In-situ sulfur isotope and trace element of pyrite constraints on the formation and evolution of the Nibao Carlin-type gold deposit in SW China
Tóm tắt
The fault-controlled Nibao Carlin-type gold deposit, together with the strata-bound Shuiyindong deposit, comprise a significant amount of the disseminated gold deposits in southwestern Guizhou Province, China. Five main types and two sub-types of pyrite at the Nibao deposit (Py1a/Py1b, Py2, Py3, Py4, Py5) were distinguished based on detailed mineralogical work. Py1, Py2 and Py3 are Au-poor, whereas Py4 and Py5 are Au-rich, corresponding to a sedimentary and hydrothermal origin, respectively. Through systematic in situ analyses of NanoSIMS sulfur isotopes, the framboid pyrite Py1a with negative δ34S values (− 53.3 to − 14.9‰) from the Nibao deposit were found to originate from bacterial sulfate reduction (BSR) processes in an open and sulfate-sufficient condition while the superheavy pyrite Py1b (73.7–114.8‰) is probably due to the potential influence of closed-system Rayleigh fractionation or the lack of preservation of deep-sea sediments. Data of Py2 and Py3 plot within the area of S isotope compositions from biogenic and abiogenic sulfate reduction. In view of few coeval magmatic rocks in the mining district, the near zero δ34S values of the Au-rich pyrites (Py4 and Py5) may discount the potential involvement of magmatic but metamorphic or sedimentary origin. LA-ICP-MS and TEM work show that Au in ore-related pyrite is present as both nanoparticles and structurally bound. LA-ICP-MS analyses show that the Au-rich pyrite also contains higher As, Cu, Sb, Tl and S than other types of pyrite, which inferred a distal manifestation of deep hydrothermal mineralization systems.
Tài liệu tham khảo
Arehart GB (1996) Characteristics and origin of sediment-hosted disseminated gold deposits: a review. Ore Geol Rev 11:383–403
Ashley RP, Cunningham CG, Bostick NH, Dean WE, Chou IM (1991) Geology and geochemistry of three sedimentary-rock-hosted disseminated gold deposits in Guizhou Province, People’s Republic of China. Ore Geol Rev 6:133–151
Barrie CD, Boyce AJ, Boyle AP, Williams PJ, Blake K, Ogawara T, Akai J, Prior DJ (2009) Growth controls in colloform pyrite. Am Miner 94:415–429
Canfield DE, Farquhar J, Zerkle AL (2010) High isotope fractionations during sulfate reduction in a low-sulfate euxinic ocean analog. Geology 38:415–418
Chang ZS, Large RR, Maslennikov V (2008) Sulfur isotopes in sediment-hosted orogenic gold deposits: evidence for an early timing and a seawater sulfur source. Geology 36:971–974
Chen MH, Mao JW, Chen ZY, Zhang W (2009a) Mineralogy of arsenian pyrites and arsenopyrites of Carlin-type gold deposits in Yunnan–Guizhou–Guangxi “golden triangle’’ area, southwestern China. Miner Deposit 28:539–557 (in Chinese with English abstract)
Chen YJ, Zhai MG, Jiang SY (2009b) Significant achievements and open issues in study of orogenesis and metallogenesis surrounding the North China continent. Acta Petrol Sin 25:2695–2726
Chen MH, Lu G, Li XH (2012) Muscovite 40Ar/39Ar Dating of the Quartz Porphyry Veins from Northwest Guangxi, China, and its geological significance. Geol J China Univ 18(1):106–116 (in Chinese with English abstract)
Chen SW, Sun J, Fu B, Nie AG (2013) Geochemical characteristics of ore-bearing rock series in the Nibao gold deposit, SW Guizhou. Bull Mineral Petrol Geochem 32:591–598
