Hypercrosslinked microporous polystyrene: from synthesis to properties to applications

Li, 2021, Synergy between Cu doping and catalytic platform in 2D Ni-MOFs/Cu-Zn0.5Cd0.5S for efficient water-to-hydrogen conversion, Chem. Eng. J., 410, 10.1016/j.cej.2020.128316 Wu, 2020, High-loaded single Cu atoms decorated on N-doped graphene for boosting Fenton-like catalysis under neutral pH, J. Mater. Chem., 8, 13685, 10.1039/D0TA04943C Zhang, 2022, On-demand fabrication of porous silver nanostructures by chloride ions inspired galvanic replacement reaction, Mater. Today Chem., 24 Bao, 2022, High-polycondensation and porous carbon nitride nanosheets for highly efficient photocatalytic hydrogen evolution, Mater, Today Chem, 26 Qin, 2021, Development of copper vacancy defects in a silver-doped CuS nanoplatform for high-efficiency photothermal–chemodynamic synergistic antitumor therapy, J. Mater. Chem. B, 9, 8882, 10.1039/D1TB01629F Zeng, 2017, Robust coating with superhydrophobic and self-cleaning properties in either air or oil based on natural zeolite, Surf. Coat. Technol., 309, 1045, 10.1016/j.surfcoat.2016.10.036 Li, 2018, Effect of adjustable molecular chain structure and pure silica zeolite nanoparticles on thermal, mechanical, dielectric, UV-shielding and hydrophobic properties of fluorinated copolyimide composites, Appl. Surf. Sci., 427, 437, 10.1016/j.apsusc.2017.08.024 Liu, 2023, Facile synthesis of pure silicon zeolite-confined silver nanoparticles and their catalytic activity for the reduction of 4-nitrophenol and methylene blue, Separ. Purif. Technol., 307, 10.1016/j.seppur.2022.122727 Völker, 2019, Systematic review of toxicity removal by advanced wastewater treatment technologies via ozonation and activated carbon, Environ. Sci. Technol., 53, 7215, 10.1021/acs.est.9b00570 Mitran, 2021, A review of composite phase change materials based on porous silica nanomaterials for latent heat storage applications, Molecules, 26, 241, 10.3390/molecules26010241 Yang, 2021, Instantaneous vapor-liquid-solid growth of amorphous SiO2 nanowires within a local-equilibrium plasma and the optimized lithiation/delithiation activity, Appl. Surf. Sci., 557, 10.1016/j.apsusc.2021.149848 Li, 2021, Boosting H2 production over C60-mediated NH2-MIL-125(Ti)/Zn0.5Cd0.5S S-scheme heterojunction via enhanced interfacial carrier separation, Small, 17 Mo, 2022, MOF(Fe)-derived composites as a unique nanoplatform for chemo-photodynamic tumor therapy, J. Mater. Chem. B, 10, 8760, 10.1039/D2TB01691E Lee, 2020, Advances in conjugated microporous polymers, Chem. Rev., 120, 2171, 10.1021/acs.chemrev.9b00399 Cousins, 2019, Highly porous organic polymers for hydrogen fuel storage, Polymers, 11, 690, 10.3390/polym11040690 Abdelnaby, 2019, A microporous organic copolymer for selective CO2 capture under humid conditions, ACS Sustainable Chem. Eng., 7, 13941, 10.1021/acssuschemeng.9b02334 Zhu, 2022, (Catecholate)CuI2-Displayed porous organic polymers as efficient heterogeneous catalysts for the mild and selective aerobic oxidation of alcohols, CCS Chem Zhu, 2022, Emerging porous organic polymers for biomedical applications, Chem. Soc. Rev., 51, 1377, 10.1039/D1CS00871D Zhang, 2015, Triptycene-based hyper-cross-linked polymer sponge for gas storage and water treatment, Macromolecules, 48, 8509, 10.1021/acs.macromol.5b02222 Feng, 2012, Covalent organic frameworks, Chem. Soc. Rev., 41, 6010, 10.1039/c2cs35157a Li, 2019, Recent progress in covalent organic frameworks as solid-state ion conductors, ACS Mater. Lett., 1, 327, 10.1021/acsmaterialslett.9b00185 Zhang, 2021, A rising star from two worlds: collaboration of COFs and ILs, Adv. Funct. Mater., 31 Cai, 2022, Improved and stable triazine-based covalent organic framework for lithium storage, Appl. Surf. Sci., 594, 10.1016/j.apsusc.2022.153481 Wang, 2020, Polymer of intrinsic microporosity (PIM) films and membranes in electrochemical energy storage and conversion: a mini-review, Electrochem. Commun. Huang, 2021, Thermally cross-linked amidoxime-functionalized polymers of intrinsic microporosity membranes for highly selective hydrogen separation, ACS Sustainable Chem. Eng., 9, 9426, 10.1021/acssuschemeng.1c02784 Tan, 2017, Hypercrosslinked porous polymer materials: design, synthesis, and applications, Chem. Soc. Rev., 46, 3322, 10.1039/C6CS00851H Kundu, 2016, Novel nitrogen and sulfur rich hyper-cross-linked