Influence of Soft Phase and Carbon Nanotube Content on the Properties of Hierarchical AZ61 Matrix Composite with Isolated Soft Phase

Nanomaterials - Tập 12 Số 16 - Trang 2877
Yunpeng Ding1, Sijia Jiao1, Yizhuang Zhang1, Zhiai Shi1, Jinbiao Hu1, Xulei Wang1, Zhiyuan Li1, Hanying Wang1, Xiaoqin Guo1
1School of Materials, Zhengzhou University of Aeronautics, Zhengzhou 450046, China

Tóm tắt

Carbon nanotube-reinforced magnesium matrix (CNTs/Mg) composite has great application potential in the transportation industry, but the trade-off between strength and ductility inhibits its widespread application. In order to balance the strength and plasticity of the composite, in this work, on the basis of the AZ61 matrix composite homogeneously reinforced by Ni-coated CNTs (hard phase), 30 vol.% large-size AZ61 particles are introduced as an isolated soft phase to fabricate hierarchical CNTs/AZ61 composites. The compression tests show the fracture strain and compressive strength of this composite increases by 54% and 8%, respectively, compared with homogeneous CNTs/AZ61 composite. During deformation, the hard phase is mainly responsible for bearing the load and bringing high strength, due to the precipitation of the Mg17Al12 phase, uniformly dispersed CNT and strong interfacial bonding of the CNTs/Mg interface through nickel plating and interfacial chemical reaction. Furthermore, the toughening of the soft phase results in high ductility. With the increase in CNT content, the compressive strength of composites is nearly unchanged but the fracture strain gradually decreases due to the stress concentration of CNT and its agglomeration.

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Tài liệu tham khảo

Hou, 2020, Combination of enhanced thermal conductivity and strength of MWCNTs reinforced Mg-6Zn matrix composite, J. Alloys Compd., 838, 155573, 10.1016/j.jallcom.2020.155573

Abazari, 2022, Functionalized carbon nanotube-encapsulated magnesium-based nanocomposites with outstanding mechanical and biological properties as load-bearing bone implants, Mater. Des., 213, 110354, 10.1016/j.matdes.2021.110354

Hou, 2019, Significantly enhancing the strength + ductility combination of Mg-9Al alloy using multi-walled carbon nanotubes, J. Alloys Compd., 790, 974, 10.1016/j.jallcom.2019.03.243

Shirasu, 2019, How do the mechanical properties of carbon nanotubes increase? An experimental evaluation and modeling of the engineering tensile strength of individual carbon nanotubes, Mater. Res. Express, 6, 55047, 10.1088/2053-1591/ab069f

Ding, Y., Shi, Z., Li, Z., Jiao, S., Hu, J., Wang, X., Zhang, Y., Wang, H., and Guo, X. (2022). Effect of CNT Content on Microstructure and Properties of CNTs/Refined-AZ61 Magnesium Matrix Composites. Nanomaterials, 12.

Luo, 2022, Evading strength and ductility trade-off in an inverse nacre structured magnesium matrix nanocomposite, Acta Mater., 228, 117730, 10.1016/j.actamat.2022.117730

Xiang, 2019, Achieving ultra-high strengthening and toughening efficiency in carbon nanotubes/magnesium composites via constructing micro-nano layered structure, Compos. Part. A-Appl. S., 119, 225, 10.1016/j.compositesa.2019.02.006

Liu, 2015, High performance heterogeneous magnesium-based nanocomposite, Mater. Lett., 143, 287, 10.1016/j.matlet.2014.12.099

Ding, 2020, High performance carbon nanotube-reinforced magnesium nanocomposite, Mat. Sci. Eng. A, 771, 1, 10.1016/j.msea.2019.138575

Suryanarayana, 2006, Mechanical alloying and milling, Prog. Mater. Sci., 46, 1, 10.1016/S0079-6425(99)00010-9

Miao, 2018, Interphase boundary segregation of silver and enhanced precipitation of Mg17Al12 Phase in a Mg-Al-Sn-Ag alloy, Scripta Mater., 154, 192, 10.1016/j.scriptamat.2018.05.047

Varin, 2003, The effect of MgNi2 intermetallic compound on nanostructurization and amorphization of Mg–Ni alloys processed by controlled mechanical milling, J. Alloys Compd., 354, 281, 10.1016/S0925-8388(03)00016-1

Wu, 2018, Synergistic effect of carbon nanotube and graphene nanoplatelet addition on microstructure and mechanical properties of AZ31 prepared using hot-pressing sintering, J. Mater. Res., 33, 4261, 10.1557/jmr.2018.421

Habibi, 2011, Enhanced compressive response of hybrid Mg-CNT nano-composites, J. Mater. Sci., 46, 4588, 10.1007/s10853-011-5358-2

Rashad, 2014, Synergetic effect of graphene nanoplatelets (GNPs) and multi-walled carbon nanotube (MW-CNTs) on mechanical properties of pure magnesium, J. Alloys Compd., 603, 111, 10.1016/j.jallcom.2014.03.038

Ng, 2010, Influence of fibre taper on the work of fibre pull-out in short fibre composite fracture, J. Mater. Sci., 45, 1086, 10.1007/s10853-009-4050-2

Huq, 2008, On defect interactions in axially loaded single-walled carbon nanotubes, J. Appl. Phys., 103, 1624, 10.1063/1.2837835

Huq, 2010, Defect-defect interaction in single-walled carbon nanotubes under torsional loading, Int. J. Mod. Phys. B, 24, 1215, 10.1142/S021797921005510X

Luo, 2021, Heterogeneous magnesium matrix nanocomposites with high bending strength and fracture toughness, J. Alloys Compd., 855, 157359, 10.1016/j.jallcom.2020.157359

Hassan, 2006, Effect of particulate size of Al2O3 reinforcement on microstructure and mechanical behavior of solidification processed elemental Mg, J. Alloys Compd., 419, 84, 10.1016/j.jallcom.2005.10.005

Paramsothy, 2011, Addition of CNTs to enhance tensile/compressive response of magnesium alloy ZK60A, Compos. Part A-Appl. S, 42, 180, 10.1016/j.compositesa.2010.11.001