Intercalation strategies in clay/polymer hybrids

Progress in Polymer Science - Tập 39 - Trang 443-485 - 2014
Chih-Wei Chiu1, Ting-Kai Huang2, Ya-Chi Wang2, Bryan G. Alamani2, Jiang-Jen Lin2
1Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan
2Institute of Polymer Science and Engineering, National Taiwan University, Taipei 10617, Taiwan

Tài liệu tham khảo

Ray, 2003, Polymer/layered silicate nanocomposites: a review from preparation to processing, Prog Polym Sci, 28, 1539, 10.1016/j.progpolymsci.2003.08.002 Pavlidou, 2008, A review on polymer-layered silicate nanocomposites, Prog Polym Sci, 33, 1119, 10.1016/j.progpolymsci.2008.07.008 Kumar, 2009, Nanoscale particles for polymer degradation and stabilization-trends and future perspectives, Prog Polym Sci, 34, 479, 10.1016/j.progpolymsci.2009.01.002 Bordes, 2009, Nano-biocomposites: biodegradable polyester/nanoclay systems, Prog Polym Sci, 34, 125, 10.1016/j.progpolymsci.2008.10.002 Kiliaris, 2010, Polymer/layered silicate (clay) nanocomposites: an overview of flame retardancy, Prog Polym Sci, 35, 902, 10.1016/j.progpolymsci.2010.03.001 Alexandre, 2000, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials, Mater Sci Eng, 28, 1, 10.1016/S0927-796X(00)00012-7 Utracki, 2007, Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs), Polym Adv Technol, 18, 1, 10.1002/pat.852 Giannelis, 1996, Polymer layered silicate nanocomposites, Adv Mater, 8, 29, 10.1002/adma.19960080104 Chiu, 2012, Self-assembly behavior of polymer-assisted clays, Prog Polym Sci, 37, 406, 10.1016/j.progpolymsci.2011.07.007 Lin, 2010, Amphiphilic poly(oxyalkylene)-amines interacting with layered clays: intercalation, exfoliation, and new applications, 459 Lin, 2010, Hydrophobic modification of layered clays and compatibility for epoxy nanocomposites, Materials, 3, 2588, 10.3390/ma3042588 Beija, 2011, RAFT/MADIX polymers for the preparation of polymer/inorganic nanohybrids, Prog Polym Sci, 36, 845, 10.1016/j.progpolymsci.2011.01.002 Spitalsky, 2010, Carbon nanotube–polymer composites: chemistry, processing, mechanical and electrical properties, Prog Polym Sci, 35, 357, 10.1016/j.progpolymsci.2009.09.003 Compton, 2010, Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials, Small, 6, 711, 10.1002/smll.200901934 Li, 2001, Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: a review, J Inorg Organomet Polym, 11, 123, 10.1023/A:1015287910502 Li, 2005, Polyhedral oligomeric silsesquioxane (POSS) polymers, copolymers and resin nanocomposites, vol. 4, 79 Wu, 2009, POSS polymers: physical properties and biomaterials applications, Polym Rev, 49, 25, 10.1080/15583720802656237 Kawakami, 2011, Polyhedral oligomeric silsesquioxanes with controlled structure: formation and application in new Si-based polymer systems, Adv Polym Sci, 235, 185, 10.1007/12_2010_55 Novoselov, 2004, Electric field effect in atomically thin carbon films, Science, 306, 666, 10.1126/science.1102896 Kuilla, 2010, Recent advances in graphene based polymer composites, Prog Polym Sci, 35, 1350, 10.1016/j.progpolymsci.2010.07.005 Sengupta, 2011, A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites, Prog Polym Sci, 36, 638, 10.1016/j.progpolymsci.2010.11.003 Premkumar, 2012, Graphene–DNA hybrid materials: assembly, applications, and prospects, Prog Polym Sci, 37, 515, 10.1016/j.progpolymsci.2011.08.003 Roy, 2012, Modifications of carbon for polymer composites and nanocomposites, Prog Polym Sci, 37, 781, 10.1016/j.progpolymsci.2012.02.002 Iwan, 2012, Perspectives of applied graphene: polymer solar cells, Prog Polym Sci, 37, 1805, 10.1016/j.progpolymsci.2012.08.001 Novoselov, 2005, Two-dimensional gas of massless Dirac fermions in grapheme, Nature, 438, 197, 10.1038/nature04233 Novoselov, 2007, Room-temperature quantum hall effect in graphene, Science, 315, 1379, 10.1126/science.1137201 Tombros, 2007, Electronic spin transport and spin precession in single graphene layers at room temperature, Nature, 448, 571, 10.1038/nature06037 Geim, 2007, The rise of graphene, Nat Mater, 6, 183, 10.1038/nmat1849 Balandin, 2008, Superior thermal conductivity of single-layer graphene, Nano Lett, 8, 902, 10.1021/nl0731872 Wang, 2008, Room-temperature all-semiconducting sub-10-nm graphene nanoribbon field-effect transistors, Phys Rev Lett, 100, 206803/1, 10.1103/PhysRevLett.100.206803 Blake, 2008, Graphene-based liquid crystal device, Nano Lett, 8, 1704, 10.1021/nl080649i Schedin, 2007, Detection of individual gas molecules adsorbed on graphene, Nat Mater, 6, 652, 10.1038/nmat1967 Stoller, 2008, Graphene-based ultracapacitors, Nano Lett, 8, 3498, 10.1021/nl802558y Xuan, 2008, Transparent, conductive graphene electrodes for dye-sensitized solar cells, Nano Lett, 8, 323, 10.1021/nl072838r