microporous poly-triazine-thiophene copolymer for superior CO2 capture, ACS Sustainable Chem. Eng., 4, 3697, 10.1021/acssuschemeng.6b00262 Liu, 2020, A highly rigid and conjugated microporous polymer membrane for solvent permeation and biofuel purification: a molecular simulation study, ACS Sustainable Chem. Eng., 8, 2892, 10.1021/acssuschemeng.9b07207 Mane, 2018, Development of adsorbents for selective carbon capture: role of homo- and cross-coupling in conjugated microporous polymers and their carbonized derivatives, ACS Sustainable Chem. Eng., 6, 17419, 10.1021/acssuschemeng.8b05323 Tian, 2020, Porous aromatic frameworks (PAFs), Chem. Rev., 120, 8934, 10.1021/acs.chemrev.9b00687 Castaldo, 2017, Microporous hyper-crosslinked polystyrenes and nanocomposites with high adsorption properties: a review, Polymers, 9, 651, 10.3390/polym9120651 Tsyurupa, 2002, Hypercrosslinked polymers: basic principle of preparing the new class of polymeric materials, React. Funct. Polym., 53, 193, 10.1016/S1381-5148(02)00173-6 Tsyurupa, 2006, Porous structure of hypercrosslinked polystyrene: state-of-the-art mini-review, React. Funct. Polym., 66, 768, 10.1016/j.reactfunctpolym.2005.11.004 Huang, 2018, Hypercrosslinked polymers: a review, Polym. Rev., 58, 1, 10.1080/15583724.2017.1344703 Woodward, 2014, Swellable, water- and acid-tolerant polymer sponges for chemoselective carbon dioxide capture, J. Am. Chem. Soc., 136, 9028, 10.1021/ja5031968 Ding, 2017, Porosity-enhanced polymers from hyper-cross-linked polymer precursors, Macromolecules, 50, 956, 10.1021/acs.macromol.6b02715 Fu, 2017, Transforming waste expanded polystyrene foam into hyper-crosslinked polymers for carbon dioxide capture and separation, Chem. Eng. J., 323, 557, 10.1016/j.cej.2017.04.090 Davankov, 1971, Patent US 3729457, 1971, Chem. Abstr, 6841 Ahn, 2006, Rapid generation and control of microporosity, bimodal pore size distribution, and surface area in Davankov-type hyper-cross-linked resins, Macromolecules, 39, 627, 10.1021/ma051152n Liao, 2020, Direct synthesis of hypercrosslinked microporous poly (para-methoxystyrene) for removal of iron (III) ion from aqueous solution, Microporous Mesoporous Mater., 307, 10.1016/j.micromeso.2020.110469 Fontanals, 2015, Hypercrosslinked materials: preparation, characterisation and applications, Polym. Chem., 6, 7231, 10.1039/C5PY00771B Xu, 2013, Recent development of hypercrosslinked microporous organic polymers, Macromol. Rapid Commun., 34, 471, 10.1002/marc.201200788 Tsyurupa, 2009, Hypercrosslinked polystyrene: the first nanoporous polymeric material, Nanotechnol. Russia, 4, 665, 10.1134/S1995078009090109 Gu, 2021, Low-cost hypercrosslinked polymers by direct knitting strategy for catalytic applications, Adv. Funct. Mater., 31 Davankov, 1974, Macronet isoporous gels through crosslinking of dissolved polystyrene, J. Polym. Sci., Polym. Symp., 47, 95, 10.1002/polc.5070470113 Davankov, 1997, Formation of regular clusters through self-association of intramolecularly hypercrosslinked polystyrene-type nanosponges, J. Polym. Sci., Part A: Polym. Chem., 35, 3847, 10.1002/(SICI)1099-0518(199712)35:17<3847::AID-POLA23>3.0.CO;2-C Veverka, 1999, Mechanism of hypercrosslinking of chloromethylated styrene–divinylbenzene copolymers, React. Funct. Polym., 41, 21, 10.1016/S1381-5148(99)00030-9 Lazutin, 2014, Hypercrosslinked polystyrene networks: an atomistic molecular dynamics simulation combined with a mapping/reverse mapping procedure, J. Chem. Phys., 140 Schwab, 2009, High surface area polyHIPEs with hierarchical pore system, Soft Matter, 5, 1055, 10.1039/b815143a Davankov, 1990, Structure and properties of hypercrosslinked polystyrene—the first representative of a new class of polymer networks, React. Polym., 13, 27, 10.1016/0923-1137(90)90038-6 Zeng, 2012, Enhanced adsorption of puerarin onto a novel hydrophilic and polar modified post-crosslinked resin from aqueous solution, J. Colloid Interface Sci., 385, 166, 10.1016/j.jcis.2012.07.006 Wang, 2018, Hierarchical porous hyper-cross-linked polymers modified with phenolic hydroxyl groups and their efficient adsorption of aniline from aqueous solution, Colloids Surf. A Physicochem. Eng. Asp., 558, 80, 10.1016/j.colsurfa.2018.08.060 Wang, 2019, One-pot synthesis of hyper-cross-linked polymers chemically modified with pyrrole, furan, and thiophene for phenol adsorption from aqueous solution, J. Colloid