High-Entropy Alloys – A New Era of Exploitation

Materials Science Forum - Tập 560 - Trang 1-9
Jien-Wei Yeh1, Yu-Liang Chen1, Su Jien Lin1, Swe Kai Chen1
1National Tsing Hua University

Tóm tắt

A high-entropy alloy (HEA) has been defined by us to have at least five principal elements, each of which has an atomic concentration between 5% and 35%. In the exploration on this new alloy field, we find that HEAs are quite simple to analyze and control, and they might be processed as traditional alloys. There exist many opportunities to create novel alloys, better than traditional ones in a wide range of applications. In this paper, we review the basic microstructural features of HEAs and discuss the mechanisms of formation. Instead of multiple intermetallic phases, the HEAs tend to form simple solid solution phases mainly of cubic crystal structure, especially at elevated temperatures. This tendency is explained by the high entropy effect based on the simple relation: (Gmix = (Hmix – T(Smix, and the second law of thermodynamics. Moreover, nanostructures and amorphous phases are easily formed in HEAs. This tendency is explained by kinetics theory as due to slow atomic diffusion.

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Materials Science Forum

Tập 560

1-9

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