Influence of Spin-Orbit Coupling on Electronic Structure of Polyyne and Cumulene Carbynes

Springer Science and Business Media LLC - Tập 1 - Trang 1353-1357 - 2016
Sergey Karabanov1, Pavel Dyachkov1, Dmitry Suvorov1, Gennady Gololobov1, Dmitry Tarabrin1, Evgeny Slivkin1
1Ryazan State Radio Engineering University, Ryazan, Russia

Tóm tắt

The present paper has suggested a new non-observational method to calculate electronic structure of carbynes taking into consideration the influence of the spin-orbital coupling. The method is demonstrated by calculations of the structure splitting at the Fermi level in cumulene and polyyne carbynes having semiconductor and metallic electronic structure correspondingly. These couplings result in 2 - 3 meV gaps.

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