Điều kiện *$${f_{{{\rm{H}}_2} - }}{f_{{{\rm{S}}_2}}}$$* cao liên quan đến sphalerite trong mỏ kim loại cơ bản và quý Latala, Trung Iran: Những hàm ý về thành phần và điều kiện hình thành của sphalerite

Journal of Earth Science - Tập 31 - Trang 523-535 - 2020
Fariba Padyar1,2, Mohammad Rahgoshay1, Alexander Tarantola3, Marie-Camille Caumon3, Seyed Mohammad Pourmoafi1
1Faculty of Earth Sciences, Shahid Beheshti University-Evin, Tehran, Iran
2Department of Exploration, Geological Survey of Iran, Tehran, Iran
3GeoResources Lab, Faculty of Sciences and Technologies, University of Lorraine, CNRS, Vandoeuvre the Nancy, France

Tóm tắt

Bài báo này trình bày về các đặc điểm của các bao gồm chất lỏng được tìm thấy trong sphalerite từ mỏ kim loại cơ bản và quý Latala (Trung Iran), được chứa trong các khối đá núi lửa – trầm tích thuộc thời đại Kenozoic. Mỏ Latala đại diện cho một ví dụ về kiểu mỏ gân, các mỏ kim loại cơ bản trong các mỏ đồng porphyry Miduk (PCDs) thuộc vành đai núi lửa Urumieh-Dokhtar (UDMB) phía nam. Quá trình khoáng hóa trong mỏ Latala thuộc kiểu gân kim loại cơ bản và quý diễn ra qua 3 giai đoạn, với các gân quartz-sphalerite xuất hiện ở giai đoạn 2 và 3. Giai đoạn 2 các gân quartz-sphalerite liên quan đến chalcopyrite và sphalerite phân vùng, cùng với quartz+hematite, trong khi các gân quartz-sphalerite ở giai đoạn 3 chứa galena+sphalerite+chalcopyrite và quartz với sự phát triển lại của calcite. Quá trình khoáng hóa ở giai đoạn 3 xảy ra dưới dạng các thể thay thế và chứa sphalerite nghèo Fe mà không có sự phân vùng ở các phần ngoài của mỏ. Bài báo này tập trung vào các bao gồm chất lỏng trong các gân chứa sphalerite và quartz. Nhiệt độ đồng nhất hóa và độ mặn của các bao gồm chất lỏng trong sphalerite (một số có sự phân vùng điển hình) dao động từ 144 đến 285 °C và từ 0.2 wt.% đến 7.6 wt.% NaCl tương đương. Sphalerite và các bao gồm chất lỏng của mỏ kim loại cơ bản và quý Latala hình thành từ các dung dịch có nhiệt độ và độ mặn tương đối thấp. Các phân tích quang phổ Raman cho thấy tỉ lệ cao của CO2 trong pha khí của các bao gồm chất lỏng trong các sphalerite nghèo Fe, như dự đoán với nhiệt độ nóng chảy của CO2 là −56.6 °C, và một lượng đáng kể H2. Việc thiếu các loài carbon giảm (metan và các hydrocarbon nhẹ hơn) đã được xác nhận trong nghiên cứu đá mỏng bằng cách sử dụng ánh sáng UV và quang phổ Raman. Lượng lớn H2 trong các bao gồm chất lỏng của sphalerite nghèo Fe có thể là kết quả của các cường độ khác nhau của quá trình biến đổi và khu khuếch tán. Sự xuất hiện chung của CO2 trong các bao gồm chất lỏng có nguồn gốc từ sự thoát khí magma và sự hòa tan của cacbonat. Các giá trị δ34S cho các khoáng chất sulfide trong galena của các gân chứa sphalerite dao động giữa −9.8‰ và −1.0‰, và các giá trị δ34S tính toán cho H2S nằm trong khoảng từ −7.1‰ đến +0.6‰. Những giá trị này tương ứng với lưu huỳnh magma có sự tương tác có thể với các đá vách. Các chất lỏng magma đã được pha loãng liên tiếp trong quá trình làm mát và sự gia tăng liên tục. Sự sôi thứ cấp sẽ dẫn đến một lượng thay đổi của biến đổi kali hoặc dự phòng và sự khuếch tán của hydrogen vào các bao gồm chất trong sphalerite của Latala.

Từ khóa

#sphalerite #Latala #bao gồm chất lỏng #magma #khoáng hóa #vỏ trái đất

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