Halloysite/phenol-formaldehyde nanocomposites with enhanced mechanical properties and lowered fire hazard

Acar, 2021, In-situ preparation of halloysite nanotube-epoxy thermoset nanocomposites via light-induced cationic polymerization, Eur. Polym. J., 158 Cheng, 2020, Halloysite nanotube-based H2O2-responsive drug delivery system with a turn on effect on fluorescence for real-time monitoring, Chem. Eng. J., 380, 10.1016/j.cej.2019.122474 Cheng, 2020, Halloysite nanotubes in polymer science: purification, characterization, modification and applications, Nanotechnol. Rev., 9, 323, 10.1515/ntrev-2020-0024 de Hoyos-Martinez, 2021, Wood fireproofing coatings based on biobased phenolic resins, ACS Sustain. Chem. Eng., 9, 1729, 10.1021/acssuschemeng.0c07505 Du, 2021, High loading BaTiO3 nanoparticles chemically bonded with fluorinated silicone rubber for largely enhanced dielectric properties of polymer nanocomposites, Phys. Chem. Chem. Phys., 23, 26219, 10.1039/D1CP04040E Glotov, 2021, Clay nanotube-metal core/shell catalysts for hydroprocesses, Chem. Soc. Rev., 50, 9240, 10.1039/D1CS00502B Guo, 2008, Biocompatible, luminescent silver@phenol formaldehyde resin core/shell nanospheres: Large-scale synthesis and application for in vivo bioimaging, Adv. Funct. Mater., 18, 872, 10.1002/adfm.200701440 Guo, 2021, Preparation of high-performance silico-aluminophosphate geopolymers using fly ash and metakaolin as raw materials, Appl. Clay Sci., 204, 10.1016/j.clay.2021.106019 Hasan, 2021, Rice straw and energy reed fibers reinforced phenol formaldehyde resin polymeric biocomposites, Cellulose, 28, 7859, 10.1007/s10570-021-04029-9 Ledoux, 1964, Infrared study of selective deuteration of kaolinite and halloysite at room temperature, Science, 145, 47, 10.1126/science.145.3627.47 Lei, 2019, Curing behavior and microstructure of epoxy-POSS modified novolac phenolic resin with different substitution degree, Polymer, 178, 10.1016/j.polymer.2019.121587 Li, 2021, Halloysite nanotubes grafted polylactic acid and its composites with enhanced interfacial compatibility, J. Appl. Polym. Sci., 138 Liao, 2021, Surface modified halloysite nanotubes with different lumen diameters as drug carriers for cancer therapy, Chem. Commun., 57, 9470, 10.1039/D1CC01879E Lisuzzo, 2021, Pickering emulsions based on wax and halloysite nanotubes: an ecofriendly protocol for the treatment of archeological woods, ACS Appl. Mater. Interfaces, 13, 1651, 10.1021/acsami.0c20443 Lvov, 2008, Halloysite clay nanotubes for controlled release of protective agents, ACS Nano, 2, 814, 10.1021/nn800259q Ma, 2019, Enhanced thermal resistance of carbon/phenolic composites by addition of novel nano-g-C3N4, Compos. Sci. Technol., 180, 60, 10.1016/j.compscitech.2019.05.005 Mai, 2022, Polymer fibers highly filled with styrene maleic anhydride-modified PBWO4 for improved wear comfort of γ-ray-shielding articles, ACS Appl. Polym. Mater Pappas, 2005, Structure and properties of phenolic resin/nanoclay composites synthesized by in situ polymerization, J. Appl. Polym. Sci., 95, 1169, 10.1002/app.21303 Peixoto, 2021, Emerging role of nanoclays in cancer research, diagnosis, and therapy, Coord. Chem. Rev., 440, 10.1016/j.ccr.2021.213956 Perez, 2011, Time-Temperature-Transformation Cure Diagrams of Phenol-Formaldehyde and Lignin-Phenol-Formaldehyde Novolac Resins, J. Appl. Polym. Sci., 119, 2275, 10.1002/app.32866 Pierchala, 2021, Soft electronic materials with combinatorial properties generated via mussel-inspired chemistry and halloysite nanotube reinforcement, ACS Nano, 15, 9531, 10.1021/acsnano.0c09204 Qasim, 2020, Biomass derived fibers as a substitute to synthetic fibers in polymer composites, Chem. Rev., 7, 193 Sanchez, 2019, Chemical reactions affecting halloysite dispersion in epoxy nanocomposites, J. Appl. Polym. Sci., 136, 47979, 10.1002/app.47979 Sandhya, 2019, Effect of starch reduced graphene oxide on thermal and mechanical properties of phenol formaldehyde resin nanocomposites, Compos. B. Eng., 167, 83, 10.1016/j.compositesb.2018.12.009 Shchukin, 2005, Halloysite nanotubes as biomimetic nanoreactors, Small, 1, 510, 10.1002/smll.200400120 Shi, 2018, Facile synthesis of a flame retardant melamine phenylphosphate and its epoxy resin composites with simultaneously improved flame retardancy, smoke suppression and water