Highly efficient removal of As(V) using metal–organic framework BUC-17
Tóm tắt
Arsenic contamination is a great threat worldwide due to its toxicity and hardly degradable. The development of highly efficient adsorbents is an essential challenge in the water treatment field. A 2D metal–organic framework [Co3(tib)2(H2O)12](SO4)3 (BUC-17) has been synthesized by hydrothermal method, and was utilized as an efficient adsorbent to remove As(V) from contaminated water. The results showed that BUC-17 have higher adsorption capacity toward As(V) than most counterpart adsorbents, its maximum uptake capacity reached 129.2 mg g−1 at 298 K. The adsorption kinetics and isotherm behaviors were well fitted with pseudo-second-order and Langmuir model, respectively. The thermodynamic parameters such as free energy change ΔG°, enthalpy change ΔH° and entropy change ΔS° were both negative during the sorption process, suggesting that the adsorption process of BUC-17 towards As(V) was spontaneous and exothermal. The influence of pH and foreign ions on the adsorptive removal of As(V) using BUC-17 were investigated. The results showed that pH values have significant influence while co-existed anions (unless phosphate) exert slight effect on adsorption capacity. Finally, a corresponding adsorption mechanism was proposed and confirmed by scanning electron microscopy, Fourier Transform infrared spectra (FTIR) and X-ray photoelectron spectroscopy analysis.
Tài liệu tham khảo
Hughes MF et al (2011) Arsenic exposure and toxicology: a historical perspective. Toxicol Sci 123(2):305–332
Song P et al (2017) Electrocoagulation treatment of arsenic in wastewaters: a comprehensive review. Chem Eng J 317:707–725
Choong TSY et al (2007) Arsenic toxicity, health hazards and removal techniques from water: an overview. Desalination 217(1–3):139–166
Mandal BK, Suzuki KT (2002) Arsenic round the world: a review. Talanta 58(1):201–235
Jain CK, Ali I (2000) Arsenic: occurrence, toxicity and speciation techniques. Water Res 34(17):4304–4312
Carlin DJ et al (2016) Arsenic and environmental health: state of the science and future research opportunities. Environ Health Perspect 124(7):890–899
Yu W et al (2019) Metal–organic framework (MOF) showing both ultrahigh As(V) and As(III) removal from aqueous solution. J Solid State Chem 269:264–270
Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17(5):517–568
Nrashant S, Deepak K, Anand PS (2007) Arsenic in the environment : effects on human health and possible prevention. J Theor Biol 28(2):359–365
Kapaj S et al (2006) Human health effects from chronic arsenic poisoning–a review. J Environ Sci Health A Tox Hazard Subst Environ Eng 41(10):2399–2428
Nicomel NR et al (2015) Technologies for arsenic removal from water: current status and future perspectives. Int J Environ Res Public Health 13(1):62
Wu H et al (2018) Arsenic removal from water by metal–organic framework MIL-88A microrods. Environ Sci Pollut Res Int 25(27):27196–27202
Zhang X et al (2017) Simultaneous oxidation and sequestration of As(III) from water by using redox polymer-based Fe(III) oxide nanocomposite. Environ Sci Technol 51(11):6326–6334
Li H et al (2016) Long-term performance of rapid oxidation of arsenite in simulated groundwater using a population of arsenite-oxidizing microorganisms in a bioreactor. Water Res 101(15):393–401
Gill LW, O'Farrell C (2015) Solar oxidation and removal of arsenic–Key parameters for continuous flow applications. Water Res 86(1):46–57
Vahter M (2002) Mechanisms of arsenic biotransformation. Toxicology 181(181–182):211–217
