Interactive behavior of cadmium ions onto polyethylene microplastics in aquatic system

D. M. Reddy Prasad1, B. S. Naveen Prasad2, R. Senthilkumar3, K. Saravana Kumar3, S. Manickkam4
1Petroleum and Chemical Engineering Programme Area, Faculty of Engineering, Universiti Teknologi Brunei, Tungku Highway, Gadong, Brunei Darussalam
2Department of Engineering, University of Technology and Applied Sciences, Salalah, Sultanate of Oman
3Department of Engineering, University of Technology and Applied Sciences, Suhar, Sultanate of Oman
4Department of Chemical Engineering, Higher Colleges of Technology, Ruwais Women’s College, Abu Dhabi, United Arab Emirates

Tóm tắt

Microplastics and heavy metals are two different classes of pollutants that are often present in aquatic systems. However, the interaction between these two pollutants is poorly understood in freshwater systems. This research has examined the sorption of cadmium(II) ions onto polyethylene microplastic (PEMP) under freshwater conditions. The scanning electron microscope, X-ray diffraction, and Fourier transform infrared analyses confirmed the existence of different functional groups and the porous nature of the PEMP surface. The influences of physicochemical parameters such as the solution pH, contact time, and initial Cd(II) concentration have been examined. The Langmuir isotherm predicted the Cd(II) sorption capacity by PEMP at pH 5 as 1.37 mg/g. Several isotherm models were utilized, including the Freundlich, Langmuir, and Sips models. The results confirmed that the Sips model has been more appropriate for Cd(II)-PEMP isotherm based on percentage errors and correlation coefficient values. Furthermore, the pseudo-first kinetic model fitted Cd(II)-PEMP more accurately than the pseudo-second kinetic equation. Desorption experiments were conducted to release Cd(II) ions from Cd(II)-bearing PEMP using different chemical agents. The findings showed that using 0.01 M nitric acid resulted in a desorption efficiency exceeding 99.8%. This demonstrates that microplastics loaded with Cd(II) may release Cd(II) ions in highly acidic environments, potentially allowing for the uptake of Cd(II) ions by aquatic organisms in their digestive tracts.

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