resistance, RSC Adv., 8, 39214, 10.1039/C8RA08696F Si, 2022, Janus phenol-formaldehyde resin and periodic mesoporous organic silica nanoadsorbent for the removal of heavy metal ions and organic dyes from polluted water, Adv. Compo. Hybrid Ma., 5, 1180, 10.1007/s42114-022-00446-x Smith, 2018, Environmentally benign halloysite nanotube multilayer assembly significantly reduces polyurethane flammability, Adv. Funct. Mater., 28, 1703289, 10.1002/adfm.201703289 Song, 2020, Halloysite nanotubes functionalized cotton fabric for oil/water separation, Prog. Org. Coat., 148 Song, 2022, Interfacial assembly of micro/nanoscale nanotube/silica achieves superhydrophobic melamine sponge for water/oil separation, Sep. Purif. Technol., 280, 10.1016/j.seppur.2021.119920 Stavitskaya, 2022, Prokaryotic and eukaryotic toxicity of halloysite decorated with photoactive nanoparticles, Chem. Commun., 10.1039/D2CC02439J Talreja, 2020, Phenol-formaldehyde-resin-based activated carbons with controlled pore size distribution for high-performance supercapacitors, Chem. Eng. J., 379, 10.1016/j.cej.2019.122332 Tang, 2021, Development of halloysite nanotube-based hydrogel with colorimetric H2O2-responsive character, Appl. Clay Sci., 212, 10.1016/j.clay.2021.106230 Tao, 2019, Flammability and mechanical properties of composites fabricated with CaCO3-filled pine flakes and Phenol Formaldehyde resin, Compos. B. Eng., 167, 1, 10.1016/j.compositesb.2018.12.005 Tasan, 2009, Mechanical Performance of Resol Type Phenolic Resin/Layered Silicate Nanocomposites, Polym. Compos., 30, 343, 10.1002/pc.20591 Wang, 2016, Unique necklace-like phenol formaldehyde resin nanofibers: scalable templating synthesis, casting films, and their superhydrophobic property, Adv. Funct. Mater., 26, 5086, 10.1002/adfm.201600907 Wang, 2018, Bionic boron/silicon-modified phenolic resin system with multifunctional groups: synthesis, thermal properties and ablation mechanism, Biosurf. Biotribol., 4, 85, 10.1049/bsbt.2018.0013 Xie, 2019, Preparation and properties of resin coated ceramic proppants with ultra light weight and high strength from coal-series kaolin, Appl. Clay Sci., 183, 10.1016/j.clay.2019.105364 Yah, 2012, Biomimetic dopamine derivative for selective polymer modification of halloysite nanotube lumen, J. Am. Chem. Soc., 134, 12134, 10.1021/ja303340f Yang, 2019, Synthesis of a novel phosphazene-based flame retardant with active amine groups and its application in reducing the fire hazard of Epoxy Resin, J. Hazard. Mater., 366, 78, 10.1016/j.jhazmat.2018.11.093 Yang, 2021, Green detergent made of halloysite nanotubes, Chem. Eng. J., 425, 10.1016/j.cej.2021.130623 Yi, 2016, Synthesis and mechanism of metal-mediated polymerization of phenolic resins, Polymers, 8, 159, 10.3390/polym8050159 Yu, 2018, Fire-retardant and thermally insulating phenolic-silica aerogels, Angew. Chem. Int. Ed., 57, 4538, 10.1002/anie.201711717 Yu, 2019, Superelastic hard carbon nanofiber aerogels, Adv. Mater., 31, 1900651, 10.1002/adma.201900651 Yum, 2015, Improvement of ablation resistance of phenolic composites reinforced with low concentrations of carbon nanotubes, Compos. Sci. Technol., 121, 16, 10.1016/j.compscitech.2015.10.016 Zhang, 2022, Halloysite nanotube-based self-healing fluorescence hydrogels in fabricating 3D cube containing UV-sensitive QR code information, J. Colloid Interface Sci., 617, 353, 10.1016/j.jcis.2022.03.025 Zhang, 2022, Effect of Al(H2PO4)3/Zn/B4C doped resin on properties and microstructure of unfired Al2O3-C slide plate materials, Ceram. Int., 48, 472, 10.1016/j.ceramint.2021.09.123 Zhao, 2018, Storing solar Energy within Ag-Paraffin@halloysite microspheres as a novel self-heating catalyst, Appl. Energy, 222, 180, 10.1016/j.apenergy.2018.04.013 Zhao, 2021, Chemosensor-anchored halloysite nanotubes for detection and removal of hypochlorite in water, ACS Appl. Nano Mater., 4, 7435, 10.1021/acsanm.1c01432 Zhao, 2023, Gold@Halloysite nanotubes-chitin composite hydrogel with antibacterial and hemostatic activity for wound healing, Bioact. Mater., 20, 355, 10.1016/j.bioactmat.2022.05.035 Zhong, 2022, Coupling Natural halloysite nanotubes and bimetallic Pt-au alloy nanoparticles for highly efficient and selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, ACS Appl. Mater. Interfaces, 14, 3949, 10.1021/acsami.1c18788