In Situ Observation of Various Phase Transformation Paths in Nb‐Rich TiAl Alloys during Quenching with Different Rates

Advanced Engineering Materials - Tập 13 Số 8 - Trang 700-704 - 2011
Andreas Stark1, Michael Oehring1, Florian Pyczak1, A. Schreyer1
1Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, D-21502, Geesthacht, Germany

Tóm tắt

AbstractIn recent years intermetallic γ‐TiAl based alloys with additional amounts of the ternary β phase have attracted attention due to their improved hot workability. Depending on alloy composition and heat treatment the ternary β phase can transform to different ternary phases at lower temperatures. A few of them are assumed to be detrimental to ductility. However, the current phase diagrams of these multiphase materials are often quite uncertain. Thus, the possible transformations of third phases in the temperature range between 700 and 1 100 °C are studied by means of in situ high‐energy X‐ray diffraction (HEXRD). Depending on quenching rate reversible transformations of βo to different ω related phases are observed, indicating a stepwise diffusion controlled transformation mechanism of B2‐ordered βo to B82‐ordered ωo. Apparently, the addition of Mo can hinder this transformation.

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