Interface Sci., 538, 499, 10.1016/j.jcis.2018.12.021 Gan, 2019, Oxygen-rich hyper-cross-linked polymers with hierarchical porosity for aniline adsorption, Chem. Eng. J., 368, 29, 10.1016/j.cej.2019.02.164 Huang, 2012, Efficient adsorptive removal of phenol by a diethylenetriamine-modified hypercrosslinked styrene–divinylbenzene (PS) resin from aqueous solution, Chem. Eng. J., 195–196, 40, 10.1016/j.cej.2012.04.098 Yang, 2016, Solution-processable hypercrosslinked polymers by low cost strategies: a promising platform for gas storage and separation, J. Mater. Chem., 4, 15072, 10.1039/C6TA05226F Davankov, 1974, Macronet isoporous gels through crosslinking of dissolved polystyrene, 95 Joseph, 1997, Solid-state 13C-NMR analysis of hypercrosslinked polystyrene, J. Polym. Sci., Part A: Polym. Chem., 35, 695, 10.1002/(SICI)1099-0518(199703)35:4<695::AID-POLA12>3.0.CO;2-I Ratvijitvech, 2015, The effect of molecular weight on the porosity of hypercrosslinked polystyrene, Polym. Chem., 6, 7280, 10.1039/C5PY00668F Qiao, 2014, Polymeric molecular sieve membranes via in situ cross-linking of non-porous polymer membrane templates, Nat. Commun., 5, 1, 10.1038/ncomms4705 Gadwdzik, 2001, Modification of porous poly (styrene-divinylbenzene) beads by Friedel-Crafts reaction, Chromatographia, 54, 323, 10.1007/BF02492677 Maya, 2014, A new approach to the preparation of large surface area poly (styrene-co-divinylbenzene) monoliths via knitting of loose chains using external crosslinkers and application of these monolithic columns for separation of small molecules, Polymer, 55, 340, 10.1016/j.polymer.2013.08.018 Wang, 2012, Electrochim. Acta, 83, 140, 10.1016/j.electacta.2012.07.092 Hradil, 1998, Styrene–divinylbenzene copolymers post-crosslinked with tetrachloromethane, Polymer, 39, 6041, 10.1016/S0032-3861(98)00057-3 Lee, 2006, Hydrogen adsorption in microporous hypercrosslinked polymers, Chem. Commun., 2670, 10.1039/b604625h Germain, 2006, High surface area nanoporous polymers for reversible hydrogen storage, Chem. Mater., 18, 4430, 10.1021/cm061186p Macintyre, 2006, Synthesis of ultrahigh surface area monodisperse porous polymer nanospheres, Macromolecules, 39, 5381, 10.1021/ma0610010 Fontanals, 2005, Synthesis of Davankov-type hypercrosslinked resins using different isomer compositions of vinylbenzyl chloride monomer, and application in the solid-phase extraction of polar compounds, J. Polym. Sci., Part A: Polym. Chem., 43, 1718, 10.1002/pola.20646 Xue, 2020, Streamlined synthesis of PEG-polypeptides directly from amino acids, Macromolecules, 53, 6589, 10.1021/acs.macromol.0c00470 Liao, 2018, In-situ construction of novel silver nanoparticle decorated polymeric spheres as highly active and stable catalysts for reduction of methylene blue dye, Appl. Catal. Gen., 549, 102, 10.1016/j.apcata.2017.09.034 Liao, 2016, Facile preparation of uniform nanocomposite spheres with loading silver nanoparticles on polystyrene-methyl acrylic acid spheres for catalytic reduction of 4-nitrophenol, J. Phys. Chem. C, 120, 25935, 10.1021/acs.jpcc.6b09356 Law, 1996, Solid-state 13C MAS NMR studies of hyper-cross-linked polystyrene resins, Macromolecules, 29, 6284, 10.1021/ma951606o Tsyurupa, 1995, Use of the hyper-crosslinked polystyrene sorbents “Styrosorb” for solid phase extraction of phenols from water, Fresenius’ J. Anal. Chem., 352, 672, 10.1007/BF00323045 Li, 2002, Adsorption of phenolic compounds from aqueous solutions by a water-compatible hypercrosslinked polymeric adsorbent, Chemosphere, 47, 981, 10.1016/S0045-6535(01)00222-3 Wu, 2011, Nanoporous polystyrene and carbon materials with core–shell nanosphere-interconnected network structure, Macromolecules, 44, 5846, 10.1021/ma2013207 Pastukhov, 1999, Hypercrosslinked polystyrene: a polymer in a non-classical physical state, J. Polym. Sci., Part B: Polym. Phys., 37, 2324, 10.1002/(SICI)1099-0488(19990901)37:17<2324::AID-POLB4>3.0.CO;2-B Wood, 2007, Hydrogen storage in microporous hypercrosslinked organic polymer networks, Chem. Mater., 19, 2034, 10.1021/cm070356a Schwab, 2011, Nanoporous copolymer networks through multiple Friedel–Crafts-alkylation—studies on hydrogen and methane storage, J. Mater. Chem., 21, 2131, 10.1039/C0JM03017A Li, 2011, A new strategy to microporous polymers: knitting rigid aromatic building blocks by external cross-linker, Macromolecules, 44, 2410, 10.1021/ma200630s Germain, 