Geometric tuning of energy storage in barium titanate/strontium titanate nanocomposites

Tạp chí Khoa học và Công nghệ - Đại học Đà Nẵng - Trang 76-81 - 2025

Ha Thi Dang¹, Dang Thi Hong Hue², Ba-Hieu Vu², Trong-Giang Nguyen², Van-Hai Dinh², Le Van Lich²

¹Vietnam National University of Forestry, Hanoi, Vietnam; PhD student in Materials Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam

²Hanoi University of Science and Technology, Hanoi, Vietnam

Tóm tắt

This study employs phase-field simulations to systematically investigate the impact of barium titanate nanoparticle geometry on polarization domain structures and energy storage properties in barium titanate/strontium titanate nanocomposites. Results reveal distinct polarization domain configurations, including dominant c domains in nanowire-based composites, coexisting a1/a2 and c domains with comparable fractions in nanodot systems, and a near-absence of c domains in nanodisk geometries. These variations of domain structures give rise to divergent hysteresis behaviors, where nanowire composites exhibit large hysteresis loops, nanodot systems display narrower loops, and nanodisk configurations show negligible hysteresis behavior. Notably, transitioning barium titanate geometry from nanowires to nanodisks significantly enhances discharge energy density and energy efficiency, attributed to optimized domain dynamics. The findings propose a novel strategy for improving energy storage capacity in ferroelectric/paraelectric nanocomposites through geometric engineering of the ferroelectric phase to regulate polarization domain structures.

Từ khóa

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