Chen MH, Mao JW, Li C, Zhang ZQ, Dang Y (2015a) Re–Os isochron ages for arsenopyrite from Carlin-like gold deposits in the Yunnan–Guizhou–Guangxi “golden triangle”, southwestern China. Ore Geol Rev 64:316–327
Chen MH, Zhang ZQ, Santosh M, Dang Y, Zhang W (2015b) The Carlin-type gold deposits of the “golden triangle” of SW China: Pb and S isotopic constraints for the ore genesis. J Asian Earth Sci 103:115–128
Chen J, Yang RD, Du LJ, Zheng LL, Gao JB, Lai CK, Wei HR, Yuan MG (2018) Mineralogy, geochemistry and fluid inclusions of the Qinglong Sb-(Au) deposit, Youjiang basin (Guizhou, SW China). Ore Geol Rev 92:1–18
Chen MH, Bagas L, Liao X, Zhang ZQ, Li QL (2019) Hydrothermal apatite SIMS Th-Pb dating: constraints on the timing of low-temperature hydrothermal Au deposits in Nibao, SW China. Lithos 324–325:418–428
Ciobanu CL, Cook NJ, Utsunomiya S, Pring A, Green L (2011) Focussed ion beam–transmission electron microscopy applications in ore mineralogy: bridging micro- and nanoscale observations. Ore Geol Rev 42(1):6–31
Cline JS, Muntean JL, Gu XX, Xia Y (2013) A comparison of Carlin-type gold deposits: Guizhou Province, golden triangle, southwest China, and northern Nevada, USA. Front Earth Sci 20:1–18
Deditius AP, Utsunomiya S, Renock D, Ewing RC, Ramana CV, Becker U, Kesler SE (2008) A proposed new type of arsenian pyrite: composition, nanostructure and geological significance. Geochim Cosmochim Acta 72:2919–2933
Deditius AP, Utsunomiya S, Reich M, Kesler SE, Ewing RC, Hough R, Walshe J (2011) Trace metal nanoparticles in pyrite. Ore Geol Rev 42(1):32–46
England BM, Ostwald J (1993) Framboid-derived structures in some Tasman fold belt base metal sulphide deposits, New-South-Wales, Australia. Ore Geol Rev 7:381–412
George LL, Biagioni C, D’Orazio M, Cook NJ (2018) Textural and trace element evolution of pyrite during greenschist facies metamorphic recrystallization in the southern Apuan Alps (Tuscany, Italy): influence on the formation of Tl-rich sulfosalt melt. Ore Geol Rev 102:59–105
Grant HLJ, Hannington MD, Petersen S, Frische M, Fuchs SH (2018) Constraints on the behavior of trace elements in the actively-forming TAG deposit, Mid-Atlantic Ridge, based on LA-ICP-MS analyses of pyrite. Chem Geol 498:45–71
Hofstra AH, Cline JS (2000) Characteristics and models for Carlin-type gold deposits. Rev Econ Geol 13:163–220
Hofstra AH, Zhang XC, Emsbo P, Hu RZ, Su WC, Christiansen WD, Fu SH (2005) Source of ore fluids in Carlin-type gold deposits in the Dian-Qian-Gui area and West Qinling belt, PR China: implications for genetic models. In: Mineral deposit research: meeting the global challenge. Springer, Berlin, pp 533–536
Hou L, Peng HJ, Ding J, Zhang JR, Zhu SB, Wu SY et al (2016) Textures and in situ chemical and isotopic analyses of pyrite, Huijiabao trend, Youjiang basin, China: implications for paragenesis and source of sulfur. Econ Geol 111:331–353
Hu RZ, Zhou MF (2012) Multiple Mesozoic mineralization events in South China-an introduction to the thematic issue. Miner Depos 47:579–588
Hu RZ, Su WC, Bi XW, Tu GZ, Hofstra AH (2002) Geology and geochemistry of Carlin-type gold deposits in China. Miner Depos 37:378–392
Hu RZ, Fu SL, Huang Y, Zhou MF, Fu SH, Zhao CH et al (2017a) The giant South China Mesozoic low-temperature metallogenic domain: reviews and a new geodynamic model. J Asian Earth Sci 137:9–34
