Hydrothermal gasification of different agricultural wastes in supercritical water media for hydrogen production: a comparative study
Tóm tắt
Conversion of different agricultural residues including almond shell, walnut shell, barley straw, canola stalk, rice straw and wheat straw to hydrogen-rich gas was performed via gasification in supercritical water media in a determined condition. Elemental characterization was performed using CHNSO analyzer. Besides, cellulose and lignin contents in biomass structure were determined according to TAPPI test methods T264cm-97 and T222om-02, respectively. The correlations between the yields of the product gas components with C/H/O ratio in the initial forms of used feedstocks were investigated. In addition, the relation between the components of biomass structure with the yields of main gaseous products was also studied for each feedstock. The maximum hydrogen yield of 8.38 mmol/g was observed for barley straw which has the highest H percentage of 6.5 wt%. Canola stalk with the highest C/H ratio showed the highest total gas yield of 25.3 mmol/g. Canola stalk with highest amount of cellulose and hemicellulose of 67.42 % had the highest CGE of 45 % and barley straw had the highest HGE of 20 %. Higher C/H value and lower oxygen percentage in the initial form of feedstocks resulted in higher total gas and CO2 yields and lower hydrogen yields. Lignin content in the initial form of the feedstocks was inversely proportional with total gas yields whereas cellulose content showed a straight relation with the total gas yield.
Tài liệu tham khảo
Wuebbles DJ, Jain AK (2001) Concerns about climate change and the role of fossil fuel use. Fuel Proc Technol 71:99–119
Ballarin A, Vecchiato D, Tempesta T, Marangon F, Troiano S (2011) Biomass energy production in agriculture: a weighted goal programming analysis. Energy Policy 39:1123–1131
Tekin K, Karagöz S, Bektaş S (2014) A review of hydrothermal biomass processing. Renew Sustain Energy Rev 40:673–687
Gerssen-Gondelachs SJ, Saygin D, Wicke B, Patel MK, Faaij APC (2014) Competing uses of biomass: assessment and comparison of the performance of bio-based heat, power, fuels and materials. Renew Sust Energy Rev 40:964–998
Tanksale A, Beltramini JN, Lu GM (2010) A review of catalytic hydrogen production processes from biomass. Renew Sust Energy Rev 14:166–182
Tekin K, Karagöz S (2012) Non-catalytic and catalytic hydrothermal liquefaction of biomass. Res Chem Intermed 39(2):485–498
IEA (2014) Key World Energy Statistics. OECD Publishing, Paris, France
Kobayashi H, Fukuoka A (2013) Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass. Green Chem 15:1740–1763
Safari F, Tavasoli A, Ataei A, Choi JK (2015) Hydrogen and syngas production from gasification of lignocellulosic biomass in supercritical water media. Int J Recycl Org Waste Agric 4:121–125
Najjar YSH (2013) Hydrogen safety: the road toward green technology. Int J Hydrogen Energy 38:10716–10728
Ding N, Azargohar R, Dalai AK, Kozinski JA (2014) Catalytic gasification of cellulose and pinewood to H2 in supercritical water. Fuel 118:416–425
Marone A, Izzo G, Mentuccia L, Massini G, Paganin P, Rosa S, Varrone C, Signorini A (2014) Vegetable waste as substrate and source of suitable microflora for bio-hydrogen production. Renew Energ 68:6–13
Midilli A, Dincer I (2008) Hydrogen as a renewable and sustainable solution in reducing global fossil fuel consumption. Int J Hydrogen Energy 33:4209–4222
Dincer I, Zamfirescu C (2012) Sustainable hydrogen production options and the role of IAHE. Int J Hydrogen Energy 37:16266–16286
Parthasarathy P, Narayanan KS (2014) Hydrogen production from steam gasification of biomass: influence of process parameters on hydrogen yield—a review. Renew Energy 66:570–579
Kalinci Y, Hepbasli A, Dincer I (2009) Biomass-based hydrogen production: a review and analysis Int. J Hydrogen Energy 34:8799–8817
Balat M (2010) Thermochemical routes for biomass-based hydrogen production. Energy Sources Part A 32:1388–1398
Akalın MK, Karagöz S (2014) Analytical pyrolysis of biomass using gas chromatography coupled to mass spectrometry. TrAC Trends Anal Chem 61:11–16
Mehrani R, Barati M, Tavasoli A, Karimi A (2015) Hydrogen production via supercritical water gasification of bagasse using Ni–Cu/γ-Al2O3 Nano-catalysts. Environ Technol 36:1265–1272
