Kết hợp cặp acid–base dựa trên polyoxometalat vào MIL-101 sulfonat nhằm đạt được vật liệu dẫn proton với độ dẫn proton cao và độ ổn định cao

Ye YX, Guo WG, Wang LH, Li ZY, Song ZJ, Chen J, Zhang ZJ, Xiang SC, Chen BL. Straightforward loading of imidazole molecules into metal-organic framework for high proton conduction. J Am Chem Soc. 2017;139(44):15604. Gui DX, Dai X, Tao Z, Zheng T, Wang XX, Silver M, Shu J, Chen LH, Wang YL, Zhang TT, Xie J, Zou L, Xia YH, Zhang JJ, Zhang J, Zhao L, Juan DW, Zhou RH, Chai ZF, Wang S. Unique proton transportation pathway in a robust inorganic coordination polymer leading to intrinsically high and sustainable anhydrous proton conductivity. J Am Chem Soc. 2018;140(19):6146. Mauritz K, Moore R. State of understanding of nafion. Chem Rev. 2004;104:4535. Wang Y, Chen K, Mishler J, Cho S, Adroher X. A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research. Appl Energy. 2011;88(4):981. Liu WJ, Dong LZ, Li RH, Chen YJ, Sun SN, Li SL, Lan YQ. Different protonic species affecting proton conductivity in hollow spherelike polyoxometalates. ACS Appl Mater Interfaces. 2019;11(7):7030. Si C, Ma PT, Han QX, Jiao JC, Du W, Wu JP, Li MX, Niu JY. A polyoxometalate-based inorganic porous material with both proton and electron conductivity by light actuation: photocatalysis for baeyer-villiger oxidation and Cr(VI) reduction. Inorg Chem. 2021;60(2):682. Ma PT, Wan R, Wang YY, Hu F, Zhang DD, Niu JY, Wang JP. Coordination-driven self-assembly of a 2D graphite-like framework constructed from high-nuclear Ce10 cluster encapsulated polyoxotungstates. Inorg Chem. 2016;55(2):918. Dolbecq A, Dumas E, Mayer C, Mialane P. Hybrid organic−inorganic polyoxometalate compounds: from structural diversity to applications. Chem Rev. 2010;110:6009. Nakamura O, Kodama T, Ogino I, Miyake Y. High-conductivity solid proton conductors: dodecamolybdophosphoric acid and dodecatungstophosphoric acid crystals. Chem Lett. 1979;8:17. Du DY, Qin JS, Li SL, Su ZM, Lan YQ. Recent advances in porous polyoxometalate-based metal-organic framework materials. Chem Soc Rev. 2014;43(13):4615. Liu YW, Yang X, Miao J, Tang Q, Liu SM, Shi Z, Liu SX. Polyoxometalate-functionalized metal-organic frameworks with improved water retention and uniform proton-conducting pathways in three orthogonal directions. Chem Commun. 2014;50(70):10023. Dey C, Kundu T, Banerjee R. Reversible phase transformation in proton conducting Strandberg-type POM based metal organic material. Chem Commun. 2012;48(2):266. Qi W, Wu LX. Polyoxometalate/polymer hybrid materials: fabrication and properties. Polym Int. 2009;58(11):1217. Song YF, Tsunashima R. Recent advances on polyoxometalate-based molecular and composite materials. Chem Soc Rev. 2012;41(22):7384. Wu HR, Li LW, Tsuboi M, Cheng YQ, Wang WY, Mamontov E, Uchida S, Wang Z, Yin PC. Spatial-temporal characteristics of confined polymer motion determine proton conduction of polyoxometalate-poly (ethylene glycol) hybrid nanocomposites. J Phys Chem Lett. 2018;9(19):5772. Sun XW, Liu SM, Zhang S, Dang TY, Tian HR, Lu Y, Liu SX. High proton conductivity achieved by the self-assembly of pom-based acid–base adduct in sba-15 over a wide range from −40 to 85 oC. ACS Appl Energy Mater. 2020;3(1):1242. Ma HP, Liu BL, Li B, Zhang LM, Li YG, Tan HQ, Zang HY, Zhu GS. Cationic covalent organic frameworks: a simple platform of anionic exchange for porosity tuning and proton conduction. J Am Chem Soc. 2016;138(18):5897. Cao XL, Xie SL, Li SL, Dong LZ, Liu J, Liu XX, Wang WB, Su ZM, Guan W, Lan YQ. A well-established pom-based single-crystal proton-conducting model incorporating multiple weak interactions. Chem Eur J. 2018;24:2365. Kim A, Park C, Vinothkannan M, Yoo D. Sulfonated poly ether sulfone/heteropoly acid composite membranes as electrolytes for the improved power generation of proton exchange membrane fuel cells. Compos B Eng. 2018;155:272. Zhang S, Lu Y, Sun XW, Li Z, Dang TY, Zhang Z, Tian HR, Liu SX. Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction. Chem Commun. 2020;56(3):391. Wu L, Yang YS, Ye YX, Yu ZJ, Song ZJ, Chen SM, Chen LJ, Zhang ZJ, Xiang SC. Loading acid–base pairs into periodic mesoporous organosilica for high anhydrous proton conductivity over a wide operating temperature window. ACS Appl Energy Mater. 2018;1(9):5068. Vinothkannan M, Hariprasad R, Ramakrishnan S, Kim A, Yoo D. Potential bifunctional filler (CeO2–ACNTs) for nafion matrix toward extended electrochemical power density and durability in proton-exchange membrane fuel cells operating at reduced relative humidity. ACS Sustain Chem Eng. 2019;7(15):12847. Kim A, Vinothkannan M, Song M, Lee J, Lee H, Yoo D. Amine functionalized carbon nanotube (ACNT) filled in sulfonated poly(ether ether ketone) membrane: effects of ACNT in improving polymer electrolyte fuel cell performance under reduced relative humidity. Compos Part B Eng. 2020;188:107890. Ferey G, Draznieks C, Serre C, Millange F, Dutour J, Surble S, Margiolaki I. A chromium terephthalate–based solid with unusually large pore volumes and surface area. Science. 2005;309:2040. Akiyama G, Matsuda R, Sato H, Takata M, Kitagawa S. Cellulose hydrolysis by a new porous coordination polymer decorated with sulfonic acid functional groups. Adv Mater. 2011;23(29):3294. Zhang FM, Dong LZ, Qin JS, Guan W, Liu J, Li SL, Lu M, Lan YQ, Su ZM, Zhou HC. Effect of imidazole arrangements on proton-conductivity in metal-organic frameworks. J Am Chem Soc. 2017;139(17):6183. Lai XY, Liu YW, Yang GC, Liu SM, Shi Z, Lu Y, Luo F, Liu SX. Controllable proton-conducting pathways via situating polyoxometalates in targeting pores of a metal–organic framework. J Mater Chem A. 2017;5(20):9611. Hwang Y, Hong DY, Chang JS, Jhung S, Seo Y, Kim J, Vimont A, Daturi M, Serre C, Ferey G. Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem Int Ed. 2008;47(22):4144. Sun JM, Abednatanzi S, Chen H, Liu YY, Leus K, Van P. Bifunctional noble-metal-free catalyst for the selective aerobic oxidation-knoevenagel one-pot reaction: encapsulation of polyoxometalates into an alkylamine-modified MIL-101 framework. ACS Appl Mater Interfaces. 2021;13(20):23558. Li XM, Liu J, Zhao C, Zhou JL, Zhao L, Li SL, Lan YQ. Strategic hierarchical improvement of superprotonic conductivity in a stable metal–organic framework system. J Mater Chem A. 2019;7(43):25165. Wang SJ, Wahiduzzaman M, Davis L, Tissot A, Shepard W, Marrot J, Corcos C, Hamdane D, Maurin G, Vinot S, Serre C. A robust zirconium amino acid metal-organic framework for proton conduction. Nat Commun. 2018;9(1):4937. Lin LD, Li Z, Zhao D, Liu JH, Li XX, Zheng ST. Development of a new Lindqvist-like Fe6 cluster secondary building unit for MOFs. Chem Commun. 2019;55(72):10729. Zhai QG, Mao CY, Zhao X, Lin QP, Bu F, Chen XT, Bu XH, Feng PY. Cooperative crystallization of heterometallic indium-chromium metal-organic polyhedra and their fast proton conductivity. Angew Chem Int Ed. 2015;54(27):7886. Hwang S, Lee E, Song D, Jeong N. High proton mobility with high directionality in isolated channels of MOF-74. ACS Appl Mater Interfaces. 2018;10(41):35354. Li R, Wang SH, Chen XX, Lu J, Fu ZH, Li Y, Xu G, Zheng FK, Guo GC. Highly anisotropic and water molecule-dependent proton conductivity in a 2D homochiral copper(ii) metal–organic framework. Chem Mater. 2017;29(5):2321.