Liu, 2008, Organic photovoltaic devices based on a novel acceptor material: graphene, Adv Mater, 20, 3924, 10.1002/adma.200800366 Yan, 2012, Tunable infrared plasmonic devices using graphene/insulator stacks, Nat Nanotechnol, 7, 330, 10.1038/nnano.2012.59 Liang, 2009, Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites, Adv Funct Mater, 19, 2297, 10.1002/adfm.200801776 Miller, 2009, Observing the quantization of zero mass carriers in graphene, Science, 324, 924, 10.1126/science.1171810 Chang, 2010, Graphene fluorescence resonance energy transfer aptasensor for the thrombin detection, Anal Chem, 82, 2341, 10.1021/ac9025384 Wang, 2012, Promoting effect of graphene on dye-sensitized solar cells, Ind Eng Chem Res, 51, 10613, 10.1021/ie300563h Yoonessi, 2012, Graphene polyimide nanocomposites; thermal, mechanical, and high-temperature shape memory effects, ACS Nano, 6, 7644, 10.1021/nn302871y Okada, 1995, The chemistry of polymer–clay hybrids, Mater Sci Eng C, 3, 109, 10.1016/0928-4931(95)00110-7 Okada, 2006, Twenty years of polymer–clay nanocomposites, Macromol Mater Eng, 291, 1449, 10.1002/mame.200600260 Porter, 2000, Nanocomposite fire retardants: a review, Fire Mater, 24, 45, 10.1002/(SICI)1099-1018(200001/02)24:1<45::AID-FAM719>3.0.CO;2-S Wang, 1998, Hybrid organic–inorganic nanocomposites: exfoliation of magadiite nanolayers in an elastomeric epoxy polymer, Chem Mater, 10, 1820, 10.1021/cm970784o Gilman, 1999, Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites, Appl Clay Sci, 15, 31, 10.1016/S0169-1317(99)00019-8 Zhang, 2004, Preparation and characterization of modified-clay-reinforced and toughened epoxy–resin nanocomposites, J Appl Polym Sci, 91, 2649, 10.1002/app.13445 Chiu, 2007, Fine dispersion of hydrophobic silicate platelets in anhydride-cured epoxy nanocomposites, Ind Eng Chem Res, 46, 7384, 10.1021/ie070629b Toldy, 2007, Intrinsically flame retardant epoxy resine fire performance backgrounde – Part I, Polym Degrad Stab, 92, 2223, 10.1016/j.polymdegradstab.2007.04.017 Joulazadeh, 2011, Study on elastic modulus of crosslinked polyurethane/organoclay nanocomposites, Polym Adv Technol, 22, 2022, 10.1002/pat.1713 Fu, 2004, Synthesis of unsaturated polyester–clay nanocomposites using reactive organoclays, Polym Eng Sci, 44, 345, 10.1002/pen.20031 Davis, 2002, Effects of melt-processing conditions on the quality of poly(ethyleneterephthalate) montmorillonite clay nanocomposites, J Polym Sci Part B Polym Phys, 40, 2661, 10.1002/polb.10331 Choi, 2001, Synthesis of exfoliated PMMA/Na-MMT nanocomposites via soap-free emulsion polymerization, Macromolecules, 34, 8978, 10.1021/ma0106494 Kim, 2002, Synthesis of exfoliated PS/Na-MMT nanocomposites via emulsion polymerization, Chem Mater, 14, 4990, 10.1021/cm020324h Noh, 1999, Intercalation of styrene–acrylonitrile copolymer in layered silicate by emulsion polymerization, J Appl Polym Sci, 74, 179, 10.1002/(SICI)1097-4628(19991003)74:1<179::AID-APP22>3.0.CO;2-G Theng, 1974, 343 Olphen, 1977, 318 Theng, 1979, 362 Triantafillidis, 2002, Homostructured mixed inorganic–organic ion clays: a new approach to epoxy polymer-exfoliated clay nanocomposites with a reduced organic modifier content, Chem Mater, 14, 4088, 10.1021/cm0202862 Muzny, 1996, Clay platelet dispersion in a polymer matrix, Mater Lett, 28, 379, 10.1016/0167-577X(96)00085-7 Bohning, 2005, Dielectric study of molecular mobility in poly(propylene-graft-maleic anhydride)/clay nanocomposites, Macromolecules, 38, 2764, 10.1021/ma048315c Robello, 2004, Spontaneous formation of an exfoliated polystyrene–clay nanocomposite using a star-shaped polymer, J Am Chem Soc, 126, 8118, 10.1021/ja048211h Tien, 2002, The effect of nano-sized silicate layers from montmorillonite on glass transition, dynamic mechanical, and thermal degradation properties of segmented polyurethane, J Appl Polym Sci, 86, 1741, 10.1002/app.11086 Lepoittevin, 2002, Polyester layered silicate nanohybrids by controlled grafting polymerization, J Mater Chem, 12, 3528, 10.1039/B205787E Myskova, 2003, Properties of epoxy systems with clay nanoparticles, Macromol Symp, 200, 291, 10.1002/masy.200351031 Wang, 1994, Clay–polymer nanocomposites formed from acidic derivatives of montmorillonite and an epoxy resin, Chem Mater, 6, 468, 10.1021/cm00040a022 Lan, 1996, Epoxy self-polymerization in smectite clays, J Phys Chem Solids, 57, 1005, 10.1016/0022-3697(95)00388-6 LeBaron, 1999, Polymer-layered silicate nanocomposites: an overview, Appl Clay Sci, 15, 11, 10.1016/S0169-1317(99)00017-4 Yang, 1999, Preparation and properties of hybrids of organo-soluble polyimide and montmorillonite with various chemical surface modification methods, Polymer, 40, 4407, 10.1016/S0032-3861(98)00675-2 Maiti, 