2009, Nanoporous polymers for hydrogen storage, Small, 5, 1098, 10.1002/smll.200801762 Modarresi, 2008, Model-based calculation of solid solubility for solvent selection A review, Ind. Eng. Chem. Res., 47, 5234, 10.1021/ie0716363 Urban, 2014, Effect of hypercrosslinking conditions on pore size distribution and efficiency of monolithic stationary phases, J. Separ. Sci., 37, 3082, 10.1002/jssc.201400730 Fontanals, 2008, Synthesis of spherical ultra-high-surface-area monodisperse amphipathic polymer sponges in the low-micrometer size range, Adv. Mater., 20, 1298, 10.1002/adma.200702237 He, 2017, Hyper-cross-linking mediated self-assembly strategy to synthesize hollow microporous organic nanospheres, ACS Appl. Mater. Interfaces, 9, 35209, 10.1021/acsami.7b08657 Zhang, 2011, Facile synthesis of hypercrosslinked resins via chloromethylation and continuous condensation of simple aryl molecules, Bull. Mater. Sci., 34, 735, 10.1007/s12034-011-0188-z Zhang, 2007, Studies progress of preparation, properties and applications of hyper-cross-linked polystyrene networks, J. Mater. Sci., 42, 7621, 10.1007/s10853-007-1763-y Zhang, 2015, Postmodification of linear poly-p-phenylenes to prepare hyper-crosslinked polymers: tuning the surface areas by the molecular weight, Polymer, 60, 234, 10.1016/j.polymer.2015.01.053 Tsyurupa, 1980, The study of macronet isoporous styrene polymers by gel permeation chromatography, J. Polym. Sci. Polym. Chem. Ed., 18, 1399, 10.1002/pol.1980.170180423 Masoumi, 2021, Synthesis of polystyrene-based hyper-cross-linked polymers for Cd(II) ions removal from aqueous solutions: experimental and RSM modeling, J. Hazard Mater., 416, 10.1016/j.jhazmat.2021.125923 Liu, 2017, Hypercrosslinked polystyrene microspheres with ultrahigh surface area and their application in gas storage, Mater. Chem. Phys., 199, 616, 10.1016/j.matchemphys.2017.07.032 Davankov, 2000, Unusual mobility of hypercrosslinked polystyrene networks: swelling and dilatometric studies, J. Polym. Sci., Part B: Polym. Phys., 38, 1553, 10.1002/(SICI)1099-0488(20000601)38:11<1553::AID-POLB160>3.0.CO;2-L Kobayashi, 2007, Positronium chemistry in porous materials, Radiat. Phys. Chem., 76, 224, 10.1016/j.radphyschem.2006.03.042 He, 2007, Positronium annihilation and pore surface chemistry in mesoporous silica films, Appl. Phys. Lett., 91, 10.1063/1.2756310 Schut, 2000, Positronium formation in NaY-zeolites studied by lifetime, positron beam Doppler broadening and 3-gamma detection techniques, Radiat, Phys. Chem., 58, 715 Consolati, 2000, Positron lifetime spectroscopy as a probe of nanoporosity of cement-based materials, Radiat. Phys. Chem., 58, 727, 10.1016/S0969-806X(00)00248-6 Kajcsos, 2000, On the peculiarities of positron annihilation features in silicalite-1 and Y-zeolites, Radiat. Phys. Chem., 58, 709, 10.1016/S0969-806X(00)00244-9 Shantarovich, 2000, Positron annihilation lifetime study of high and low free volume glassy polymers: effects of free volume sizes on the permeability and permselectivity, Macromolecules, 33, 7453, 10.1021/ma000551+ Shantarovich, 2002, Positron annihilation study of hyper-cross-linked polystyrene networks, Macromolecules, 35, 9723, 10.1021/ma020615b He, 2003, Temperature dependence of ortho-positronium annihilation in hypercrosslinked polystyrene, Radiat. Phys. Chem., 68, 511, 10.1016/S0969-806X(03)00220-2 Wang, 2019, Porous hypercrosslinked polymer-TiO2-graphene composite photocatalysts for visible-light-driven CO2 conversion, Nat. Commun., 10, 1 Schuur, 2015, Climate change and the permafrost carbon feedback, Nature, 520, 171, 10.1038/nature14338 Li, 2013, Nitrogen-rich porous adsorbents for CO2 capture and storage, Chem. Asian J., 8, 1680, 10.1002/asia.201300121 Oschatz, 2018, A search for selectivity to enable CO2 capture with porous adsorbents, Energy Environ. Sci., 11, 57, 10.1039/C7EE02110K Liao, 2019, Semiconductor polymeric graphitic carbon nitride photocatalysts: the “holy grail” for the photocatalytic hydrogen evolution reaction under visible light, Energy Environ. Sci., 12, 2080, 10.1039/C9EE00717B Kumar, 2020, Chitosan-based zeolite-Y and ZSM-5 porous biocomposites for H2 and CO2 storage, Carbohydr. Polym., 232, 10.1016/j.carbpol.2019.115808 Yang, 2023, Carbon defective g-C3N4 thin-wall tubes for drastic improvement of photocatalytic H2 production, Carbon, 202, 348, 10.1016/j.carbon.2022.10.074 Liao, 2022, An