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Phim Mono Bạc Gây Tăng Cường Tán Xạ Raman Tại Giao Diện Để Phát Hiện Enrofloxacin Không Tan Trong Nước
Tóm tắt
Các phân tử không tan trong nước thường cho tín hiệu tán xạ Raman tăng cường bề mặt (SERS) kém, vì chúng khó được hấp phụ trên bề mặt của các chất nền SERS thường được sử dụng, chẳng hạn như keo bạc (Ag) hoặc vàng (Au) trong môi trường nước. Trong nghiên cứu này, một chất nền SERS phim mono bạc (Ag MLF) nhạy cảm và có khả năng tái tạo cao được chế tạo bằng phương pháp tự lắp ghép các hạt nano bạc (Ag NPs) trên giao diện nước/dầu có thể thực hiện việc phát hiện enrofloxacin không tan trong nước ở nồng độ vết. Chất xúc tác chuyển pha mang tải dương có thể chuyển các hạt nano bạc mang tải âm trong dung dịch nước tới giao diện nước/dầu. Đồng thời, enrofloxacin không tan trong nước cũng có thể bị thu hút tới giao diện nhờ vào nhóm ưa mỡ của nó. Loại/thể tích của pha dầu, chất xúc tác chuyển pha và thời gian khuấy xoáy đã được tối ưu hóa để tối đa hóa hiệu ứng SERS của Ag MLF. Kết quả cho thấy enrofloxacin không tan trong nước ở nồng độ vết có thể được nhận diện bởi Ag MLF và độ nhạy phát hiện của nó đã được cải thiện đáng kể. Ag MLF mới được đề xuất có thể được áp dụng để phát hiện các phân tử không tan trong nước khác trong SERS.
Từ khóa
#Phim bạc đơn lớp #Tán xạ Raman tăng cường bề mặt #Enrofloxacin không tan trong nước #Hạt nano bạc #Chất xúc tác chuyển phaTài liệu tham khảo
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