 259–271.
Choudarv, U.V., Gaskell, D.R., and Belton, G.R., Thermodynamics of mixing in molten sodium-potassium silicates at 1100°C: the effect of a calcium oxide addition, Metal. Trans. B, 1977, vol. 8, no. 1, pp. 67–71.
Kassis, N. and Friscliat, G.H., Dampfdrucke von Glasschmelzen des Mischalkalisystems Na2O–Rb2O–SiO2, Glastech. Ber., 1981, vol. 54, no. 4, pp. 89–98.
Garfinkel, H.T., Ion-exchange equlibria between glass and molten salts, J. Phys. Chem., 1968, vol. 72, no. 12, pp. 4175–4181.
Lezzi, P.J. and Tomozawa, M., Enthalpy of mixing of mixed alkali glasses, J. Non-Cryst. Solids, 2010, vol. 356, nos. 28–30, pp. 1439–1446.
Sviridov, S.I., Tyurnina, Z.G., and Tyurnina, N.G., Enthalpies of mixing of two alkali glasses and glasses containing alkali and alkaline-earth cations, Glass Phys. Chem., 2008, vol. 34, no. 5, pp. 634–636.
Zhabrev, V.A., Moiseev, V.V., Nekrasov, A.A., and Sviridov, S.I., Study of interdiffusion processes in sodium potassium silicate melts, Fiz. Khim. Stekla, 1978, vol. 4, no. 5, pp. 597–599.
Moiseev, V.V., Permyakova, T.V., Sheshukova, G.E., and Shul’ts, M.M., Thermodynamical characteristics of ion exchange process in sodium silicate glasses, Fiz. Khim. Stekla, 1977, vol. 3, no. 1, pp. 22–28.
Gerasimov, Ya.I. and Geiderikh, V.A., Termodinamika rastvorov (Thermodynamics of Solutions), Moscow: Mosk. Gos. Univ., 1980.
Lamsden, J., Thermodynamics of molten mixtures of alklimetall halides, Discuss. Faraday Soc., 1961, no. 32, pp. 138–146.
Egan, J.J. and Bracker, J., Thermodynamic properties of some binary fused chloride mixtures obtained from e.m.f. measurements, J. Chem. Thermodyn., 1974, vol. 6, no. 1, pp. 9–16.
Huheey, J.E., Inorganic Chemistry: Principles of Structure and Reactivity, New York: Harper Collins College Publ., 1993.
Diagrammy sostoyaniya sistem tugoplavkikh oksidov (State Diagrams of Refractory Oxide Systems), Galakhov, F.Ya., Ed., Leningrad: Nauka, 1985, vol. 5, part 1.
Mazurin, O.V, Roskova, G.P., Aver’yanov, V.I., and Antropova, T.V., in Dvukhfaznye stekla: struktura, svoistva, primenenie (Two-Phase Glasses: Structure, Properties, Application), Varshal, B.G., Ed., Leningrad: Nauka, 1991.
Vedishcheva, N.M. and Wright, A.C., The thermodynamic origin of compositional nanoheterogeneity in glasses, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol., Part B, 2017, vol. 58, no. 4, pp. 150–155.
Vedishcheva N.M., Wright A.C. Chemical structure of oxide glasses: a concept for establishing structure-property relationships, in Glass. Selected Properties and Crystallization, Schmelzer J.W.P., Ed., Berlin: De Gruyter, 2014, Chap. 5, pp. 269–299.
Vedishcheva, N.M., Shakhmatkin, B.A., and Wright, A.C., Thermodynamic modelling of the structure and properties of glasses in the systems Na2O–B2O3–SiO2 and Na2O–CaO–SiO2, Phys. Chem. Glasses, 2005, vol. 46, no. 2, pp. 99–107.
Neudorf, D.A. and Elliott, J.F., Thermodynamic properties of Na2O–SiO2–CaO melts at 1000 to 1100°C, Metall. Trans. B, 1980, vol. 11, no. 12, pp. 607–614.