Geometrical aspects of QENS experiments in case of anisotropic samples

The European Physical Journal Special Topics - Tập 141 - Trang 285-288 - 2007
F. Jurányi1,2, F. González3, S. Gvasaliya2
1Physical Chemistry, Saarland University, Saarbrücken, Germany
2Laboratory for Neutron Scattering, Villigen PSI, Switzerland
3Laboratory for Waste Management, Paul Scherrer Institute, Villigen PSI, Switzerland

Tóm tắt

Diffusion in anisotropic samples is often studied by quasi-elastic neutron scattering at time-of-flight (t-o-f) instruments. During the data analysis the measured dynamic structure factor S(Q,E) is fitted by a model function, which - reflecting the anisotropy of the sample - depends on the sample orientation. The error introduced in this way will be discussed. Correct measurements can be performed for such cases at a triple axis spectrometer, where energy scan can be performed for a certain Q vector fixed to the sample orientation. Clays show 2D anisotropy in the structure, which is supposed to be visible also in the diffusion of water located between the clay sheets. A first experiment performed on TASP (SINQ) will be shown.

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