2006, Preparation and characterization of nanocomposites based on thermoplastic elastomers from rubber-plastic blends, J Appl Polym Sci, 99, 1645, 10.1002/app.22699 Subramani, 2007, Waterborne trifunctionalsilane-terminated polyurethane nanocomposite with silane-modified clay, J Polym Sci B Polym Phys, 45, 2747, 10.1002/polb.21285 Bourlinos, 2004, Clay–organosiloxane hybrids: a route to cross-linked clay particles and clay monoliths, Chem Mater, 16, 2404, 10.1021/cm049975z Mahadevaiah, 2007, Restrictive entry of aqueous molybdate species into surfactant modified montmorillonite – a breakthrough curve study, Chem Mater, 19, 4606, 10.1021/cm071028d Vaia, 1994, Interlayer structure and molecular environment of alkylammonium layered silicates, Chem Mater, 6, 1017, 10.1021/cm00043a025 Hotta, 2004, Nanocomposites formed from linear low density polyethylene and organoclays, Polymer, 45, 7639, 10.1016/j.polymer.2004.08.059 Zeng, 2001, Poly(methyl methacrylate) and polystyrene/clay nanocomposites prepared by in-situ polymerization, Macromolecules, 34, 4098, 10.1021/ma010061x Fu, 2001, Polymer–clay nanocomposites: exfoliation of organophilic montmorillonite nanolayers in polystyrene, Polymer, 42, 807, 10.1016/S0032-3861(00)00385-2 Fu, 2000, Synthesis of polystyrene–clay nanocomposites, Mater Lett, 42, 12, 10.1016/S0167-577X(99)00151-2 Imai, 2002, High-modulus poly(ethylene terephthalate)/expandable fluorine mica nanocomposites with a novel reactive compatibilizer, Chem Mater, 14, 477, 10.1021/cm010408a Chang, 2003, Poly(vinyl alcohol) nanocomposites with different clays: pristine clays and organoclays, J Appl Polym Sci, 90, 3208, 10.1002/app.12996 Kim, 2004, Synthesis and material properties of syndiotactic polystyrene/organophilic clay nanocomposites, J Appl Polym Sci, 92, 2144, 10.1002/app.20186 Ijdo, 1999, Solid solution formation in amphiphilic organic–inorganic clay heterostructures, Chem Mater, 11, 3227, 10.1021/cm990294r Maiti, 2002, New polylactide/layered silicate nanocomposites: role of organoclays, Chem Mater, 14, 4654, 10.1021/cm020391b Xie, 2002, Thermal stability of quaternary phosphonium modified montmorillonites, Chem Mater, 14, 4837, 10.1021/cm020705v Bottino, 2003, Polystyrene–clay nanocomposites prepared with polymerizable imidazolium surfactants, Macromol Rapid Commun, 24, 1079, 10.1002/marc.200300054 Fox, 2007, Use of a polyhedral oligomeric silsesquioxane (POSS)-imidazolium cation as an organic modifier for montmorillonite, Langmuir, 23, 7707, 10.1021/la0636863 Wang, 2003, Melt-processable syndiotactic polystyrene/montmorillonite nanocomposites, J Polym Sci B Polym Phys, 41, 3173, 10.1002/polb.10697 Gilman, 2002, Polymer/layered silicate nanocomposites from thermally stable trialkylimidazolium-treated montmorillonite, Chem Mater, 14, 3776, 10.1021/cm011532x Hotta, 1996, Formation of thin films of clay-organic complexes with an application as an electrode modifier, Langmuir, 12, 5195, 10.1021/la950695v Wang, 2005, Preparation of highly exfoliated epoxy/clay nanocomposites by “slurry compounding”: process and mechanisms, Langmuir, 21, 3613, 10.1021/la047709u Szabo, 1998, Clay–aminopropylsiloxane compositions, Chem Mater, 10, 639, 10.1021/cm9706311 Hotta, 1997, A clay self-assembled on a gold surface as studied by atomic force nicroscopy and electrochemistry, Langmuir, 13, 6697, 10.1021/la970333i Chou, 2005, Unusual intercalation of cationic smectite clays with detergent-ranged carboxylic ions, Macromol Rapid Commun, 26, 1841, 10.1002/marc.200500559 Chu, 2005, Exfoliation of montmorillonite clay by mannich polyamines with multiple quaternary salts, Macromolecules, 38, 6240, 10.1021/ma0503716 Lin, 2006, First isolation of individual silicate platelets from clay exfoliation and their unique self-assembly into fibrous arrays, J Phys Chem B, 110, 18115, 10.1021/jp0636773 Pinnavaia, 1983, Intercalated clay catalysts, Science, 220, 365, 10.1126/science.220.4595.365 Cseri, 1995, Benzylation of aromatics on ion-exchanged clays, J Mol Catal A, 98, 101, 10.1016/1381-1169(95)00016-X Ajjou, 1997, Cation-exchanged montmorillonite catalyzed hydration of styrene derivatives, J Mol Catal A, 126, 55, 10.1016/S1381-1169(97)00094-0 Laszlo, 1987, Chemical reactions on clays, Science, 235, 1473, 10.1126/science.235.4795.1473 Corma, 1998, Delaminated zeolite precursors as selective acidic catalysts, Nature, 396, 353, 10.1038/24592 Celis, 2002, Inorganic and organic clays as carriers for controlled release of the herbicide hexazinone, J Agric Food Chem, 50, 2324, 10.1021/jf011360o Rawajfih, 2006, Characteristics of phenol and chlorinated phenols sorption onto surfactant-modified bentonite, J Colloid Interface Sci, 298, 39, 10.1016/j.jcis.2005.11.063 Kiraly, 