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Xử lý hydroformyl hóa các alkene trên rhodium hỗ trợ trong khung tổ chức kim loại-hữu cơ ZIF-8
Tóm tắt
Một khung tổ chức kim loại-hữu cơ (MOF) ZIF-8 có độ xốp cao và tinh thể đã được tổng hợp và sử dụng để chế tạo một chất xúc tác hỗ trợ nanoparticle rhodium (Rh@ZIF-8). Vật liệu đã được đặc trưng bằng PXRD, TEM, EDX, ICP-AES và hấp thụ nitơ. Các đặc tính xúc tác của Rh@ZIF-8 đã được nghiên cứu trong quá trình hydroformyl hóa các alkene, với chiều dài chuỗi và cấu trúc khác nhau, tạo ra các aldehyde tương ứng và cho thấy độ hoạt động cao. Hơn nữa, sau khi phản ứng hoàn tất, chất xúc tác có thể được tách ra dễ dàng khỏi sản phẩm bằng cách lật nghiêng đơn giản và được tái sử dụng năm lần mà không có sự suy giảm đáng kể về độ hoạt động dưới điều kiện nghiên cứu.
Từ khóa
#Khung tổ chức kim loại-hữu cơ #ZIF-8 #Rhodium #xúc tác #hydroformyl hóa #aldehyde.Tài liệu tham khảo
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