innovative synthesis strategy for high-efficiency and defects-switchable-hydrogenated TiO2 photocatalysts, Matter, 5, 377, 10.1016/j.matt.2022.01.006 Castaldo, 2022, Hierarchically porous hydrogels and aerogels based on reduced graphene oxide, montmorillonite and hyper-crosslinked resins for water and air remediation, Chem. Eng. J., 430, 10.1016/j.cej.2021.133162 Baker, 2002, Future directions of membrane gas separation technology, Ind. Eng. Chem. Res., 41, 1393, 10.1021/ie0108088 He, 2012, Microporous metal–organic frameworks for storage and separation of small hydrocarbons, Chem. Commun., 48, 11813, 10.1039/c2cc35418g Mitra, 2016, PIM-1 mixed matrix membranes for gas separations using cost-effective hypercrosslinked nanoparticle fillers, Chem. Commun., 52, 5581, 10.1039/C6CC00261G Veverka, 2004, Influence of hypercrosslinking on adsorption and absorption on or in styrenic polymers, React. Funct. Polym., 59, 71, 10.1016/j.reactfunctpolym.2003.12.008 Xie, 2019, Iodine capture in porous organic polymers and metal–organic frameworks materials, Mater. Horiz., 6, 1571, 10.1039/C8MH01656A Liao, 2017, Novel poly (acrylic acid)-modified tourmaline/silver composites for adsorption removal of Cu (II) ions and catalytic reduction of methylene blue in water, Chem. Lett., 46, 1631, 10.1246/cl.170785 Samaddar, 2019, Polymer hydrogels and their applications toward sorptive removal of potential aqueous pollutants, Polym. Rev., 59, 418, 10.1080/15583724.2018.1548477 Yan, 2021, Self-assembly preparation of lignin–graphene oxide composite nanospheres for highly efficient Cr(vi) removal, RSC Adv., 11, 4713, 10.1039/D0RA09190A Li, 2011, Hypercrosslinked microporous polymer networks for effective removal of toxic metal ions from water, Microporous Mesoporous Mater., 138, 207, 10.1016/j.micromeso.2010.08.023 Yang, 2018, Thiourea modified hyper-crosslinked polystyrene resin for heavy metal ions removal from aqueous solutions, J. Appl. Polym. Sci., 135, 10.1002/app.45568 Huang, 2008, Synthesis, characterization, and adsorption behavior of aniline modified polystyrene resin for phenol in hexane and in aqueous solution, J. Colloid Interface Sci., 317, 434, 10.1016/j.jcis.2007.09.077 Ling, 2016, Polar-modified post-cross-linked polystyrene and its adsorption towards salicylic acid from aqueous solution, Chem. Eng. J., 286, 400, 10.1016/j.cej.2015.11.014 Fu, 2016, Comparison of hyper-cross-linked polystyrene/polyacryldiethylenetriamine (HCP/PADETA) interpenetrating polymer networks (IPNs) with hyper-cross-linked polystyrene (HCP): structure, adsorption and separation properties, RSC Adv., 6, 32340, 10.1039/C6RA01932C Manzano, 2020, Mesoporous silica nanoparticles for drug delivery, Adv. Funct. Mater., 30, 10.1002/adfm.201902634 Wu, 2015, Synthesis, characterization, and adsorption properties of ionic liquid-modified hypercrosslinked polystyrene resins, RSC Adv., 5, 72601, 10.1039/C5RA08273K Udalova, 2015, Sorption of tetracycline antibiotics on hyper-crosslinked polystyrene from aqueous and aqueous-organic media, Russ. J. Phys. Chem. A, 89, 1082, 10.1134/S003602441506031X Yang, 2015, Hierarchical porous polystyrene monoliths from polyHIPE, Macromol. Rapid Commun., 36, 1553, 10.1002/marc.201500235 Xiao, 2017, Novel robust superhydrophobic coating with self-cleaning properties in air and oil based on rare earth metal oxide, Ind. Eng. Chem. Res., 56, 12354, 10.1021/acs.iecr.7b03131 Xiao, 2018, Thermally and chemically stable candle soot superhydrophobic surface with excellent self-cleaning properties in air and oil, ACS Appl. Nano Mater., 1, 1204, 10.1021/acsanm.7b00363 Svec, 2012, Quest for organic polymer-based monolithic columns affording enhanced efficiency in high performance liquid chromatography separations of small molecules in isocratic mode, J. Chromatogr. A, 1228, 250, 10.1016/j.chroma.2011.07.019 Urban, 2010, New approach to porous polymer monolithic capillary columns with large surface area for the highly efficient separation of small molecules, J. Chromatogr. A, 1217, 8212, 10.1016/j.chroma.2010.10.100 Li, 2019, Metal-organic frameworks as advanced sorbents in sample preparation for small organic analytes, Coord. Chem. Rev., 397, 1, 10.1016/j.ccr.2019.06.014 Maya, 2013, Porous polymer monoliths with large surface area and functional groups prepared via copolymerization of protected functional monomers and hypercrosslinking, J. Chromatogr. A, 