2001, Preparation of ultrafine palladium particles on cationic and anionic clays, mediated by oppositely charged surfactants: catalytic probes in hydrogenations, Langmuir, 17, 5381, 10.1021/la0102004 Giannelis, 1998, Polymer-layered silicate nanocomposites: synthesis, properties and applications, Appl Organomet Chem, 12, 675, 10.1002/(SICI)1099-0739(199810/11)12:10/11<675::AID-AOC779>3.0.CO;2-V Balogh, 1993, 184 Usuki, 2001, Three-dimensional observation of structure and morphology in nylon-6/clay nanocomposite, Nano Lett, 1, 271, 10.1021/nl010015a Lai, 2009, Enhancing the performance of dye-sensitized solar cells by incorporating nanosilicate platelets in gel electrolyte, Sol Energy Mater Sol Cells, 93, 1860, 10.1016/j.solmat.2009.06.027 Tateyama, 1992, Synthesis of expandable fluorine mica from talc, Clays Clay Miner, 40, 180, 10.1346/CCMN.1992.0400207 Kodama, 2001, Synthesis of Na-2-mica from metakaolin and its cation exchange properties, J Mater Chem, 11, 2072, 10.1039/b101186n Chiu, 2008, Self-piling silicate rods and dendrites from high aspect-ratio clay platelets, J Phys Chem C, 112, 17940, 10.1021/jp806768v Sun, 2010, Thermogelling aqueous fluids containing low concentrations of pluronic F127 and laponite nanoparticles, Langmuir, 26, 8015, 10.1021/la904907b Haraguchi, 2011, Synthesis and properties of soft nanocomposite materials with novel organic/inorganic network structures, Polym J, 43, 223, 10.1038/pj.2010.141 Leach, 2005, Nonaqueous suspensions of laponite and montmorillonite, Langmuir, 21, 3821, 10.1021/la0503909 Rives, 1999, Layered double hydroxides (LDH) intercalated with metal coordination compounds and oxometalates, Coord Chem Rev, 181, 61, 10.1016/S0010-8545(98)00216-1 Rives, 2002, Characterisation of layered double hydroxides and their decomposition products, Mater Chem Phys, 75, 19, 10.1016/S0254-0584(02)00024-X Khan, 2002, Intercalation chemistry of layered double hydroxides: recent developments and applications, J Mater Chem, 12, 3191, 10.1039/B204076J Lagaly, 1986, Interaction of alkylamines with different types of layered compounds, Solid State Ionics, 22, 43, 10.1016/0167-2738(86)90057-3 Hackett, 1998, Molecular dynamics simulations of organically modified layered silicates, J Chem Phys, 108, 7410, 10.1063/1.476161 Lin, 2001, Tailoring basal spacings of montmorillonite by poly(oxyalkylene)diamine intercalation, Macromolecules, 34, 8832, 10.1021/ma011169f Moss PH. Nickel–copper–chromia catalyst and the preparation thereof. US 3,152,998, 1964. Yeakey EL. Poly(oxyalkylene) polyamines. US 3,654,370, 1972. Lin, 2003, Critical conformational change of poly(oxypropylene)diamines in layered aluminosilicate confinement, Macromol Rapid Commun, 24, 492, 10.1002/marc.200390073 Chou, 2004, Conformational change of trifunctional poly(oxypropylene)amines intercalated within a layered silicate confinement, Macromolecules, 37, 473, 10.1021/ma0343941 Chou, 2003, Preparation, organophilicity, and self-assembly of poly(oxypropylene)amine–clay hybrids, Macromolecules, 36, 2187, 10.1021/ma025773h Lin, 2004, Amphiphilic properties of poly(oxyalkylene)amine-intercalated smectite aluminosilicates, Langmuir, 20, 4261, 10.1021/la0362775 Lin, 2003, Copolymer-layered silicate hybrid surfactants from the intercalation of montmorillonite with amphiphilic copolymers, Langmuir, 19, 5184, 10.1021/la034022l Chou, 2005, One-step exfoliation of montmorillonite via phase inversion of amphiphilic copolymer emulsion, Macromolecules, 38, 230, 10.1021/ma047761x Chang, 2005, Emulsion intercalation of smectite clays with comb-branched copolymers consisting of multiple quaternary amine salts and a poly(styrene–butadiene–styrene) backbone, Langmuir, 21, 7023, 10.1021/la050948c Lin, 2007, Mechanistic aspects of clay intercalation with amphiphilic poly(styrene-co-maleic anhydride)-grafting polyamine salts, Macromolecules, 40, 1579, 10.1021/ma062508d Iyi, 2008, Water-swellable MgAl-LDH (layered double hydroxide) hybrids: synthesis, characterization, and film preparation, Langmuir, 24, 5591, 10.1021/la800302w Moujahid, 2005, In situ polymerization of aniline sulfonic acid derivatives into LDH interlamellar space probed by ESR and electrochemical studies, Chem Mater, 17, 373, 10.1021/cm0401701 Lee, 2006, Preparation and properties of layered double hydroxide/poly(ethyleneterephthalate) nanocomposites by direct melt compounding, Polymer, 47, 1364, 10.1016/j.polymer.2005.12.056 Mohanambe, 2005, Inclusion of ferrocene in a cyclodextrin-functionalized layered metal hydroxide: a new organometallic-organic-LDH nanohybrid, Inorg Chem, 44, 2128, 10.1021/ic050039a Lee, 2007, Selective layer reaction of layer-by-layer assembled layered double-hydroxide nanocrystals, J Am Chem Soc, 129, 