Investigation of the interaction of benzene with vanadium-molybdenum oxide catalysts by programmed thermal desorption
Tóm tắt
Programmed thermal desorption was used to investigate the interaction of benzene with vanadium-molybdenum oxide catalysts. It was established that the amount of maleic anhydride desorbed from the catalyst surface depends on the catalyst composition and that it varies with its activity and selectivity.
Tài liệu tham khảo
Yu. V. Belokopytov, Yu. N. Grebennikov, Yu. I. Pyatnitskii, and A. I. Telyatnik, “Investigation of the interaction of benzene with a vanadium-molybdenum catalyst by programmed thermal desorption,” Katal. Katal., No. 21, 57 (1933).
Z. I. Ezhkova, I. I. Ioffe, V. B. Razanskii, et al., “Activity, structure, and electrical properties of mixed vanadium catalysts,” Rinet. Katal.,5, No. 5, 861 (1964).
M. Blanchard and Ch. Lyuege, “Analysis of deep oxidation of butenes with oxygen enriched with the18O isotope,” Rinet. Katal.,14, No. 1, 30 (1973).
J. F. Germain and J. C. Peuch, “Rinetics of the catalytic oxidation of benzene on vanadium-molybdenum oxides. 3. Selectivity, activity, and composition of the catalyst,” Bull. Soc. Chim. France, No. 6, 1844 (1969).
I. I. Ioffe, “Rinetics and mechanism of the vapor-phase oxidation of aromatic hydrocarbons,” in: Chemical Rinetics, Catalysis, and Reactivity [in Russian], Izd. Akad. Nauk SSSR, Moscow (1955), pp. 232–240.
G. Boocock and R. J. Cvetanovic, “Reaction of oxygen atoms with benzene,” Can. J. Chem.,39, No. 12, 2436 (1961).
J. Lucas, D. Vandervell, and K. C. Waugh, “Analysis of the factors affecting selectivity in the partial oxidation of benzene to maleic anhydride,” J. Chem. Soc. Faraday Trans., I,77, No. 1, 34 (1931).
Yu. I. Pyatnitskii, “Gas-phase, heterogeneous-catalytic oxidation of aromatic hydrocarbons,” Usp. Rhim.,45, No. 8, 1505 (1970).
G. I. Golodets, “Selection of catalysts for the incomplete oxidation of organic substances with molecular oxygen,” Dokl. Akad. Nauk SSSR,184, No. 6, 1334 (1969).