High-performance size-exclusion chromatography with crosslinked polystyrene. Separation of polymers and oligomers using LiChrogel PS

Springer Science and Business Media LLC - Tập 15 - Trang 347-350 - 1982
R. Wernicke1, F. Eisenbeiß1
1E. Merck, Chemical Research, Darmstadt, FRG

Tóm tắt

A new series of polystyrene-divinyl benzene PS/DVB-based microparticulate packings for size-exclusion chromatography [SEC] is presented. These gel-based packings are characterized by mechanical stability, minimal interaction with solutes and ability to handle a wide variety and size range of polymers and low relative molecular mass samples. Combinations of different pore sizes are discussed and separations of standard polymers and commercial products are shown.

Tài liệu tham khảo

R. E. Majors, J. Chromatogr. Sci.18, 488 (1980). F. Eisenbeiß, E. Dumont, H. Henke, Angew. Makromol. Chem.71, 67 (1978). K. H. Altgelt, I. Segal, Gel Permeation Chromatography, Marcel Dekker, New York, 1971. H. Engelhardt, D. Mathes, J. Chromatogr.185, 305 (1979). R. Ohmacht, I. Halász, Chromatographia14, 155 (1981). W. W. Yau, C. R. Ginnhard, J. J. Kirkland, J. Chromatogr.149, 465 (1978). J. H. Knox, F. McLennan, Chromatographia10, 75 (1977). J. V. Dawkins, Chromatogr. Sci.13, 19 (1980). J. V. Dawkins, G. Yeadon, J. Chromatogr.206, 215 (1981). D. D. Bly, H. J. Stoklosa, J. J. Kirkland, W. W. Yau, Anal. Chem.47, 1810, 2328 (1975).