3522, 10.1021/ja070512e Sayes, 2005, Nano-C60 cytotoxicity is due to lipid peroxidation, Biomaterials, 26, 7587, 10.1016/j.biomaterials.2005.05.027 Zhang, 2009, Intercalation of sulfonate into layered double hydroxide: comparison of simulation with experiment, J Phys Chem C, 113, 559, 10.1021/jp807411x Choy, 1999, Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide, J Am Chem Soc, 121, 1399, 10.1021/ja981823f Choy, 2000, Inorganic layered double hydroxides as nonviral vectors, Angew Chem Int Ed, 39, 4041, 10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-C Sels, 1999, Layered double hydroxides exchanged with tungstate as biomimetic catalysts for mild oxidative bromination, Nature, 400, 855, 10.1038/23674 Schonhals, 2009, Dielectric properties of nanocomposites based on polyethylene and layered double hydroxide, Macromolecules, 42, 4165, 10.1021/ma900077w Tsai, 2006, Polymer-dispersed liquid crystal/layered double hydroxide nanocomposite: a new emerging optical application, J Phys Chem Solids, 67, 938, 10.1016/j.jpcs.2006.01.078 Jin, 2010, Preparation of 5-fluorouracil/β-cyclodextrin complex intercalated in layered double hydroxide and the controlled drug release properties, Ind Eng Chem Res, 49, 11176, 10.1021/ie100990z Liao, 2010, General intercalation of poly(oxyalkylene)-amidoacids for anionic and cationic layered clays, Ind Eng Chem Res, 49, 5001, 10.1021/ie901136u Lin, 2004, Intercalation of layered double hydroxides by poly(oxyalkylene)-amidocarboxylates: tailoring layered basal spacing, Polymer, 45, 7887, 10.1016/j.polymer.2004.09.031 Chiu, 2012, Mg–Al layered doublehydroxides intercalated with polyetheramidoacids and exhibiting a pH-responsive releasing property, Ind Eng Chem Res, 51, 581, 10.1021/ie201535n Choy, 1997, New organo-montmorillonite complexes with hydrophobic and hydrophilic functions, Mater Lett, 33, 143, 10.1016/S0167-577X(97)00092-X Choy, 2001, Cellular uptake behavior of [γ-32P] labeled ATP-LDH nanohybrids, J Mater Chem, 11, 1671, 10.1039/b008680k Choy, 2007, Clay minerals and layered double hydroxides for novel biological applications, Appl Clay Sci, 36, 122, 10.1016/j.clay.2006.07.007 Fan, 2003, Polymer brushes grafted from clay nanoparticles adsorbed on a planar substrate by free radical surface-initiated polymerization, Langmuir, 19, 916, 10.1021/la026039u Fan, 2003, Grafting of polymers from clay nanoparticles via in situ free radical surface-initiated polymerization: monocationic versus bicationic initiators, Langmuir, 19, 4381, 10.1021/la0268193 Braunecker, 2007, Controlled/living radical polymerization: features, developments, and perspectives, Prog Polym Sci, 32, 93, 10.1016/j.progpolymsci.2006.11.002 Weimer, 1999, Direct synthesis of dispersed nanocomposites by in situ living free radical polymerization using a silicate-anchored initiator, J Am Chem Soc, 121, 1615, 10.1021/ja983751y Di, 2006, Exfoliated block copolymer/silicate nanocomposites by one-pot, one-step in-situ living polymerization from silicate-anchored multifunctional initiator, Macromolecules, 39, 5052, 10.1021/ma060543e Konn, 2007, Nitroxide-mediated polymerization of styrene initiated from the surface of laponite clay platelets, Macromolecules, 40, 7464, 10.1021/ma070283g Yang, 2007, PMMA colloid particles stabilized by layered silicate with PMMA-b-PDMAEMA block copolymer brushes, Langmuir, 23, 2867, 10.1021/la063078n Yang, 2006, Poly(l-lactide) comb polymer brushes on the surface of clay layers, Polymer, 47, 7374, 10.1016/j.polymer.2006.08.053 Zhao, 2003, Preparation of poly(styrene-block-butyl acrylate) block copolymer-silicate nanocomposites, Chem Mater, 15, 2693, 10.1021/cm034013y Zhao, 2004, Polymer-silicate nanocomposites produced by in situ atom transfer radical polymerization, J Polym Sci Part A Polym Chem, 42, 916, 10.1002/pola.11071 Sedjo, 2000, Synthesis of polystyrene-block-poly(methyl methacrylate) brushes by reverse atom transfer radical polymerization, Macromolecules, 33, 1492, 10.1021/ma991549p Bottcher, 2002, Organic/inorganic hybrids by ‘living’/controlled ATRP grafting from layered silicates, J Mater Chem, 12, 1351, 10.1039/b110819k Datta, 2008, Tailor-made hybrid nanostructure of poly(ethyl acrylate)/clay by surface-initiated atom transfer radical polymerization, J Polym Sci Part A Polym Chem, 46, 5014, 10.1002/pola.22829 Datta, 2008, Beneficial effect of nanoclay in atom transfer radical polymerization of ethyl acrylate: a one pot preparation of tailor-made polymer nanocomposite, Macromolecules, 41, 50, 10.1021/ma071528s Behling, 2009, Influence of graft density on kinetics of surface-initiated ATRP of polystyrene from montmorillonite, Macromolecules, 42, 1867, 10.1021/ma8024909 Di, 2006, Intergallery living polymerization