Siêu tụ điện đối xứng hiệu suất cao trên nền tảng chất lỏng dựa trên cực âm được điện phân một bước của sulfide hỗn hợp niken mangan hình dạng vỏ cây nứt trên vải carbon hoạt tính

Science China Technological Sciences - Tập 65 - Trang 293-301 - 2021
Emin Adil1, WenLu Xie1, Xiao Long1, Xiao Wang1, XiaoQiang Song1, Yue Chen1, YuJun Fu1, JunShuai Li1, YaLi Li1, DeYan He1
1Key Laboratory of Special Function Materials & Structure Design of the Ministry of Education, and School of Materials & Energy, Lanzhou University, Lanzhou, China

Tóm tắt

Trong nghiên cứu này, chúng tôi báo cáo một điện cực siêu tụ điện tự đứng hiệu suất cao của các sulfide niken mangan (NMS) hỗn hợp với hình dạng vỏ cây nứt được phát triển thông qua quy trình điện phân một bước trên vải carbon hoạt tính (ACC). Điện cực này sở hữu các tính chất điện hóa xuất sắc, bao gồm một điện dung riêng cao lên đến 3142.8 F g−1 ở mật độ dòng 1.0 A g−1, hiệu suất ở tốc độ cao (∼ 1206.8 F g−1 ở 60.0 A g−1) và độ ổn định chu kỳ (∼ 92.3% giữ được điện dung sau 8000 chu kỳ ở 8 A g−1). Một siêu tụ điện không đối xứng được lắp ráp với NMS trên ACC làm cực âm, carbon hoạt tính trên vải carbon làm cực dương, và KOH 1.0 mol L−1 làm điện phân, cung cấp một mật độ năng lượng cao đạt 111.2 W h kg−1 ở 800.0 W kg−1 và hiệu suất chu kỳ nổi bật với ∼ 93.2% giữ lại điện dung sau 10000 chu kỳ ở 5 A g−1 với hiệu suất Columbic khoảng 100% trong suốt 10000 chu kỳ này. Hiệu suất cao và sự chuẩn bị dễ dàng chỉ ra rằng NMS trên ACC có tiềm năng to lớn như là điện cực cho các siêu tụ điện.

Từ khóa

#siêu tụ điện #sulfide niken mangan #điện phân một bước #điện cực tự đứng #carbon hoạt tính

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