Inorganic benzenes as the noncovalent interaction donor: a study of the π-hole interactions

Journal of Molecular Modeling - Tập 23 Số 12 - Trang 1-9 - 2017
Chu, Runtian1, Zhang, Xueying1, Meng, Lingpeng1, Zeng, Yanli1,2
1Institute of Computational Quantum Chemistry, College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, People’s Republic of China
2National Demonstration Center for Experimental Chemistry Education, Hebei Normal University, Shijiazhuang, People’s Republic of China

Tóm tắt

For inorganic benzenes C3N3X3 and B3O3X3 (X = H, F, CN), the positive electrostatic potentials (π-hole) were discovered above and below the inorganic benzene ring center. Then, the π-hole interactions between the inorganic benzenes and NCH have been designed and investigated by MP2/aug-cc-pVDZ calculations. In this paper, the termolecular complexes B3O3X3···NCH···NCH, C3N3X3···NCH···NCH (X = H, F, CN) were also designed to illustrate the enhancing effects of the H···N hydrogen bond on the π-hole interactions. The π-hole interaction energy was influenced by the strength of different electron-withdrawing substituents of inorganic benzenes, gradually increasing in the order of X = H, F, CN. What’s more, the π electron densities account for 71~88% of the total electron densities, indicating the strength of interaction energy is mainly determined by π-type electron densities.

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