Gauge invariance of the g tensor

The Royal Society - Tập 271 Số 1346 - Trang 424-434 - 1963
Anthony J. Stone1
1Department of Theoretical Chemistry, University Chemical Laboratory, Cambridge

Tóm tắt

The usual theory of g values cannot be applied to molecules as it is not gauge-invariant. Dirac’s wave equation is used to derive a gauge-invariant theory, and a general expression is obtained for the principal g values of a molecule in an orbitally non-degenerate state.

Từ khóa


Tài liệu tham khảo

Salpeter E. E., 1957, Handb, Pliys., 35, 140

Dirac P . A. M. 1958 The principles oj quantum mechanics 4th ed. p. 257. Oxford U niversity Press.

Griffith J . S. 1961 The theory of transition metal ions p. 122. Cambridge U niversity Press.

Longuet H ., 1962, M ol, Phys., 5, 417

10.1088/0370-1298/63/1/304

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Thông tin xuất bản

The Royal Society

Tập 271 Số 1346

424-434

Thông tin tác giả