using silicate-anchored photoiniferter. A versatile preparatory method for exfoliated silicate nanocomposites, Macromolecules, 39, 1020, 10.1021/ma049794i Shah, 2005, Structure and dynamics of polymer-grafted clay suspensions, Langmuir, 21, 19, 10.1021/la049857q Zhou, 2001, Living anionic surface initiated polymerization (SIP) of styrene from clay surfaces, Chem Mater, 13, 2465, 10.1021/cm0101780 Fan, 2002, Living anionic surface-initiated polymerization (LASIP) of styrene from clay nanoparticles using surface bound 1,1-diphenylethylene (DPE) initiators, Langmuir, 18, 4511, 10.1021/la025556+ Herrera, 2005, Silylation of laponite clay particles with monofunctional and trifunctional vinyl alkoxysilanes, J Mater Chem, 15, 863, 10.1039/b415618h Herrera, 2004, Aqueous dispersions of silane-functionalized laponite clay platelets. A first step toward the elaboration of water-based polymer/clay nanocomposites, Langmuir, 20, 1564, 10.1021/la0349267 Herrera, 2006, Polymer/laponite composite colloids through emulsion polymerization: influence of the clay modification level on particle morphology, Macromolecules, 39, 9177, 10.1021/ma0610515 Lee, 2006, Waterborne polyurethane/clay nanocomposites: novel effects of the clay and its interlayer ions on the morphology and physical and electrical properties, Macromolecules, 39, 6133, 10.1021/ma060621y Sun, 2007, Water-based polymer/clay nanocomposite suspension for improving water and moisture barrier in coating, Compos Sci Technol, 67, 1823, 10.1016/j.compscitech.2006.10.022 Bonnefond, 2013, Morphology and properties of waterborne adhesives made from hybrid polyacrylic/montmorillonite clay colloidal dispersions showing improved tack and shear resistance, Colloid Polym Sci, 291, 167, 10.1007/s00396-012-2649-3 Wheeler, 2006, Poly(methyl methacrylate)/laponite nanocomposites: exploring covalent and ionic clay modifications, Chem Mater, 18, 3937, 10.1021/cm0526361 Wheeler, 2005, Synthesis and characterization of covalently functionalized laponite clay, Chem Mater, 17, 3012, 10.1021/cm050306a Li, 2005, Properties of covalently bonded layered-silicate/polystyrene nanocomposites synthesized via atom transfer radical polymerization, J Polym Sci Part A Polym Chem, 43, 534, 10.1002/pola.20536 Wu, 2009, Functional colloidal particles stabilized by layered silicate with hydrophilic face and hydrophobic polymer brushes, J Polym Sci Part A Polym Chem, 47, 1535, 10.1002/pola.23256 Wang, 2007, Synthesis and characterization of dual-functionalized laponite clay for acrylic nanocomposites, J Appl Polym Sci, 106, 1496, 10.1002/app.26763 Lagaly, 1975, Magadiite and H-magadiite: I. Sodium magadiite and some of its derivatives, Am Mineral, 60, 642 Beneke, 1977, Kanemite-innercrystalline reactivity and relations to others odium silicates, Am Mineral, 62, 763 Beneke, 1983, Kenyaite-synthesis and properties, Am Mineral, 68, 818 Brindley, 1969, Unit cell of magadiite in air, in vacuo, and under other conditions, Am Mineral, 54, 1583 Leu, 2002, Synthesis and properties of covalently bonded layered silicates/polyimide (BTDA-ODA) nanocomposites, Chem Mater, 14, 3016, 10.1021/cm0200240 Chen, 2009, Thermoresponsive dual-phase transition and 3D self-assembly of poly(N-isopropylacrylamide) tethered to silicate platelets, Chem Mater, 21, 4071, 10.1021/cm901560e Chen, 2009, Orderly arranged NLO materials based on chromophore-containing dendrons on exfoliated layered templates, ACS Appl Mater Interfaces, 1, 2371, 10.1021/am900499s Chen, 2008, Optical non-linearity from montmorillonite intercalated with a chromophore-containing dendritic structure: a self-assembly approach, Macromol Rapid Commun, 29, 587, 10.1002/marc.200700774 Tsai, 2006, Synthesis and montmorillonite-intercalated behavior of dendritic surfactants, J Mater Chem, 16, 2056, 10.1039/b600544f Juang, 2007, Organo-clay hybrids based on dendritic molecules: preparation and characterization, Nanotechnology, 18, 205606/1, 10.1088/0957-4484/18/20/205606 Chen, 2009, Dendronized organic–inorganic nonlinear optical hybrid materials with homogeneous morphology, Synth Met, 159, 1852, 10.1016/j.synthmet.2009.06.005 Juang, 2010, Nanoscale organic/inorganic hybrids based on self-organized dendritic macromolecules on montmorillonites, Appl Clay Sci, 48, 103, 10.1016/j.clay.2009.11.049 Lichtenhan, 1996, Silsesquioxane-based polymers, 7768 Carmo, 2004, Thermolysis of octa (hydridodimethylsiloxyl) octasilsesquioxane in pyridine media and subsequent toluidine blue O adsorption, Appl Surf Sci, 235, 449, 10.1016/j.apsusc.2004.02.061 He, 2006, Using inorganic POSS-modified laponite clay to support a nickel α-diimine catalyst for in situ formation of high performance polyethylene nanocomposites, Nanotechnology, 