Hendrik-Willem Bakhuis Roozeboom: Equilibrium and phase topology
Tóm tắt
Hendrik-Willem Bakhuis Roozeboom (1854–1907) is well known for his applications of the phase rule to the study of heterogeneous equilibrium and its representation using the projection of the P-T-x space into the P-T and T-x planes. Together with van der Waals, he put Gibbs’ abstract studies of phase equilibrium in a language that any chemist could understand and use. The graphical representation of the phenomena of equilibrium had a profound influence in the study of the phase rule and the variety of its applications. With its help, Bakhuis Roozeboom was able to improve significantly the original phase diagram for the system iron-carbon presented by Roberts-Austen. Bakhuis Roozeboom may well be considered one of the pioneers of phase topology.
Tài liệu tham khảo
W. Stortenbeker and H.-G. Bakhuis Roozeboom: Rec. Trav. Chim. Pays-Bas, 1908, 27, pp. 360–410 (in French).
H.J. Bakhuis Roozeboom: “Sur le Bromure Butylique Tertiare,” Ber. Deutsch Chem. Ges., 1881, 14, pp. 2396–400 (in French).
H.S. van Klooster: “Bakhuis Roozeboom and the Phase Rule,” J. Chem. Educ., 1954, 31, 594–97.
H.J. Bakhuis Roozeboom: “Sur l’Hydrate de l’Acide Sulfureux,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 29–58 (in French).
H.J. Bakhuis Roozeboom: “Sur l’Hydrate de Chlore,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 59–72 (in French).
H.J. Bakhuis Roozeboom: “Sur l’Hydrate de Brome,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 73–83 (in French).
H.J. Bakhuis Roozeboom: “Sur l’Hydrate de Gaz Chlorhydrique,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 84–104 (in French).
H. Le Châtelier: “Sur la Dissociation de l’Hydrate de Chlore,” Compt. Rendu, 1884, 99, pp. 1074–77 (in French).
H.J. Bakhuis Roozeboom: “Sur la Dissociation des Hydrates de l’Acide Sulfureux, du Chlore et du Brome,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 65–73 (in French).
H.J. Bakhuis Roozeboom: “Solubilité de l’Acide Bromhydrique à des Températures et Sour des Pressions Différentes,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 102–07 (in French).
H.J. Bakhuis Roozeboom: “Dissociation de l’Hydrate HBr.2H2O,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 108–24 (in French).
J.D. van der Waals: “Influence de la Température sur la Richese en Gaz d’une Solution et Sur l’Equilibre Entre Solutions Gazeuses et des Hydrates Solides,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 135–38 (in French).
H.J. Bakhuis Roozeboom: “Dissociation de l’Hydrate HBr.2H2O”, Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 331–46 (in French).
A. Smits, A. De Beteenkenis, and van J.D. van der Waals Sr.: “Voor de Chemische Wetenshap,” Faraday, 1937, 8, pp. 50–71.
J.W. Gibbs: “On the Equilibrium of Heterogeneous Systems, Part I,” Trans. Connecticut Acad. Sci., 1876, 3, pp. 108–248.
J.W. Gibbs: “On the Equilibrium of Heterogeneous Systems, Part II,” Trans. Connecticut Acad. Sci., 1878, 3, pp. 343–524.
P.M. Duhem: “Étude Thermodynamique sur les Travaux de J. W. Gibbs,” Bull. Soc. Mathematiques [2], 1887, 11, pp. 122, 159 (in French).
H.J. Bakhuis Roozeboom: “Sur les Conditions d’Équilibre de Deux Corps Dans Trois États, Solide, Liquide et Gazeux, d’Après M. v. d. Waals,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 335–50 (in French).
H.J. Bakhuis Roozeboom: “Sur un Nouvel Hydrate de l’Acide Bromhydrique HBr.H2O,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 363–79 (in French).
H.J. Bakhuis Roozeboom: “La Dissociation des Composées Liquids et la Loi de MM. Debray et Wiedemann,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 355–60 (in French).
H.J. Bakhuis Roozeboom: “Dissociation du Composé AzH4Br.3AzH3 à l’État Solide et à l’État Liquide,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 361–78 (in French).
H.J. Bakhuis Roozeboom: “Sur les Combinaisons du Bromure d’Ammonium Avec l’Ammoniaque,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 387–92 (in French).
H.J. Bakhuis Roozeboom: “Solubilité du Chlore Dans l’Oxychlorure de Chrome,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 379–81 (in French).
H.J. Bakhuis Roozeboom: “Sur les Points Quadruples Dans l’Équilibre d’un Système Formé de Deux Corps,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 393–413 (in French).
H.J. Bakhuis Roozeboom: “Application de la Formule de M. v. d. Waals Aux Hydrates de SO2, Cl2, Br2, et à la Glace,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 380–86 (in French).
H.J. Bakhuis Roozeboom: “Sur les Différentes Formes de l’Equilibre Chimique Hétérogène,” Rec. Trav. Chim. Pays-Bas, 1887, 6, pp. 262–303 (in French).
H.J. Bakhuis Roozeboom: “Erstarrungspunkte der Mischkrystalle Zweier Stoffe. Umwandlungspunkte vei Mischkrystallen,” Zeit. Phys. Chem., 1899, 30, pp. 385–412 (in German).
H.J. Bakhuis Roozeboom: Heterogene Gleichgewichte vom Standpunkte Phasenlehre (Heterogeneous Equilibrium from the Standpoint of the Phase Rule), Braunsweig volume 1, 1901, volume 2, 1904 (in German).
H.J. Bakhuis Roozeboom: “Iron and Steel From the Point of View of the Phase Doctrine,” J. Iron Steel Institute, 1900, 2, 311–16. (Also published verbatim in The Metallographist, 1900, 3, pp. 293–300.)
H. Le Châtelier: “Fer et Acier au Point de Vue de la Doctrine des Phases,” Bull. Soc. Enc. Ind. Nationale, 1900, 6, pp. 661–70 (in French).
W.C. Roberts-Austen: Procedures of the 4th Report to the Alloys Research Committee of the Institute of Mechanical Engineers, February 1897.
W.C. Roberts-Austen: Procedures of the 5th Report to the Alloys Research Committee of the Institute of Mechanical Engineers, February 1899.