Zhang L, Xu C, Champagne P (2010) Overview of recent advances in thermo-chemical conversion of biomass. Energy Convers Manage 51:969–982
Guo Y, Wang SZ, Xu DH, Gong YM, Ma HH, Tang XY (2010) Review of catalytic supercritical water gasification for hydrogen production from biomass. Renew Sust Energy Rev 14:334–343
Lu YJ, Guo LJ, Ji CM, Zhang XM, Hao XH, Yan QH (2006) Hydrogen production by biomass gasification in supercritical water: a parametric study. Int J Hydrogen Energy 31:822–831
Guo LJ, Lu YJ, Zhang XM, Ji CM, Guan Y, Pei AX (2007) Hydrogen production by biomass gasification in supercritical water: a systematic experimental and analytical study. Catal Today 129:275–286
Madenoglu TG, Kurt S, Saglam M, Yuksel M, Gokkaya D, Ballice L (2012) Hydrogen production from some agricultural residues by catalytic subcritical and supercritical water gasification. J Supercrit Fluids 67:22–28
Madenoglu TG, Yildirir E, Saglam M, Yuksel M, Ballice L (2014) Improvement in hydrogen production from hard-shell nut residues by catalytic hydrothermal gasification. J Supercrit Fluids 67:22–28
Afif E, Azadi P, Farnood R (2011) Catalytic hydrothermal gasification of activated sludge. Appl Catal B Environ 105:136–143
Barati M, Babatabar M, Tavasoli A, Dalai AK, Das U (2014) Hydrogen production via supercritical water gasification of bagasse using unpromoted and zinc promoted Ru/γ-Al2O3 nanocatalysts. Fuel Proc Technol 123:140–148
Resende FLP, Fraley SA, Berger MJ, Savage PE (2008) Noncatalytic gasification of lignin in supercritical water. Energy Fuel 22:1328–1334
Zeng J, Singh D, Laskar DD, Chen S (2013) Degradation of native wheat straw lignin by Streptomyces viridosporus T7A. Int J Environ Sci Technol 10:165–174
Azadi P, Khan S, Stroble F, Azadi F, Farnood R (2012) Hydrogen production from cellulose, lignin, bark and model carbohydrates in supercritical water using nickel and ruthenium catalysts. Appl Catal B Environ 117–118:330–338
Safari F, Salimi M, Tavasoli A, Ataei A (2016) Non-catalytic conversion of wheat straw, walnut shell and almond shell into hydrogen rich gas in supercritical water media. Chin J Chem Eng. doi:10.1016/j.cjche.2016.03.002
Boswell JG (2006) The biological decomposition of celluloe. New Phytol 40:20–34
Waldner MH, Vogel F (2005) Renewable production of methane from woody biomass by catalytic hydrothermal gasification. Ind Eng Chem Res 44:4543–4551
Mosier N, Wyman C, Dale B, Elander R, Lee YY, Holtzapple M, Laadisch M (2005) Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresour Technol 97:673–686
Carrier M, Loppinet-Serani A, Absalon C, Aymonier C, Mench M (2012) Degradation pathways of holocellulose, lignin and α-cellulose from Pteris vittata fronds in sub- and super critical conditions. Biomass Bioenerg 43:65–71
Reddy SN, Nanda S, Dalai AK, Kozinski JA (2014) Supercritical water gasification of biomass for hydrogen production. Int J Hydrogen Energy 39:6912–6926
Brebu M, Vasile C (2010) Thermal degradation of lignin—a review. Cell Chem Technol 44:353–363
Susanti RF, Dianinngrum LW, Yum T, Kim Y, Lee Y, Kim J (2014) High-yield hydrogen production by supercritical water gasification of various feedstocks: alcohols, glucose, glycerol and long-chain alkanes. Chem Eng Res Des 92:1834–1844
Resende FLP, Savage PE (2015) Kinetic model for noncatalytic supercritical water gasification of cellulose and lignin. AIChE J 6:2412–2420
Rashidi M, Tavasoli A (2015) Hydrogen rich gas production via supercritical water gasification of sugarcane bagasse using unpromoted and copper promoted Ni/CNT nanocatalysts. J Supercrit Fluids 98:111–118
TAPPI T 222 om-02 (2002) Acid insoluble lignin in wood and pulp. http://www.tappi/org. Accessed June 2015
TAPPI T 264 cm-97 (1997) Sampling and preparing wood for chemical analysis. http://www.tappi/org. Accessed June 2015
Parsons JL (1963) Holocellulose in wood. Standard Methods Chem Anal 2:1732–1734. http://www.sciencedirect.com/science/article/pii/S0960852413000722
Ding N, Azargohar R, Dalai AK, Kozinski JA (2014) Catalytic gasification of glucose to H2 in supercritical water. Fuel Proc Technol 127:33–40
Yoon SY, Han SH, Shin SJ (2011) The effect of hemicelluloses and lignin on acid hydrolysis of cellulose. Energy 77:19–24
Ju X, Engelhard M, Zhang X (2013) An advanced understanding of the specific effects of xylan and surface lignin contents on enzymatic hydrolysis of lignocellulosic biomass. Bioresour Technol 132:137–145