Hu RZ, Chen WT, Xu DR, Zhou MF (2017b) Reviews and new metallogenic models of mineral deposits in South China: an introduction. J Asian Earth Sci 137:1–8
Hu XL, Gong YJ, Zeng GP, Zhang ZJ, Wang J, Yao SZ (2018) Multistage pyrite in the Getang sediment-hosted disseminated gold deposit, southwestern Guizhou Province, China: insights from textures and in situ chemical and sulfur isotopic analyses. Ore Geol Rev 99:1–16
Jin XY (2017) Geology, mineralization and genesis of the Nibao, Shuiyindong and Yata gold deposits in SW Guizhou Province, China. Ph.D. thesis, China University of Geosciences, Wuhan, China (in Chinese with English abstract)
Kovalev KR, Kalinin YA, Naumov EA, Pirajno F, Borisenko AS (2009) A mineralogical study of the Suzdal sediment-hosted gold deposit, Eastern Kazakhstan: implications for ore genesis. Ore Geol Rev 35:186–205
Large DJ, Fortey NJ, Milodowski AE, Christy AG, Dodd J (2001) Petrographic observations of iron, copper, and zinc sulfides in freshwater canal sediment. J Sediment Res 71(1):61–69
Large RR, Maslennikov VV, Robert F, Danyushevsky LV, Chang ZS (2007) Multistage sedimentary and metamorphic origin of pyrite and gold in the giant Sukhoi log deposit, Lena gold province, Russia. Econ Geol 7:1233–1267
Li HB, Zeng FZ (2005) The pyrite’s typomorphic characteristics in gold deposit. Contrib Geol Miner Resour Res 20:199–203 (in Chinese with English abstract)
Li YN, Li Y, Liu SR, Tang Y, Mo B, Liao H (2018) New zonal structure and transition of the membrane to mammillae in the eggshell of chicken Gallus domesticus. J Struct Biol 203:162–169
Liang JL, Sun WD, Zhu SY, Li H, Liu YL, Zhai W (2014) Mineralogical study of sediment-hosted gold deposits in the Yangshan ore field, Western Qinling Orogen, Central China. J Asian Earth Sci 85:40–52
Liu JZ, Liu CQ (2005) Origin and metallogenic model for Shuiyindong gold deposit of Guizhou. Guizhou Geol 22:9–13 (in Chinese with English abstract)
Liu JZ, Deng YM, Liu CQ, Xia Y, Zhang XC, Tao Y (2006a) Geochemical studies on the inclusion and isotopes of the Shuiyindong gold deposit. Guizhou Geol 23:51–56 (in Chinese with English abstract)
Liu P, Lei ZY, Ye DS, Li KQ, Jin HY, Wei SY, Lu TQ (2006b) Geology and geochemistry of the Nibao gold deposit in Guizhou. Sediment Geol Tethyan Geol 26(4):78–85 (in Chinese with English abstract)
Liu P, Li PG, Ma R, Han ZH, Yang GL, Ye DS (2006c) A gold deposit associated with pyroclastic rock and hydrothermal exhalation: Nibao gold deposit in Guizhou Province, China. Miner Depos 25(1):101–110 (in Chinese with English abstract)
Liu JZ, Xia Y, Deng YM, Zhang XC, Qiu L (2007) Re-study on modes of gold occurrence in the Shuiyindong super-large-sized gold deposit. Guizhou Geol 24(3):165–169 (in Chinese with English abstract)
Liu YS, Hu ZC, Gao S, Günther D, Xu J, Gao CG, Chen HH (2008) In-situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chem Geol 257:34–43
Liu JZ, Xia Y, Deng YM, Su WC, Zhang XC, Qiu L, Chen M, Chen FE, Fu ZK (2009) Researches on the Sbt of Shuiyindong gold deposit and significance for regional prospecting. Gold Sci Technol 17(3):1–5 (in Chinese with English abstract)
Liu JZ, Yang CF, Xia Y, Chen S, Chen FE, You B, Fu ZK (2010) Sbt Study and Ideas in Patform Lithofaices Area in the Southwest Guizhou. Guizhou Geol 27(3):178–184 (in Chinese with English abstract)
Liu Y, Hu K, Han SC, Sun ZH (2015) The nature of ore-forming fluids of the carlin-type gold deposit in Southwest China: a case from the Zimudang gold deposit. Resource Geol 65(2):136–159