17, 5941, 10.1088/0957-4484/17/24/007 Liu, 2005, Montmorillonite intercalated by ammonium of octaaminopropyl polyhedral oligomeric silsesquioxane and its nanocomposites with epoxy resin, Polymer, 46, 157, 10.1016/j.polymer.2004.10.078 Yei, 2004, Enhanced thermal properties of PS nanocomposites formed from inorganic POSS-treated montmorillonite, Polymer, 45, 2633, 10.1016/j.polymer.2004.02.020 Fu, 2008, Properties enhancement of PS nanocomposites through the POSS surfactants, J Nanomater, 2008, 739613/1, 10.1155/2008/739613 Fu, 2008, Studies on thermal properties of PS nanocomposites for the effect of intercalated agent with side groups, Polymer, 49, 1305, 10.1016/j.polymer.2008.01.013 Kuo, 2011, POSS related polymer nanocomposites, Prog Polym Sci, 36, 1649, 10.1016/j.progpolymsci.2011.05.002 Toh, 2010, Packing behaviors of structurally different polyhedral oligomeric silsesquioxane-imidazolium surfactants in clay, J Phys Chem B, 114, 207, 10.1021/jp908276a Nair, 2010, Microvesicles through self-assembly of polystyrene–clay nanocomposite, Langmuir, 26, 1431, 10.1021/la903360e Wan, 2008, Surface characteristics of polyhedral oligomeric silsesquioxane modified clay and its application in polymerization of macrocyclic polyester oligomers, J Phys Chem B, 112, 11915, 10.1021/jp805259q Gui, 2010, Carbon nanotube sponges, Adv Mater, 22, 617, 10.1002/adma.200902986 Zhang, 2011, Dramatically enhanced mechanical performance of nylon-6 magnetic composites with nanostructured hybrid one-dimensional carbon nanotube/two-dimensional clay nanoplatelet heterostructures, J Phys Chem B, 115, 3392, 10.1021/jp112284k Geng, 2009, Preparation of graphite nanoplatelets and graphene sheets, J Colloid Interface Sci, 336, 592, 10.1016/j.jcis.2009.04.005 Wei, 2009, Preparation of graphene nanosheet/polymer composites using in situ reduction-extractive dispersion, Carbon, 47, 2290, 10.1016/j.carbon.2009.04.030 Hummers, 1958, Preparation of graphitic oxide, J Am Chem Soc, 80, 1339, 10.1021/ja01539a017 Park, 2008, Aqueous suspension and characterization of chemically modified graphene sheets, Chem Mater, 20, 6592, 10.1021/cm801932u Worsley, 2007, Soluble graphene derived from graphite fluoride, Chem Phys Lett, 445, 51, 10.1016/j.cplett.2007.07.059 Niyogi, 2006, Solution properties of graphite and graphene, J Am Chem Soc, 128, 7720, 10.1021/ja060680r Bai, 2009, Non-covalent functionalization of graphene sheets by sulfonated polyaniline, Chem Commun, 13, 1667, 10.1039/b821805f Salavagione, 2009, Polymeric modification of graphene through esterification of graphite oxide and poly(vinyl alcohol), Macromolecules, 42, 6331, 10.1021/ma900845w Stankovich, 2006, Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate), J Mater Chem, 16, 155, 10.1039/B512799H Bourlinos, 2003, Graphite oxide: chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids, Langmuir, 19, 6050, 10.1021/la026525h Lomeda, 2008, Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets, J Am Chem Soc, 130, 16201, 10.1021/ja806499w Liu, 2008, One-step ionic-liquid-assisted electrochemical synthesis of ionic-liquid-functionalized graphene sheets directly from graphite, Adv Funct Mater, 18, 1518, 10.1002/adfm.200700797 Liu, 2010, Thermosensitive graphene nanocomposites formed using pyrene-terminal polymers made by RAFT polymerization, J Polym Sci Part A Polym Chem, 48, 425, 10.1002/pola.23802 1992, 408 Okazaki K, Nakagawa A, Sugii K. Composite filaments and fibers. US 3,558,419, 1971. Fukumoto T, Yano K, Iwamoto M. Polyether-ester amide and permanently antistatic resin composition. US 5,096,995, 1992. Finocchio, 2011, Hybrid organo-inorganic clay with nonionic interlayers. Mid- and near-IR spectroscopic studies, J Phys Chem A, 115, 7484, 10.1021/jp200845e Guegan, 2010, Intercalation of a nonionic surfactant (C10E3) bilayer into a Na-montmorillonite clay, Langmuir, 26, 19175, 10.1021/la1039267 Lin, 2007, Hydrogen-bond driven intercalation of synthetic fluorinated mica by poly(oxypropylene)-amidoamine salts, Colloids Surf A, 302, 162, 10.1016/j.colsurfa.2007.02.017 Lin, 2004, Novel mechanism for layered silicate clay intercalation by poly(propylene oxide)-segmented carboxylic acid, Macromol Rapid Commun, 25, 508, 10.1002/marc.200300076 Hu, 2011, Immobilization of ionic liquids in layered compounds via mechanochemical intercalation, J Phys Chem C, 115, 5509, 10.1021/jp111646d Ogawa, 1991, Intercalation of 2,2′-bipyridine and complex formation in the interlayer space of montmorillonite by solid–solid reactions, Inorg Chem, 30, 584, 10.1021/ic00003a050 Mako, 2009, Kaolinite-urea complexes obtained by mechanochemical and aqueous suspension techniques – a comparative study, J Colloid Interface Sci, 330, 367, 10.1016/j.jcis.2008.10.054 