Federico B et al (1987) Cellular uptake and metabolic reduction of pentavalent to trivalent arsenic as determinants of cytotoxicity and morphological transformation. Carcinogenesis 8(6):803–808
Li J et al (2014) Characteristics of arsenate removal from water by metal-organic frameworks (MOFs). Water Sci Technol 70(8):1391–1397
Bissen M, Frimmel FH (2003) Arsenic—a review. Part II: oxidation of arsenic and its removal in water treatment. Acta Hydroch Hydrob 31(2):97–107
Simsek EB, Özdemir E, Beker U (2013) Zeolite supported mono-and bimetallic oxides: promising adsorbents for removal of As(V) in aqueous solutions. Chem Eng J 220(11):402–411
Gupta SK, Chen KY (1978) Arsenic removal by adsorption. Water Pollut Contr Fed 50(3):493–506
Clifford DA, Ghurye G, Tripp AR (2003) Arsenic removal from drinking Water using ion-exchange with spent brinere cycling. J Am Water Works Ass 95(6):119–130
Ng KS, Ujang Z, Le.Clech P (2004) Arsenic removal technologies for drinking water treatment. Rev Environ Sci Biotechnol 3(1):43–53
Huang CP, Fu PLK (1984) Treatment of Arsenic(V)-containing water by the activated carbon process. Water Pollut Contr Fed 56(3):233–242
Gillman GP (2006) A simple technology for arsenic removal from drinking water using hydrotalcite. Sci Total Environ 366(2–3):926–931
Altundogan H, Fikret F (2003) As(V) removal from aqueous solutions by coagulation with liquid phase of red mud. J Environ Sci Health Part A 38(7):1247–1258
Lin TF, Wu JK (2001) Adsorption of arsenite and arsenate within activated alumina grains equilibrium and kinetics. Water Res 35(8):2049–2057
Wang C-C et al (2014) Photocatalytic organic pollutants degradation in metal–organic frameworks. Energy Environ Sci 7(9):2831–2867
Wang C-C, Yi X-H, Wang P (2019) Powerful combination of MOFs and C3N4 for enhanced photocatalytic performance. Appl Catal B 247:24–48
Du X-D et al (2019) Robust photocatalytic reduction of Cr(VI) on UiO-66-NH2(Zr/Hf) metal–organic framework membrane under sunlight irradiation. Chem Eng J 356:393–399
Fu H-F et al (2018) Formation mechanism of rod-like ZIF-L and fast phase transformation from ZIF-L to ZIF-8 with morphology changes controlled by polyvinylpyrrolidone and ethanol. Cryst Eng Comm 20(11):1473–1477
Yi X-H et al (2018) Highly efficient photocatalytic Cr(VI) reduction and organic pollutants degradation of two new bifunctional 2D Cd/Co-based MOFs. Polyhedron 152:216–224
Xie D et al (2017) Bifunctional NH2-MIL-88(Fe) metal–organic framework nanooctahedra for highly sensitive detection and efficient removal of arsenate in aqueous media. J Mater Chem A 5(45):23794–23804
He X et al (2019) Exceptional adsorption of arsenic by zirconium metal-organic frameworks: engineering exploration and mechanism insight. J Colloid Interface Sci 539:223–234
Tian C et al (2018) Enhanced adsorption of p-Arsanilic acid from Water by amine-modified UiO-67 as examined using extended X-ray absorption fine structure, x-ray photoelectron spectroscopy, and density functional theory calculations. Environ Sci Technol 52(6):3466–3475
Jian M et al (2015) Adsorptive removal of arsenic from aqueous solution by zeolitic imidazolate framework-8 (ZIF-8) nanoparticles. Colloid Surface A 465:67–76
Li J et al (2014) Zeolitic Imidazolate framework-8 with high efficiency in trace arsenate adsorption and removal from water. J Phys Chem C 118(47):27382–27387
Li J-J et al (2017) High-performance adsorption and separation of anionic dyes in water using a chemically stable graphene-like metal-organic framework. Dalton Trans 46(31):10197–10201