Liu JZ, Yang CF, Wang ZP, Wang DF, Qi LS, Li JH, Hu CW, Xu LY (2017) Geological research of Shuiyindong gold deposit in Zhenfeng County, Guizhou Province. Geol Surv China 4:32–41 (in Chinese with English abstract)
MacLean LCW, Tyliszczak T, Gilbert PUPA, Zhou D, Pray TJ, Onstott TC, Southam G (2008) A high-resolution chemical and structural study of framboidal pyrite formed within a low-temperature bacterial biofilm. Geobiology 6(5):471–480
Mao JW, Cheng YB, Chen MH, Pirajno F (2013) Major types and time–space distribution of Mesozoic ore deposits in South China and their geodynamic settings. Miner Depos 48:267–294
Monteiro LVS, Xavier RP, Hitzman MW, Juliani C, de Souza Filho CR, Carvalho EDR (2008) Mineral chemistry of ore and hydrothermal alteration at the Sossego iron oxide–copper–gold deposit, Carajás Mineral Province, Brazil. Ore Geol Rev 34:317–336
Morishita Y, Shimada N, Shimada K (2008) Invisible gold and arsenic in pyrite from the high-grade Hishikari gold deposit, Japan. Appl Surf Sci 255:1451–1454
Murowchick JB (1992) Marcasite inversion and the petrographic determination of pyrite ancestry. Econ Geol 87:1141–1152
Nevolko PA, Hoa TT, Redin YO, Anh TT, Phuong NT et al (2017) Geology, mineralogy, geochemistry and δ34S of sedimentary rock-hosted Au deposits in Song Hien structure, NE Vietnam. Ore Geol Rev 84:273–288
Ohfuji H, Rickard D (2005) Experimental syntheses of framboids—a review. Earth Sci Rev 71:147–170
Ohmoto H (1972) Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Econ Geol 67:551–578
Palenik CS, Utsunomiya S, Reich M, Kesler SE, Wang LM, Ewing RC (2004) Invisible gold revealed: direct imaging of gold nanoparticles in a Carlin-type deposit. Am Miner 89:1359–1366
Peng YW, Gu XX, Liu L, Cheng WB, Zhang YM, Wu CY, Lv PR (2012) Fluid inclusion characteristics and implications to mineralization in the Zimudang gold deposit in southwest Guizhou Province, China. Acta Mineral Sin 32(2):211–220 (in Chinese with English abstract)
Peng YW, Gu XX, Zhang YM, Liu L, Wu CY, Chen SY (2014) Source and evolution of ore-forming fluid of the Huijiabao gold field, Southwestern Guizhou: evidences from fluid inclusions and stable isotopes. Bull Miner Petrol Geochem 33:666–680
Perry KA, Pedersen TF (1993) Sulphur speciation and pyrite formation in meromictic ex-fjords. Geochim Cosmochim Acta 57:4405–4418
Peters SG, Huang JZ, Li ZP, Jing CG (2007) Sedimentary rock-hosted Au deposits of the Dian-Qian-Gui area, Guizhou, and Yunnan Provinces, and Guangxi District, China. Ore Geol Rev 31:170–204
Pi QH, Hu RZ, Xiong B, Li QL, Zhong RC (2017) In-situ SIMS U-Pb dating of hydrothermal rutile: reliable age for the Zhesang Carlin-type gold deposit in the golden triangle region, SW China. Miner Depos 52:1179–1190
Qi LS, He YN, Qi J, Yang TC, Zhang MM, Zheng Y, Zhang C (2014) New cognizance of orebody type and formation mechanism of Nibao gold deposit in Guizhou. Guizhou Geol 31(2):109–115 (in Chinese with English abstract)
Rao SDV, Naqvi SM (1997) Geological setting, mineralogy, geochemistry and genesis of the Middle Archaean Kalyadi copper deposit, western Dharwar craton, southern India. Miner Depos 32:230–242
Reich M, Kesler SE, Utsunomiya S, Palenik CS, Chryssoulis SL, Ewing RC (2005) Solubility of gold in arsenian pyrite. Geochim Cosmochim Acta 69:2781–2796
