Hydrothermal synthesis and crystal structure of a new 2D metal-organic framework: [Gd(Oba)(Ox)0.5(H2O)2] n (H2Oba = 4,4′-oxybis(benzoic acid); H2Ox = oxalic acid)

Russian Journal of Coordination Chemistry - Tập 38 - Trang 305-308 - 2012
S. Sun1, M. Y. Zhang1, G. X. Zhang1, Z. B. Han1
1College of Chemistry, Liaoning University, Shenyang, P.R. China

Tóm tắt

A new coordination polymer [Gd(Oba)(Ox)0.5(H2O)2] n (I) (H2Oba = 4,4′-oxybis(benzoic acid), H2Ox = oxalic acid) has been synthesized by hydrothermal reactions and characterized by elemental analysis and single-crystal X-ray diffraction. In I, two Gd3+ ions are bridged by Oba ligands to form 1D ribbon chains, which are further connected by Ox ligands, generating a 2D layer structure.

Tài liệu tham khảo

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