High-pressure crystal chemistry of binary intermetallic compounds

Zeitschrift fur Kristallographie - Crystalline Materials - Tập 221 Số 5-7 - Trang 420-434 - 2006
R. Demchyna1, Stefano Leoni1, H. Rösner2, Ulrich Schwarz3
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society
2Helge Rosner, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society
3Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society

Tóm tắt

Abstract Effects of high pressure on intermetallic compounds are reviewed with regards to structural stability and phase transitions. Changes of bonding properties and electronic structure are examplified by means of the elemental metals caesium and titanium, the latter forming an internal intermetallic compound at high pressures. After a short systematic overview regarding pressure effects, structural transformations in selected classes of intermetallic compounds like Zintl phases and AlB2-type arrangements precedes sections concerning high-pressure synthesis of Laves phases and intermetallic clathrates.

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