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Hợp chất hydrazide Schiff base chứa đơn vị triphenylphosphonium dùng để cảm biến huỳnh quang Al3+ và ứng dụng trong mẫu thực tế
Journal of Fluorescence - Trang 1-8 - 2023
Tóm tắt
Sự dư thừa Al3+ trong cơ thể có thể gây ra nhiều bệnh. Do đó, việc phát triển các cảm biến hóa học để phát hiện Al3+ là rất cần thiết. Một hợp chất hydrazide Schiff base chứa các đơn vị triphenylphosphonium (ER) đã được tổng hợp và sử dụng làm cảm biến huỳnh quang để phát hiện Al3+. Việc phát hiện Al3+ giữa các kim loại khác nhau đã được thực hiện thành công thông qua sự hình thành các phức hợp phối trí Al3+-ligand. Để phát hiện Al3+, tính chất “bật sáng” của cảm biến huỳnh quang đã được nghiên cứu. Các nghiên cứu cảm biến huỳnh quang được thực hiện trong môi trường CH3OH-Nước (v/v, 9/1, pH 7.0) tại λem = 528 nm. Giới hạn phát hiện (LOD) cho việc cảm biến Al3+ được xác định là 0.129 µM. Bằng cách sử dụng đồ thị Job, tỉ lệ tỷ stoichiometric của ER- Al3+ được xác định là 1:1. Hằng số liên kết được xác định là 1.7 × 107 M−1 giữa Al3+ và cảm biến hóa học ER. Cuối cùng, việc xác định Al3+ trong trà thảo mộc thực tế đã được thực hiện bằng cách sử dụng chức năng cảm biến của cảm biến ER.
Từ khóa
#Al3+ #cảm biến huỳnh quang #hợp chất Schiff base #triphenylphosphonium #phức hợp phối tríTài liệu tham khảo
Quang DT, Kim JS (2010) Fluoro- and chromogenic chemodosimeters for heavy metal ion detection in solution and biospecimens. Chem Rev 110:6280–6301
Paquin F, Rivnay J, Salleo A, Stingelin N, Silva C (2015) Multi-phase semicrystalline microstructures drive exciton dissociation in neat plastic semiconductors. J Mater Chem C 3:10715–10722
Arjunan S, Gopalan S, Selvaraj S, Thangaraj S, Krishna K, Nanjan B, Raju N, Palathurai Subramaniam M (2018) A selective fluorescence Chemosensor: pyrene motif Schiff base derivative for detection of Cu2 + ions in living cells. J Photochem Photobiol A Chem 364:424–432
Saravanan A, Shyamsivappan S, Suresh T, Subashini G, Kadirvelu K, Bhuvanesh N, Nandhakumar R, Mohan PS (2019) An efficient new dual fluorescent pyrene based Chemosensor for the detection of bismuth (III) and aluminium (III) ions and its applications in bio-imaging. Talanta 198:249–256
Ghorai A, Mondal J, Chowdhury S, Patra GK (2016) Solvent-dependent fluorescent-colorimetric probe for dual monitoring of Al3 + and Cu2 + in aqueous solution: an application to bio-imaging. Dalt Trans 45:11540–11553
Velmurugan K, Mathankumar S, Santoshkumar S, Amudha S, Nandhakumar R (2015) Specific fluorescent sensing of aluminium using naphthalene benzimidazole derivative in aqueous media. Spectrochim Acta - Part A Mol Biomol Spectrosc 139:119–123
Xu Y, Mao S, Peng H, Wang F, Zhang H, Aderinto SO, Wu H (2017) A fluorescent sensor for selective recognition of Al3 + based on naphthalimide Schiff-base in aqueous media. J Lumin 192:56–63
Alam R, Bhowmick R, Islam ASM, Katarkar A, Chaudhuri K, Ali M (2017) A rhodamine based fluorescent trivalent sensor (Fe3+, Al3+, Cr3+) with potential applications for live cell imaging and combinational logic circuits and memory devices. New J Chem 41:8359–8369
Kim SH, Choi HS, Kim J, Lee SJ, Quango DT, Kim JS (2010) Novel optical/electrochemical selective 1,2,3-triazole ring-appended chemosensor for the Al3 + ion. Org Lett 12:560–563
Soni MG, White SM, Flamm WG, Burdock GA (2001) Safety evaluation of dietary aluminum. Regul Toxicol Pharmacol 33:66–79
Baylor NW, Egan W, Richman P (2002) Aluminum salts in vaccines - US perspective. Vaccine 20:18–23