1317, 32, 10.1016/j.chroma.2013.07.073 Penner, 1998, A novel stationary phase for the high performance liquid chromatographic separation and determination of phenols, Mendeleev Commun., 8, 24, 10.1070/MC1998v008n01ABEH000895 Penner, 1999, Anion-exchange ability of neutral hydrophobic hypercrosslinked polystyrene, Anal. Commun., 36, 199, 10.1039/a902449b Penner, 1999, Investigation of the properties of hypercrosslinked polystyrene as a stationary phase for high-performance liquid chromatography, Chromatographia, 50, 611, 10.1007/BF02493669 Penner, 2001, Use of hypercrosslinked polystyrene for the determination of pyrocatechol, resorcinol, and hydroquinone by reversed-phase HPLC with dynamic on-line preconcentration, J. Anal. Chem., 56, 934, 10.1023/A:1012361428727 Zhang, 2011, Optimization of the synthesis of a hyper-crosslinked stationary phases: a new generation of highly efficient, acid-stable hyper-crosslinked materials for HPLC, J. Separ. Sci., 34, 1407, 10.1002/jssc.201100252 Zhang, 2012, Silica-based, hyper-crosslinked acid stable stationary phases for high performance liquid chromatography, J. Chromatogr. A, 1228, 110, 10.1016/j.chroma.2011.07.096 Davankov, 2003, Hypercrosslinked polystyrene as a novel type of high-performance liquid chromatography column packing material: mechanisms of retention, J. Chromatogr. A, 987, 67, 10.1016/S0021-9673(02)01914-3 Sychov, 2004, Elucidation of retention mechanisms on hypercrosslinked polystyrene used as column packing material for high-performance liquid chromatography, J. Chromatogr. A, 1030, 17, 10.1016/j.chroma.2003.10.098 Wu, 2014, Retention mechanism of hypercrosslinked polystyrene silica hybrid phase in normal phase chromatography, J. Chromatogr. A, 1370, 50, 10.1016/j.chroma.2014.10.018 Yang, 2020, Recent progress of carbon-supported single-atom catalysts for energy conversion and storage, Matter, 3, 1442, 10.1016/j.matt.2020.07.032 Liao, 2019, Ag-Based nanocomposites: synthesis and applications in catalysis, Nanoscale, 11, 7062, 10.1039/C9NR01408J Liao, 2019, Unlocking the door to highly efficient Ag-based nanoparticles catalysts for NaBH4-assisted nitrophenol reduction, Nano Res., 1 Han, 2019, Noble metal (Pt, Au@ Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts, J. Catal., 370, 70, 10.1016/j.jcat.2018.12.005 Sulman, 2011, Kinetics of phenol hydrogenation over Pd-containing hypercrosslinked polystyrene, Chem. Eng. J., 176, 33, 10.1016/j.cej.2011.05.044 Nikoshvili, 2015, Selective hydrogenation of 2-methyl-3-butyn-2-ol over Pd-nanoparticles stabilized in hypercrosslinked polystyrene: solvent effect, Catal. Today, 241, 179, 10.1016/j.cattod.2014.01.045 Sidorov, 2001, Platinum-containing hyper-cross-linked polystyrene as a modifier-free selective catalyst for L-sorbose oxidation, J. Am. Chem. Soc., 123, 10502, 10.1021/ja0107834 Li, 2021, Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction, Nat. Commun., 12, 914, 10.1038/s41467-021-21132-4 Nasrollahzadeh, 2020, Recent progresses in the application of cellulose, starch, alginate, gum, pectin, chitin and chitosan based (nano)catalysts in sustainable and selective oxidation reactions: a review, Carbohydr. Polym., 241, 10.1016/j.carbpol.2020.116353 Bronstein, 2004, Structure and catalytic properties of Pt-modified hyper-cross-linked polystyrene exhibiting hierarchical porosity, J. Phys. Chem. B, 108, 18234, 10.1021/jp046459n Doluda, 2007, Kinetics of phenol oxidation over hypercrosslinked polystyrene impregnated with Pt nanoparticles, Chem. Eng. J., 134, 256, 10.1016/j.cej.2007.03.069 Mondal, 2015, Fabrication of ruthenium nanoparticles in porous organic polymers: towards advanced heterogeneous catalytic nanoreactors, Chem. Eur J., 21, 19016, 10.1002/chem.201504055 Sulman, 2007, Catalytic properties of Ru nanoparticles introduced in a matrix of hypercrosslinked polystyrene toward the low-temperature oxidation of D-glucose, J. Mol. Catal. Chem., 278, 112, 10.1016/j.molcata.2007.08.029 Doluda, 2013, Kinetics of lactose hydrogenation over ruthenium nanoparticles in hypercrosslinked polystyrene, Ind. Eng. Chem. Res., 52, 14066, 10.1021/ie401778y Sulman, 2015, Maltose hydrogenation over ruthenium nanoparticles impregnated in hypercrosslinked polystyrene, Chem. Eng. J., 282, 37, 10.1016/j.cej.2015.04.002 Sapunov, 2013, D-glucose hydrogenation over Ru nanoparticles embedded in mesoporous hypercrosslinked