Hydrothermal synthesis and structural characterization: a novel α-Keggin unit supported zinc-bipyridyl complex [Zn(2,2′-bipy)3]2[ZnW12O40Zn(2,2′-bipy)2]·H2O

Inorganic Chemistry Communications - Tập 6 Số 9 - Trang 1272-1274 - 2003
Jingyang Niu1, Zi-Liang Wang1, Jingping Wang1
1School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, PR China

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Tài liệu tham khảo

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Crystal data: C80H66N16O41W12Zn4: M=4376.12, monoclinic, space group P21/n, a=26.257(5) Å, b=13.877(3) Å, c=28.451(6), β=97.83(3)°, V=10270(4) Å3, Z=4, Dc=2.831 g cm−3, μ=14.381 mm−1, T=293(2) K. R1=0.0660 for 16326 independent reflections. The structures were solved by direct methods and refined by a full-matrix least squares technique based on F2 using the SHELXTL-97 program. CCDC reference number 204619

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