Khaw BA, Beller GA, Haber E, Gold HK, Leinbach R, Fallon JT, Strauss W, Pohost GM, Strauss HW, Katz AM, Doris I, Repke CT, Rubin BB, Jose S, Scott JA, Leder CD, Miller SW (1965) Covaspheres were purchased from Covalent Technology Corporation. Circ Res 19:611
Pugliano N, Saykally RJ (1992) Measurement of quantum tunneling between chiral isomers of the cyclic water trimer. Sci (80-) 257:1937–1940
Mashhadizadeh MH, Khani H (2010) Sol-Gel-Au nano-particle modified carbon paste electrode for potentiometric determination of sub ppb level of Al(iii). Anal Methods 2:24–31
He H, Li Y, He LF (2019) Aluminum toxicity and tolerance in Solanaceae plants. South Afr J Bot 123:23–29
Han T, Feng X, Tong B, Shi J, Chen L, Zhi J, Dong Y (2012) A novel turn-on fluorescent chemosensor for the selective detection of Al3 + based on aggregation-induced emission. Chem Commun 48:416–418
García-Medina S, Razo-Estrada AC, Gómez-Oliván LM, Amaya-Chávez A, Madrigal-Bujaidar E, Galar-Martínez M (2010) Aluminum-induced oxidative stress in lymphocytes of common carp (Cyprinus carpio). Fish Physiol Biochem 36:875–882
Rahman FU, Ali A, Khalil SK, Guo R, Zhang P, Wang H, Li ZT, Zhang DW (2017) Tuning sensitivity of a simple hydrazone for selective fluorescent turn on chemo-sensing of Al3 + and its application in living cells imaging. Talanta 164:307–313
Alam P, Leung NLC, Zhang J, Kwok RTK, Lam JWY, Tang BZ (2021) AIE-based luminescence probes for metal ion detection. Coord Chem Rev 429
Razi SS, Ali R, Srivastava P, Misra A (2014) A selective quinoline-derived fluorescent chemodosimeter to detect Cyanide in aqueous medium. Tetrahedron Lett 55:1052–1056
Bulhac I, Ureche D, Kravtsov V, Bourosh P (2023) Synthesis and structure of Heterometallic compounds with Dimethyl Pyridine-2,6-dicarboxylate. Russ J Coord Chem Khimiya 49:77–85
Talouki SA, Grivani G, Khalaji AD (2018) Six-coordinated vanadium(IV) complexes with tridentate task-specific ionic liquid Schiff base ligands: synthesis, characterization and effect of ionic nature on catalytic activity. Appl Organomet Chem 32:1–12
Dong WK, Sun YX, Xing SJ, Wang Y, Gao XH (2012) An asymmetric salen-type bisoxime ligand and its supramolecular copper(II) complex: synthesis, crystal structure and spectral properties. Z fur Naturforsch - Sect B J Chem Sci 67:197–203
Shi Z, Tang X, Zhou X, Cheng J, Han Q, Zhou JA, Wang B, Yang Y, Liu W, Bai D (2013) A highly selective fluorescence turn-on probe for Cu(II) based on reaction and its imaging in living cells. Inorg Chem 52:12668–12673
Lmei L, Yang Z (2018) yin A new off-on fluorescent sensor for the detection of Al(III) based on a chromone-derived Schiff-base. Inorganica Chim Acta 469:588–592
Qin JC, Yang ZY, Yang P (2015) Recognition of Al3 + based on a naphthalene-based off-On chemosensor in near 100% aqueous media. Inorganica Chim Acta 432:136–141
Suresh S, Bhuvanesh N, Prabhu J, Thamilselvan A, Rjr S, Kannan K, Rk V, Nandhakumar R (2018) Pyrene based chalcone as a reversible fluorescent chemosensor for Al3 + ion and its biological applications. J Photochem Photobiol A Chem 359:172–182
Kumar V, Kumar P, Kumar S, Singhal D, Gupta R (2019) Turn-on fluorescent sensors for the selective detection of Al3+ (and Ga3+) and PPi ions. Inorg Chem 58:10364–10376
Wang W, Mao Z, Wang M, Liu LJ, Kwong DWJ, Leung CH, Ma DL (2016) A long lifetime luminescent iridium(iii) complex chemosensor for the selective switch-on detection of Al3 + ions. Chem Commun 52:3611–3614
Hou L, Feng J, Wang Y, Dong C, Shuang S, Wang Y (2017) Single fluorescein-based probe for selective colorimetric and fluorometric dual sensing of Al3 + and Cu2+. Sens Actuators B Chem 247:451–460