Improvement of lithium battery performance through composite electrode microstructure optimization
Tóm tắt
The lithium trivanadate Li1.2V3O8 has been investigated during the past decade as a very promising positive electrode material for lithium batteries due to its high theoretical capacity of 360 mAh/g. However, the experimental capacity remains generally much lower than (about half) the theoretical value. To increase electrode cycling performance in batteries, most researchers generally focus their work on the active material optimisation. Here we show that the polymeric binder of the composite electrode may have an important role on the electrode performance. We describe a new tailored polymeric binder combination with controlled polymer-filler (carbon black) interactions that allows the preparation of new and more efficient electrode architecture. Using this polymeric binder, composite electrodes based on Li1.2V3O8 display a room-temperature cycling capacity of 280 mAh/g (C/5 rate, 3.3-2V) instead of 180 mAh/g using a Bellcore-type composite electrode (PLIonTM technology). We have coupled SEM observations, galvanostatic cycling and electrochemical impedance spectroscopy in order to define and understand the impact of the microstructure of the composite electrode on its electrochemical performance. Derived from these studies, the main key factors that provide efficient charge carrier collection within the composite electrode complex medium will be discussed. Present findings open up new and attractive prospects for electrode performance optimisation.
Tài liệu tham khảo
M. Armand, Solid State ionics69, 309 (1994).
J.M. Tarascon, A.S. Gozdz, C. Schmutz, F. Shokoohi and P.C. Warren, Solid State Ionics86–88, 49 (1996).
N.S. Choi, Y.G. Lee and J.K. Park, J. Power Sources112, 61 (2002).
S.S. Zhang and T.R. Jow, J. Power Sources109, 422 (2002).
M. Manickam and M. Takata, Electrochim. Acta48, 957 (2003).
J. Drofenik, M. Gaberscek, R. Dominko, F.W. Poulsen, M. Mogensen, S. Pejovnik and J. Jamnik, Electrochim. Acta48, 883 (2003).
S. Panero, M. Pasquali and G. Pistoia, J. Electrochem. Soc.130, 1225 (1983).
F. Bonino, M. Ottaviani, B. Scrosati and G. Pistoia, J. Electrochem. Soc.135, 12 (1988).
Y. Geronov, B. Puresheva, R.V. Moshtev, P. Zlatilova, T. Kosev, Z. Stoynov, G. Pistoia and M. Pasquali, J. Electrochem. Soc.137, 3338 (1990).
K. West, B. Zachau-Christiansen, S. Skaarup, Y. Saidi, J. Barker, I. I. Olsen, R. Pynenburg and R. Koksbang, J. Electrochem. Soc.143, 820 (1996).
R. Dominko, M. Gaberscek, J. Drofenik, M. Bele and S. Pejovnik, Electrochem. Solid-State Lett.4, A187 (2001).
J.K. Hong, J.H. Lee and S.M. Oh, J. Power Sources111, 90 (2002).
J.L. Leblanc, Prog. Polym. Sci.27, 627 (2002).
P. Bezot, C. Hesse-Bezot, R. Rousset and C. Diraison, Colloid. Surf. A97, 53 (1995).
R.W.A. Franco, J.P. Donoso, C.J. Magon, C.B. Rodella, A.O. Florentino, M.J. Saeki, J.M. Pernaut and A.L. de Oliveira, Solid State Ionics149, 113 (1998).
J.M. Pernaut and G. Goulart, J. Power Sources55, 93 (1995).
S. Jouanneau, A. Le Gal La Salle, A. Verbaere, D. Guyomard, M. Deschamps and S. Lascaud, Solid State Ionics, in press.
F. Leroux, D. Guyomard and Y. Piffard, Solid State Ionics80, 30 (1995).
D. Guy, B. Lestriez and D. Guyomard, Adv. Mater.16, 553 (2004).
D. Guy, B. Lestriez, R. Bouchet, V. Gaudefroy and D. Guyomard, Electrochem. Solid-State Lett. accepted.
M.G. Lazarraga, S. Mandal, J. Ibanez, J.M. Amarilla and J.M. Rojo, J. Power Sources115, 315 (2003).
K.K. Patel, J.M. Paulsen and J. Desilvestro, J. Power Sources122, 144 (2003).
D. Stauffer, A. Aharony, Introduction to the Percolation Theory, Taylor & Francis, London, 1994.
B.H. Bijsterbosch, in: Solid/liquid Dispersions (T.F. Tadros, Ed.) Academic Press, London, 1987, p. 91.