Hydrocarbon Reformer Trap by Use of Transition Metal Oxide-Incorporated Beta Zeolites

Catalysis Letters - Tập 118 - Trang 72-78 - 2007
Masaru Ogura1, Tatsuya Okubo2, Shanmugam P. Elangovan2
1Institute of Industrial Science, The University of Tokyo, Tokyo, Japan
2Department of Chemical System Engineering, The University of Tokyo, Tokyo, Japan

Tóm tắt

The concept of a hydrocarbon reformer trap is proposed as a novel technology for cleaning up automobile emissions. Zeolite beta with/without metal species such as iron, manganese, or cobalt is synthesized through a solid phase transformation of mesoporous (metallo)aluminosilicate MCM-41 along with tetraethylammonium cations for structure direction to zeolite beta. The microporosity of zeolite functions as a hydrocarbon trap, and the metal species inside the pores provide a reforming site.

Tài liệu tham khảo

Taylor KC (1990) CHEMTECH 551

Haaβ F, Fuess H (2005) Adv Eng Mater 7:899

Kanazawa T (2004) Catal Today 96:171

Otto K, Montreuil CN, Todor O, McCabe RW, Gandhi HS (1991) Ind Eng Chem Res 30:2333

Lafyatis DS, Ansell GP, Bennett SC, Frost JC, Millington PJ, Rajaram RR, Walker AP, Ballinger TH (1998) Appl Catal B18:123

Yamamoto S (2003) Petrotech 26:119

Burke NR, Trimm DL, Howe RF (2003) Appl Catal B46:97

Liu X, Lampert JK, Arendarskiia DA, Farrauto RJ (2001) Appl Catal B35:125

Czaplewski KF, Reitz TL, Kim YJ, Snurr RQ (2002) Micropor Mesopor Mater 56:55

Elangovan SP, Ogura M, Davis ME, Okubo T (2004) J Phys Chem B108:13059

Elangovan SP, Ogura M, Zhang Y, Chino N, Okubo T (2005) Appl Catal B57:31

Yang BL, Kung HH (1994) Environ Sci Technol 28:1561

Baek S-W, Kim J-R, Ihm S-K (2004) Catal Today 93–95:575

Choudhary VR, Deshmukh GM, Mishra DP (2005) Energ Fuel 19:54

Lopez-Fonseca R, Elizundia U, Landa I, Gutierrez-Ortiz MA, Gonzalez-Velasco JR (2005) Appl Catal B61:150

Centi G, Lanzafame P, Perathoner S (2005) Catal Today 99:161

Takewaki T, Hwang S-J, Yamashita H, Davis ME (1999) Micropor Mesopor Mater 32:265

Matsukata M, Ogura M, Osaki T, Rao PRHP, Nomura M, Kikuchi E (1999) Top Catal 9:77

Yoshimoto R, Hara K, Okumura K, Katada N, Niwa M (2007) J Phys Chem C111:1474

Yoshimoto R, Ninomiya T, Okumura K, Niwa M (2006) 97th CATSJ (Catalysis Society of Japan) Meeting Abstracts, 1A08

Machado NRCF, Calsavara V, Astrath NGC, Matsuda CK, Junior AP, Baesso ML (2005) Fuel 84:2064

Zhang C-H, Wan H-J, Yang Y, Xiang H-W, Li Y-W (2006) Catal Commun 7:733

Heimrich MJ, Smith LR, Kitowski J (1992) SAE Paper 920847

Engler BH, Lindner D, Lox ES, Ostgathe K, Schafer-Sindlinger A, Muller W (1993) SAE Paper 930738

Li H-X, Donohue JM, Cormier WE, Chu YF (2005) Stud Surf Sci Catal 158:1375