Sự tương tác giữa các chất pha tạp và khuyết tật trong sự tiến hóa từ tính của TiO2 nanoparticle pha tạp La và Fe

Journal of Sol-Gel Science and Technology - Tập 83 - Trang 365-374 - 2017
Hong Zhang1,2, Yong Xu1, Xinhua Ouyang2, Yonghao Ni2,3
1College of Mechanical and Electrical Engineering, Fujian Agriculture and Forestry University, Fuzhou, China
2College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, China
3Department of Chemical Engineering, University of New Brunswick, Fredericton, Canada

Tóm tắt

Các nanoparticle oxit titan pha tạp La và Fe với nhiều nồng độ La khác nhau đã được tổng hợp bằng phương pháp sol-gel. Tất cả các mẫu đã được đặc trưng hóa bằng các kỹ thuật nhiễu xạ tia X, kính hiển vi điện tử quét, phổ phát quang, biến đổi Fourier hồng ngoại và đo lường từ tính. Kết quả cho thấy cả ion La và Fe đã được pha tạp vào mạng tinh thể oxit titan, và không phát hiện được các pha thứ cấp bao gồm ion La và Fe. Kết quả từ tính cho thấy rằng các mẫu TiO2 pha tạp La và Fe chuẩn bị có cơ chế từ tính phức tạp, bao gồm hành vi từ ferromagnetic ở nhiệt độ phòng và hành vi paramagnetic. Hành vi từ ferromagnetic ở nhiệt độ phòng giảm trong khi sự đóng góp paramagnetic tăng lên với sự gia tăng nồng độ La. Các tính chất từ tính có thể do sự liên kết từ tính giữa hai ion Fe3+ lân cận thông qua khuyết tật oxy (trung tâm F+) khi hình thành các polaron từ tính ràng buộc. Việc tăng nồng độ La làm giảm tỷ lệ khuyết tật oxy, và do đó giảm hành vi từ ferromagnetic, dẫn đến việc tăng cường sự định hướng paramagnetic.

Từ khóa

#La doped #Fe doped #titanium dioxide #magnetic properties #sol-gel method.

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