Reich M, Utsunomiya S, Kesler SE, Wang LM, Ewing RC, Becker U (2006) Thermal behavior of metal nanoparticles in geologic materials. Geology 34:1033–1036
Reich M, Chryssoulis SL, Deditius A, Palacios C, Zúñiga A, Weldt M, Alvear M (2010) “Invisible” silver and gold in supergene digenite (Cu1.8S). Geochim Cosmochim Acta 74:6157–6173
Scott RJ, Meffre S, Woodhead J, Gilbert SE, Berry RF, Emsbo P (2009) Development of framboidal pyrite during diagenesis, low-grade regional metamorphism, and hydrothermal alteration. Econ Geol 104:1143–1168
Simon G (1999) Geochemistarny and textures of gold-bearing arsenian pyrite, Twin Creeks, Nevada: implications for deposition of gold in Carlin-Type deposits. Econ Geol 94:405–421
Sim MS, Bosak T, Ono S (2011) Large Sulfur Isotope Fractionation Does Not Require Disproportionation. Science 333(6038):74–77
Spirakis CS, Sassano GP, Schrijver K (1990) Framboidal pyrite; early-diagenetic, late-diagenetic, and hydrothermal occurrences from the Acton Vale quarry, Cambro-Ordovician, Quebec. Am J Sci 290(7):843–851
Su WC, Xia B, Zhang HT, Zhang XC, Hu RZ (2008) Visible gold in arsenian pyrite at the Shuiyindong Carlin-type gold deposit, Guizhou, China: implications for the environment and processes of ore formation. Ore Geol Rev 33:667–679
Su WC, Hu RZ, Xia B, Xia Y, Liu YP (2009a) Calcite Sm-Nd isochron age of the Shuiyindong Carlin-type gold deposit, Guizhou, China. Chem Geol 258:269–274
Su WC, Heinrich CA, Pettke T, Zhang XC, Hu RZ, Xia B (2009b) Sediment-hosted gold deposits in Guizhou, China: products of wall-rock sulfidation by deep crustal fluids. Econ Geol 104:73–93
Su WC, Hu RZ, Ge X, Xia B, Chen YY, Zhu C (2012) Mineralogy and geochemistry of gold-bearing arsenian pyrite from the Shuiyindong Carlin-type gold deposit, Guizhou, China: implications for gold depositional processes. Miner Depos 47:653–662
Su WC, Dong WD, Zhang XC, Shen NP, Hu RZ, Hofstra AH, Cheng LZ, Xia Y, Yang KY (2018) Carlin-type gold deposits in the Dian-Qian-Gui “Golden Triangle” of southwest China. Rev Econ Geol 20:157–185
Suo ST, Hou GJ, Zhang MF, Wang K (1993) The large panjiang river multi-level sheeted thrust-nappe structure in southwestern guizhou. Reg Geol China 3:239–247 (in Chinese with English abstract)
Suo ST, Bi XM, Zhao WX, Hou GG (1998) Very low-grade metamorphism and its geodynamical signification of Triassic strata within the Youjiang River basin. Sci Geol Sin 33:395–405 (in Chinese with English abstract)
Sweeney RE, Kaplan IR (1973) Pyrite framboid formation; Laboratory synthesis and marine sediments. Econ Geol 68(5):618–634
Tao P, Li PG, Li KQ (2002) The structure of the deposits of the Nibao goldfield and its relationship with metallogenesis. Guizhou Geol 19(4):221–227 (in Chinese with English abstract)
Tao P, Du FY, Du CQ, Ma R (2005) Ore-controlling factors of gold deposits in volcanic tuff in the southwestern Guizhou province. Geol Prospect 41(2):12–16 (in Chinese with English abstract)
Wacey D, Kilburn MR, Saunders M, Cliff JB, Kong C, Liu AG, Matthews JJ, Brasier MD (2015) Uncovering framboidal pyrite biogenicity using nano-scale CNorg mapping. Geology 43:27–30
Wang YG, Wang LT, Zhang MF, Wang LL (1995) Texture of the Upper crust and pattern of the disseminated gold deposits distributed in Nanpanjiang area. Guizhou Geol 12:91–183 (in Chinese with English abstract)
Wang JL, Lin FC, Yu YS, Wang H, Wu SY (2014) The Indosinan-Yanshanian Gold Metallogenic System in the Youjiang Sedimentary Basin, Southwestern China. Geol Explor 50:105–113 (in Chinese with English abstract)
