Initial kinetics of reactive spreading in metal systems with different interactions between components
Tóm tắt
The paper analyzes results on the initial spreading kinetics in binary metal systems, including those that involve the formation of intermediate phases and mass transfer through the interface. The drop flowing technique is used to study the effect of temperature, drop mass, and mutual saturation of the melt and solid substrate in binary systems of copper and tin with iron, cobalt, and nickel and also of tin with Ni3Sn and Ni3Sn2 intermetallics on the spreading rate. The proposed formal kinetic analysis of the spreading process using exponential time dependences for the motion of the three-phase boundary and for the difference between cosines of quasiequilibrium and dynamic contact angles permits satisfactory description of spreading in nonsteady-state conditions for the initial stages of the process and determination of its modes. The nature of phase interaction corresponds to phase equilibria in the studied systems with tin.
Tài liệu tham khảo
É. A. Raud, B. D. Summ, and E. D. Shchukin, “Spreading of Newtonian liquid over a solid,“ Dokl. AN SSSR, 205, No. 5, 1134–1137 (1972).
B. D. Summ and Yu. V. Goryunov, Physics and Chemistry of Wetting and Spreading [in Russian], Khimiya, Moscow (1976), p. 232.
A. I. Bykhovskyi, Spreading [in Russian], Naukova Dumka, Kiev (1983), p. 192.
V. N. Eremenko and N. D. Lesnik, “Spreading kinetics of molten metals on solids and structure of the transition zone at their contact,” in: Physical Chemistry of Inorganic Materials, Vol. 3: Physical Chemistry of Interaction between Molten Metals and Materials [in Russian], Naukova Dumka, Kiev (1988), pp. 7–50.
S. O. Popel’, Surface Phenomena in Melts [in Russian], Metallurgiya, Moscow (1994), p. 440.
T. B. Massalski, J. Z. Murray, L. H. Bennett, and H. Baker (eds.), Binary Alloy Phase Diagrams, Vol. 1–2, Metal Park, ASM, Ohio (1986), p. 2224.
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Effect of temperature and mass of the melt on the kinetics of spreading of tin on cobalt,” Powder Metall. Met. Ceram., 28, No. 6, 452–457 (1989).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Studying the spread of tin on cobalt,” Adgez. Raspl. Paika Mater., Issue 11, 33–36 (1983).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Effect of chemical interaction on the kinetics of spreading of tin on nickel and its stannides,” in: Capillary and Adhesion Properties of Melts [in Russian], Naukova Dumka, Kiev (1987), p. 30.
V. N. Eremenko, N. D. Lesnik, and L. I. Kostrova, “Kinetic patterns of spreading of tin on iron in drop flowing to the upper plate,” Adgez. Raspl. Paika Mater., Issue 18, 28–32 (1987).
V. N. Eremenko, N. D. Lesnik, L. I. Kostrova, and P. A. Verkhovodov, “Contact interaction in tin–iron family metals,” Ukr. Khim. Zh., 51, No. 11, 1132–1136 (1985).
V. N. Eremenko, N. D. Lesnik, L. I. Kostrova, and P. A. Verkhovodov, “Contact reactions during the spreading of tin on nickel and its stannides,” Powder Metall. Met. Ceram., 24, No. 3, 203–206 (1985).
S. Newman, “Kinetics of wetting by polymers: capillary flow,” J. Colloid Interface Sci., 26, 209–213 (1968).
B. V. Cherry and C. M. Holmes, “Kinetics of wetting of surfaces by polymers,” J. Colloid Interface Sci., 29, 174–176 (1969).
G. A. Grigor’ev, V. L. Lapin, V. S. Beleevskii, et al., “On application of the dimensional theory to describe the kinetics of wetting of solids by liquids,” in: Wetting and Surface Properties of Melts and Solids [in Russian], Naukova Dumka, Kiev (1972), pp. 80–83.
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetic laws of spreading during the initial stages in metallic systems differing in the character of interaction of the components II. Effect of physicochemical parameters on the kinetics of spreading. Formal-kinetic analysis of spreading,” Powder Metall. Met. Ceram., 37, No. 3–4, 187–192 (1998).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetics of spreading in initial stages in metallic systems with different types of interaction between components. IV. Effect of chemical reaction on the kinetics of spreading in tin—Iron group metal systems,” Powder Metall. Met. Ceram., 37, No. 7–8, 400–406 (1998).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Effect of mutual solubility of contacting phases on the kinetics of spreading in the iron–copper system,” Adgez. Raspl. Paika Mater., Issue 28, 12–17 (1992).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetics of spreading in systems with complete and limited solid-state solubility of components,” Adgez. Raspl. Paika Mater., Issue 28, 17–22 (1992).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetic laws of spreading in binary systems of tin and copper with iron,” Adgez. Raspl. Paika Mater., Issue 29, 23–28 (1993).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetic laws of spreading during the initial stages in metallic systems with different types of interactions among the components. I. Methodological aspects of studying the initial stage of spreading,” Powder Metall. Met. Ceram., 36, No. 11–12, 621–625 (1997).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetic laws of spreading during the initial stages in metallic systems with different types of component interactions. III. Effect of mutual saturation on spreading kinetics in copper—Iron-family-metal systems,” Powder Metall. Met. Ceram., 37, No. 5–6, 302–306 (1998).
V. N. Eremenko, L. I. Kostrova, and N. D. Lesnik, “Kinetics of reactive spreading in metallic systems with different characters of interaction between components,” in: N. Eustathopoulos (ed.), Proc. Int. Conf. High Temperature Capillarity, Bratislava (1995), pp. 113–117.
L. I. Kostrova and N. D. Lesnik, “Chemical interaction at the initial stages of spreading,” in: A. Bellosi (ed.), Proc. NATO ARW on Interfacial Science in Ceramic Joining, Kluwer Academic Publisher, Holland (1998), pp. 69–79.