Innovative Poly(Butylene Terephthalate) Based Nanocomposites: a Preliminary Investigation

Macromolecular Symposia - Tập 247 Số 1 - Trang 120-128 - 2007
Domenico Acierno1, Eugenio Amendola2, G. Callegaro1, G. Napolitano2
1Department of Materials and Production Engineering, University of Naples `Federico II', P.le Tecchio 80, 80125 Naples, Italy
2Institute of Composite and Biomedical Materials, CNR ‐ Italy's National Council of Research, P.le E. Fermi 1, 80055 Portici (Na) Italy

Tóm tắt

AbstractA polymer‐clay nanocomposite based on Poly(butyleneterephthalate) (PBT) and an innovative organoclay has been synthesized via intercalation of Bis(hydroxyethyl terephthalate) (BHET) in Na‐Montmorillonite layers. Chemical and physical properties of this nanocomposite have been studied in comparison to other PBT/nanocomposites based on two commercial organoclay: Cloisite 25A and Somasif MEE. Nanocomposites have been prepared via melt compounding using a twin‐screw extruder, with extrusion rate of 150 rpm. Samples were characterized by using wide‐angle X‐ray diffraction, TEM, thermal and mechanical analysis.

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10.1016/S0169-1317(99)00017-4

10.1016/S0169-1317(99)00013-7

10.1007/3-540-44473-4_3

10.1002/(SICI)1099-0739(199810/11)12:10/11<675::AID-AOC779>3.0.CO;2-V

10.1021/ma0013657

10.1021/ma010780b

10.1002/pola.1995.080330707

10.1002/1099-1018(200007/08)24:4<201::AID-FAM739>3.0.CO;2-D

10.1021/cm0001760

10.1016/S0927-796X(00)00012-7

10.1002/pen.10918

10.1007/BF00360767

10.1002/adma.19960080104

10.1021/cm00030a019

10.1021/cm960102h

10.1002/1521-3927(20011101)22:16<1306::AID-MARC1306>3.0.CO;2-I

10.1021/cm010305s

10.1002/pen.20094

10.1021/cm010451y

10.1007/s00289-002-0072-5

10.1002/polb.10331