Guo J, Li J-J, Wang C-C (2019) Adsorptive removal of Cr(VI) from simulated wastewater in MOF BUC-17 ultrafine powder. J Environ Chem Eng 7(1):102909
Ofomaja AE, Naidoo EB, Modise SJ (2010) Kinetic and pseudo-second-order modeling of lead biosorption onto pine cone powder. Ind Eng Chem Res 49(6):2562–2572
Wu YN et al (2014) Amino acid assisted templating synthesis of hierarchical zeolitic imidazolate framework-8 for efficient arsenate removal. Nanoscale 6(2):1105–1112
Vu TA et al (2015) Arsenic removal from aqueous solutions by adsorption using novel MIL-53(Fe) as a highly efficient adsorbent. RSC Adv 5(7):5261–5268
Abu Tarboush BJ et al (2018) Metal–organic framework-74 for ultratrace arsenic removal from water: experimental and density functional theory studies. ACS Appl Nano Mater 1(7):3283–3292
Li Z-Q et al (2015) Facile synthesis of metal–organic framework MOF-808 for arsenic removal. Mater Lett 160:412–414
Yang JC, Yin XB (2017) CoFe2O4@MIL-100(Fe) hybrid magnetic nanoparticles exhibit fast and selective adsorption of arsenic with high adsorption capacity. Sci Rep 7:40955
Faria MCS et al (2014) Arsenic removal from contaminated water by ultrafine δ-FeOOH adsorbents. Chem Eng J 237:47–54
Zhao X, Jia Q, Song N (2010) Adsorption of Pb(II) from an aqueous solution by titanium dioxide/carbon nanotube nanocomposites: kinetics, thermodynamics, and isotherms†. J Chem Eng Data 55(10):4428–4433
Kumar M, Tamilarasan R, Sivakumar V (2013) Adsorption of Victoria blue by carbon/Ba/alginate beads: kinetics, thermodynamics and isotherm studies. Carbohydr Polym 98(1):505–513
Eren E (2009) Removal of basic dye by modified Unye bentonite. Turkey. J Hazard Mater 162(2–3):1355–1363
Bulut Y, Tez Z (2007) Adsorption studies on ground shells of hazelnut and almond. J Hazard Mater 149(1):35–41
Milonjic SK (2007) A consideration of the correct calculation of thermodynamic parameters of adsorption. Serb Chem Soc 72(12):1363–1367
Zaki AB et al (2000) Kinetics and mechanism of the sorption of some aromatic amines onto amberlite IRA-904 anion-exchange resin. J Colloid Interface Sci 221(1):58–63
Du X-D et al (2017) Highly efficient removal of Pb2+ by a polyoxomolybdate-based organic–inorganic hybrid material {(4-Hap)4 [Mo8O26 ]}. J Environ Chem Eng 5(2):1866–1873
Lu P, Zhu C (2010) Arsenic Eh–pH diagrams at 25 °C and 1 bar. Environ Earth Sci 62(8):1673–1683
Heibati B et al (2016) Removal of linear alkyl benzene sulfonate from aqueous solutions by functionalized multi-walled carbon nanotubes. J Mol Liq 213:339–344
Cumbal L, SenGupta AK (2005) Arsenic removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of Donnan membrane effect. Environ Sci Technol 39(17):6508–6515
Chen B et al (2013) Facile synthesis of mesoporous Ce–Fe bimetal oxide and its enhanced adsorption of arsenate from aqueous solutions. J Colloid Interface Sci 398:142–151
Sharma VK, Sohn M (2009) Aquatic arsenic: toxicity, speciation, transformations, and remediation. Environ Int 35(4):743–759
Amita J, Richard HL (2000) Effect of competing anions on the adsorption of arsenate and arsenite by ferrihydrite. J Environ Qual 29(5):1422–1430
Castaldi P et al (2010) Study of sorption processes and FT-IR analysis of arsenate sorbed onto red muds (a bauxite ore processing waste). J Hazard Mater 175(1–3):172–178
Song X-X et al (2018) The selectively fluorescent sensing detection and adsorptive removal of Pb(2+) with a stable [delta-Mo8O26]-based hybrid. J Colloid Interface Sci 532:598–604
Tan X-L et al (2009) Eu(III) sorption to TiO2 (anatase and rutile): batch, XPS, and EXAFS studies. Environ Sci Technol 43(9):3115–3121