polystyrene, J. Phys. Chem. A, 117, 4073, 10.1021/jp312703j Sulman, 2011, Nanosized catalysts as a basis for intensifications of technologies, Chem. Eng. Process: Process Intensif., 50, 1041, 10.1016/j.cep.2011.05.017 Liras, 2019, Hybrid materials based on conjugated polymers and inorganic semiconductors as photocatalysts: from environmental to energy applications, Chem. Soc. Rev., 48, 5454, 10.1039/C9CS00377K Che, 2020, Facile construction of porous intramolecular g-C3N4-based donor-acceptor conjugated copolymers as highly efficient photocatalysts for superior H2 evolution, Nano Energy, 67, 10.1016/j.nanoen.2019.104273 Cheng, 2020, Achieving an unprecedented hydrogen evolution rate by solvent-exfoliated CPP-based photocatalysts, J. Mater. Chem., 8, 5890, 10.1039/C9TA13514F Li, 2020, Z-scheme AgVO3/ZnIn2S4 photocatalysts:“One Stone and Two Birds” strategy to solve photocorrosion and improve the photocatalytic activity and stability, Chem. Eng. J. Li, 2020, Confinement of ultrasmall CoFe2O4 nanoparticles in hierarchical ZnIn2S4 microspheres with enhanced interfacial charge separation for photocatalytic H2 evolution, J. Colloid Interface Sci., 581, 764, 10.1016/j.jcis.2020.08.019 Liao, 2022, Donor-acceptor organic semiconductor heterojunction nanoparticles for efficient photocatalytic H2 evolution, Matter, 5, 1635, 10.1016/j.matt.2022.05.001 Liao, 2021, Emerging polymeric carbon nitride Z-scheme systems for photocatalysis, Cell Rep. Phys. Sci., 2 Li, 2021, Interface engineering of Co9S8/CdIn2S4 ohmic junction for efficient photocatalytic H2 evolution under visible light, J. Colloid Interface Sci., 600, 794, 10.1016/j.jcis.2021.05.084 Yang, 2021, 1D/2D carbon-doped nanowire/ultra-thin nanosheet g-C3N4 isotype heterojunction for effective and durable photocatalytic H2 evolution, Int. J. Hydrogen Energy, 46, 25436, 10.1016/j.ijhydene.2021.05.066 Yang, 2022, Ultrathin porous carbon nitride nanosheets with well-tuned band structures via carbon vacancies and oxygen doping for significantly boosting H2 production, Appl. Catal. B Environ., 314, 10.1016/j.apcatb.2022.121521 Li, 2022, Interior and surface synergistic modifications modulate the SnNb2O6/Ni-doped ZnIn2S4 S-scheme heterojunction for efficient photocatalytic H2 evolution, Inorg. Chem., 61, 4681, 10.1021/acs.inorgchem.1c03936 Li, 2022, Photocatalysis over NH2-UiO-66/CoFe2O4/CdIn2S4 double p-n junction: significantly promoting photocatalytic performance by double internal electric fields, Chem. Eng. J., 435 Tan, 2022, EDOT-based conjugated polymers accessed via C–H direct arylation for efficient photocatalytic hydrogen production, Chem. Sci., 13, 1725, 10.1039/D1SC05784G Liao, 2022, Emerging frontiers of Z-scheme photocatalytic systems, Trends Chem, 4, 111, 10.1016/j.trechm.2021.11.005 Liao, 2022, Z-scheme systems: from fundamental principles to characterization, synthesis, and photocatalytic fuel-conversion applications, Phys. Rep., 983, 1, 10.1016/j.physrep.2022.07.003 Zhu, 2023, Photocatalytic degradation of organic pollutants over MoS2/Ag-ZnFe2O4 Z-scheme heterojunction: revealing the synergistic effects of exposed crystal facets, defect engineering, and Z-scheme mechanism, Chem. Eng. J., 453, 10.1016/j.cej.2022.139775 Zhai, 2022, Waste textile reutilization via a scalable dyeing technology: a strategy to enhance dyestuffs degradation efficiency, Adv. Fiber Mater., 10.1007/s42765-022-00192-1 Chaukura, 2019, Photodegradation of humic acid in aqueous solution using a TiO2-carbonaceous hyper-cross-linked polystyrene polymer nanocomposite, Int. J. Environ. Sci. Technol., 16, 1603, 10.1007/s13762-018-1755-2 Hojamberdiev, 2019, Amorphous Fe2O3 nanoparticles embedded into hypercrosslinked porous polymeric matrix for designing an easily separable and recyclable photocatalytic system, Appl. Surf. Sci., 466, 837, 10.1016/j.apsusc.2018.10.098 Zhao, 2019, Cu2O nanoparticle hyper-cross-linked polymer composites for the visible-light photocatalytic degradation of methyl orange, ACS Appl. Nano Mater., 2, 2706, 10.1021/acsanm.9b00210 Razzaque, 2020, Synthesis of surface functionalized hollow microporous organic capsules for doxorubicin delivery to cancer cells, Polym. Chem., 11, 2110, 10.1039/C9PY01772K Razzaque, 2017, Development of functionalized hollow microporous organic capsules encapsulating morphine–an in vitro and in vivo study, J. Mater. Chem. B, 5, 742, 10.1039/C6TB02497A Mo, 