Ogawa, 1993, Photophysical probe study of alkylammonium-montmorillonites, Langmuir, 9, 1529, 10.1021/la00030a018 Choy, 2003, Solid–solid transformation mechanism for nanocrystalline sodalite from pillared clay, Chem Commun, 15, 1922, 10.1039/B304638A Lee, 2003, Nanocrystalline sodalite from Al2O3 pillared clay by solid–solid transformation, Chem Mater, 15, 4841, 10.1021/cm034614p Hemmen, 2012, X-ray studies of carbon dioxide intercalation in Na-fluorohectorite clay at near-ambient conditions, Langmuir, 28, 1678, 10.1021/la204164q Chiu, 2008, Exfoliation of smectite clays by branched polyamines consisting of multiple ionic sites, Eur Polym J, 44, 628, 10.1016/j.eurpolymj.2007.12.013 Liu, 2006, Synthesis, anion exchange, and delamination of Co–Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies, J Am Chem Soc, 128, 4872, 10.1021/ja0584471 Ma, 2010, Nanosheets of oxides and hydroxides: ultimate 2D charge-bearing functional crystallites, Adv Mater, 22, 5082, 10.1002/adma.201001722 Ma, 2008, Topochemical synthesis of monometallic (Co2+–Co3+) layered double hydroxide and its exfoliation into positively charged Co(OH)2 nanosheets, Angew Chem Int Ed, 47, 86, 10.1002/anie.200703941 Sasaki, 1996, Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. Pairwise association of nanosheets and dynamic reassembling process initiated from it, J Am Chem Soc, 118, 8329, 10.1021/ja960073b Wang, 2004, A new mesoporous manganese oxide pillared with double layers of alumina, Adv Mater, 16, 1412, 10.1002/adma.200306562 Dong, 2009, Synthesis of Mn-substituted Titania nanosheets and ferromagnetic thin films with controlled doping, Chem Mater, 21, 4366, 10.1021/cm900210m Ozawa, 2007, Preparation and characterization of the Eu3+ doped perovskite nanosheet phosphor: La0.90Eu0.05Nb2O7, Chem Mater, 19, 6575, 10.1021/cm702552p Liu, 2007, Synthesis and delamination of layered manganese oxide nanobelts, Chem Mater, 19, 6504, 10.1021/cm7019203 Li, 2005, Positively charged nanosheets derived via total delamination of layered double hydroxides, Chem Mater, 17, 4386, 10.1021/cm0510460 Hu, 2010, Exfoliation of layered europium hydroxide into unilamellar nanosheets, Chem Asian J, 5, 248, 10.1002/asia.200900475 Geng, 2010, Anion-exchangeable layered materials based on rare-earth phosphors: unique combination of rare-earth host and exchangeable anions, Acc Chem Res, 43, 1177, 10.1021/ar900289v Ozawa, 2009, Enhancement of host excitation-mediated photoluminescence and preferential quenching of direct photoactivator excitation-mediated photoluminescence by exfoliation of layered KLa0.90Sm0.05Nb2O7 into La0.90Sm0.05Nb2O7 nanosheets, J Phys Chem C, 113, 8735, 10.1021/jp900748e Ozawa, 2008, (K1.5Eu0.5)Ta3O10: a far-red luminescent nanosheet phosphor with the double perovskite structure, J Phys Chem C, 112, 17115, 10.1021/jp805545u Liu, 2007, General synthesis and delamination of highly crystalline transition-metal-bearing layered double hydroxides, Langmuir, 23, 861, 10.1021/la062345m Liang, 2010, Topochemical synthesis, anion exchange, and exfoliation of Co–Ni layered double hydroxides: a route to positively charged Co–Ni hydroxide nanosheets with tunable composition, Chem Mater, 22, 371, 10.1021/cm902787u Ma, 2007, Synthesis and exfoliation of Co2+–Fe3+ layered double hydroxides: an innovative topochemical approach, J Am Chem Soc, 129, 5257, 10.1021/ja0693035 Ida, 2008, Synthesis of hexagonal nickel hydroxide nanosheets by exfoliation of layered nickel hydroxide intercalated with dodecyl sulfate ions, J Am Chem Soc, 130, 14038, 10.1021/ja804397n Naik, 2011, Neutral nanosheets that gel: exfoliated layered double hydroxides in toluene, J Phys Chem Lett, 2, 1193, 10.1021/jz2004655 Mochizuki, 2005, Molecular manipulation of two- and three-dimensional silica nanostructures by alkoxysilylation of a layered silicate octosilicate and subsequent hydrolysis of alkoxy groups, J Am Chem Soc, 127, 7183, 10.1021/ja042194e Mochizuki, 2006, Synthesis of microporous inorganic-organic hybrids from layered octosilicate by silylation with 1,4-bis(trichloro- and dichloromethyl-silyl)benzenes, Chem Mater, 18, 5223, 10.1021/cm061357q Takahashi, 2011, Exfoliation of layered silicates through immobilization of imidazolium groups, Chem Mater, 23, 266, 10.1021/cm102942s Laufer, 2012, Clay–chitosan nanobrick walls: completely renewable gas barrier and flame-retardant nanocoatings, ACS Appl Mater Interfaces, 4, 1643, 10.1021/am2017915 Pack, 2010, Role of surface interactions in the synergizing polymer/clay flame retardant properties, Macromolecules, 43, 5338, 10.1021/ma100669g Li, 2010, Flame retardant behavior of polyelectrolyte clay thin film assemblies on cotton fabric, ACS Nano, 4, 3325, 10.1021/nn100467e