Wei DT (2017) Study on the metallogenetic source and mechanisms of the Nibao gold deposit, southwestern Guizhou Province, China. Ph.D. thesis, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China (in Chinese with English abstract)
Wignall PB, Newton R (1998) Pyrite framboid diameter as a measure of oxygen deficiency in ancient mudrocks. Am J Sci 298:537–552
Wilkin RT, Barnes HL (1996) Pyrite formation by reactions of iron monosulfides with dissolved inorganic and organic sulfur species. Geochim Cosmochim Acta 60:4167–4179
Xia Y (2005) Characteristics and model for Shuiyindong gold deposit in southwestern Guizhou, China. Ph.D. thesis, Institute of Geochemistry, Chinese Academy of Sciences, Guizhou, China, pp 1–123(in Chinese with English abstract)
Xiao DC (2012) The study on ore-forming fluids in the Yata Carlin-type gold deposit, Guizhou Province. Master thesis, Chengdu University of Technology, pp 1–63 (in Chinese with English abstract)
Yan J, Hu RZ, Liu S, Lin YT, Zhang JC, Fu SL (2018) NanoSIMS element mapping and sulfur isotope analysis of Au-bearing pyrite from Lannigou Carlin-type Au deposit in SW China: new insights into the origin and evolution of Au-bearing fluids. Ore Geol Rev 92:29–41
Zhang XC (1998) The geology and hydrothermal evolution of sediment-hosted gold deposits in Southwestern Guzhou Province, PRC. Dissertation, Imperial College London (University of London)
Zhang XC, Spiro B, Halls C, Stanley CJ, Yang KY (2003) Sediment-Hosted Disseminated Gold Deposits in Southwest Guizhou, PRC: their Geological Setting and Origin in Relation to Mineralogical, Fluid Inclusion, and Stable-Isotope Characteristics. Int Geol Rev 45:407–470
Zhang XC, Hofstra AH, Hu RZ, Emsbo P, Su WC, Ridley WI (2005) Geochemistry and δ34S of ores and ore stage iron sulfides in Carlin-type gold deposits, Dian-Qian-Gui area, China: implications for ore genesis. In: Mineral deposit research: meeting the global challenge. Springer, Berlin, pp 1107–1110
Zhang J, Deng J, Chen HY, Yang LQ, Cooke D, Danyushevsky L, Gong QJ (2014a) LA-ICP-MS trace element analysis of pyrite from the Chang’an gold deposit, Sanjiang region, China: implication for ore-forming process. Gondwana Res 26:557–575
Zhang JC, Lin YT, Yang W, Shen WJ, Hao JL, Hu S, Cao MJ (2014b) Improved precision and spatial resolution of sulfur isotope analysis using NanoSIMS. J Anal At Spectrom 29:1934–1943
Zheng LL, Yang RD, Liu JZ, Gao JB, Chen J, Li JH (2014) Geological features of a large concealed gold orebody in the Nibao gold deposit, southwestern Guizhou Province. Geol Explor 50(4):689–699 (in Chinese with English abstract)
Zheng LL, Yang RD, Liu JZ, Gao JB, Chen J, Liu JZ, He YN (2016) Geochemical characteristics of the giant Nibao Carlin-type gold deposit (Guizhou, China) and their geological implications. Arab J Geosci 9:108
Zhu JJ, Hu RZ, Richards JP, Bi XW, Stern R, Lu G (2017) No genetic link between Late Cretaceous felsic dikes and Carlin-type Au deposits in the Youjiang basin, Southwest China. Ore Geol Rev 84:328–337
Zong KQ, Klemd R, Yuan Y, He ZY, Guo JL, Shi XL et al (2017) The assembly of Rodinia: the correlation of early Neoproterozoic (ca. 900 Ma) high-grade metamorphism and continental arc formation in the southern Beishan Orogen, southern Central Asian Orogenic Belt (CAOB). Precambrian Res 290:32–48