2022, A nanoarchitectonic approach enables triple modal synergistic therapies to enhance antitumor effects, ACS Appl. Mater. Interfaces, 14, 10001, 10.1021/acsami.1c20416 Liang, 2022, Manganese-based hollow nanoplatforms for MR imaging-guided cancer therapies, Biomater. Res., 26, 32, 10.1186/s40824-022-00275-5 Liao, 2022, Emerging carbon-supported single-atom catalysts for biomedical applications, Matter, 5, 3341, 10.1016/j.matt.2022.07.031 Zhang, 2022, Recent advances in near-infrared-II hollow nanoplatforms for photothermal-based cancer treatment, Biomater. Res., 26, 61, 10.1186/s40824-022-00308-z Wu, 2022, Hyaluronic-acid-coated chitosan nanoparticles for insulin oral delivery: fabrication, characterization, and hypoglycemic ability, Macromol. Biosci., 22, 10.1002/mabi.202270020 Yang, 2022, NIR-II-Triggered composite nanofibers to simultaneously achieve intracranial hemostasis, killing superbug and residual cancer cells in brain tumor resection surgery, Adv. Fiber Mater. Wang, 2022, Structural and interfacial effects on drug release kinetics of liquid-based fibrous catheter, Adv. Fiber Mater. Li, 2013, Hollow microporous organic capsules, Sci. Rep., 3, 2128, 10.1038/srep02128 Gencoglu, 2014, Electrochemical detection techniques in micro-and nanofluidic devices, Microfluid. Nanofluidics, 17, 781, 10.1007/s10404-014-1385-z Liao, 2020, Emerging graphitic carbon nitride-based materials for biomedical applications, Prog. Mater. Sci. Xu, 2018, A novel fluorescent biosensor for adenosine triphosphate detection based on a metal–organic framework coating polydopamine layer, Materials, 11, 1616, 10.3390/ma11091616 Li, 2022, Development of electroactive materials-based immunosensor towards early-stage cancer detection, Coord. Chem. Rev., 471, 10.1016/j.ccr.2022.214723 Li, 2022, Rapid and selective on-site detection of triacetone triperoxide based on visual colorimetric method, J. Chem. Res. Šálek, 2011, Immunomagnetic sulfonated hypercrosslinked polystyrene microspheres for electrochemical detection of proteins, J. Mater. Chem., 21, 14783, 10.1039/c1jm12475g Razzaque, 2019, Facile synthesis of hypercrosslinked hollow microporous organic capsules for electrochemical sensing of CuII ions, Chem. Eur J., 25, 548, 10.1002/chem.201803643 Branchi, 2018, Highly ion selective hydrocarbon-based membranes containing sulfonated hypercrosslinked polystyrene nanoparticles for vanadium redox flow batteries, J. Membr. Sci., 563, 552, 10.1016/j.memsci.2018.06.022 Jia, 2022, Renewable plant-derived lignin for electrochemical energy systems, Trends Biotechnol., 40, 1425, 10.1016/j.tibtech.2022.07.017 Wu, 2022, Design and development of nucleobase modified sulfonated poly(ether ether ketone) membranes for high-performance direct methanol fuel cells, J. Mater. Chem., 10, 19914, 10.1039/D2TA03166C Li, 2018, Preparation of novel fluorinated copolyimide/amine-functionalized sepia eumelanin nanocomposites with enhanced mechanical, thermal, and UV-shielding properties, Macromol. Mater. Eng., 303, 10.1002/mame.201700407 Wang, 2019, Novel activated N-doped hollow microporous carbon nanospheres from pyrrole-based hyper-crosslinking polystyrene for supercapacitors, React. Funct. Polym., 143, 10.1016/j.reactfunctpolym.2019.104326 Lv, 2012, Hypercrosslinked large surface area porous polymer monoliths for hydrophilic interaction liquid chromatography of small molecules featuring zwitterionic functionalities attached to gold nanoparticles held in layered structure, Anal. Chem., 84, 8457, 10.1021/ac302438m Hradil, 2005, Heterogeneous membranes filled with hypercrosslinked microparticle adsorbent, React. Funct. Polym., 65, 57, 10.1016/j.reactfunctpolym.2004.10.005 Hradil, 2007, Heterogeneous membranes based on a composite of a hypercrosslinked microparticle adsorbent and polyimide binder, React. Funct. Polym., 67, 432, 10.1016/j.reactfunctpolym.2007.02.004 Li, 2017, Wettable magnetic hypercrosslinked microporous nanoparticle as an efficient adsorbent for water treatment, Chem. Eng. J., 326, 109, 10.1016/j.cej.2017.05.049 Sidorov, 1999, Cobalt nanoparticle formation in the pores of hyper-cross-linked polystyrene: control of nanoparticle growth and morphology, Chem. Mater., 11, 3210, 10.1021/cm990274p Wang, 2019, Hollow hyper-cross-linked polymer microspheres for efficient rhodamine B adsorption and CO2 capture, J. Chem. Eng. Data, 64, 1662, 10.1021/acs.jced.8b01197