Fundamental Studies of Physical-Mechanical Properties of Environmentally Friendly Fluorine-Free Slags and Their Use in Ladle Steel Industry

Dyudkin, D.A. and Kisilenko, V.V., Proizvodstvo stali (Steel Production), vol. 3: Vnepechnaya metalluriya stali (Extra-Furnace Metallurgy of Steel), Moscow: Teplotekhnik, 2010.

Chumakov S.M., Lamukhin A.M., Zinchenko S.D., et al., Concept of production of low-sulfur steels at JSC Severstal taking into account technological aspects, Trudy VI kongressa staleplavil’shchikov (Proceedings of the 6th Congress of Steelmakers), Moscow: Chermetinformatsiya, 2001, pp. 63–66.

Takahashi, D., Kamo, M., Kurose, Y., and Nomura, H., Deep steel desulphurisation technology in ladle furnace at KSC, Ironmaking Steelmaking, 2003, vol. 30, no. 2, pp. 116–119. https://doi.org/10.1179/030192303225001711

Akberdin, A.A., Kulikov, I.S., Kim, V.A., Nadyrbekov, A.K., and Kim, A.S., Fizicheskie svoistva rasplavov sistemy CaO–SiO 2 –Al 2 O 3 –MgO–CaF 2 (Physical Properties of the Melts of CaO–SiO2–Al2O3–MgO–CaF2 System, Moscow: Metallurgiya, 1987.

Wamg, H.-M., Li, G.-R., Dai, Q.-X., Li, B., Zhang, X.-J., and Shi, G.M., CAS-OB refining: Slag modification with B2O3–CaO and CaF2–CaO, Ironmaking Steelmaking, 2007, vol. 34, no. 4, pp. 350–353. https://doi.org/10.1179/174328107X155277

Ko, K.Y. and Park, J.H., Effect of CaF2 addition on the viscosity and structure of CaO–SiO2–MnO slags, ISIJ Int., 2013, vol. 53, no. 6, pp. 958–965.  https://doi.org/10.2355/isijinternational.53.958

Demin L.B., Sorokin Yu.V., Smirnov L.A., Shcherbakov E.N. Stabilization of decaying ferroalloy and steelmaking slags, Perspektivy razvitiya metallurgii i mashinostroeniya s ispol’zovaniem zavershennykh fundamental’nykh issledovanii in NIOKR. Trudy mezhdunarodnoi nauchno-prakticheskoi konferentsii (Prospects for the Development of Metallurgy and Mechanical Engineering using Completed Fundamental Research and R&D: Proceedings of the Int. Sci. and Pract. Conf.), Yekaterinburg: Al’fa Print, 2018, pp. 342–345.

Babenko A.A., Smirnov L.A., Upolovnikova A.G., and Smetannikov A.N., Development of composition of environmentally friendly fluorine-free slags of ladle steel metallurgy, Fundamental’nye issledovaniya i prikladnye razrabotki protsessov pererabotki i utilizatsii tekhnogennykh obrazovanii. Sbornik trudov V mezhdunarodnogo kongressa TEKhNOGEN-2021 (Fundamental Research and Applied Development of Processing and Utilization of Technogenic Formations: Proceedings of the 5th Int. Congress TECHNOGEN-2021), Yekaterinburg, 2021, pp. 349–350. https://doi.org/10.34923/technogen-ural.2021.39.62.123

Grabeklis, A.A., Demin, B.L., Kairakbaev, S.N., Musabekov, Zh.B., and Kavanov, B.O., Crystal-chemical stabilization of slags from refined-ferrochrome production, Steel Transl., 2010, vol. 40, pp. 479–484.  https://doi.org/10.3103/S0967091210050153

Demin, B.L., Sorokin, Yu.V., Sharafutdinov, R.Ya., Murzin, A.V., and Zhilin, A.M., Testing the technology of crystal chemical stabilization of self-decaying steelmaking slags. Stal’, 2014, no. 6, pp. 102–106.

Akberdin, A.A., Kireeva, G.M., and Medvedovskaya, I.A., Effect of B2O3 on the viscosity of CaO–SiO2–Al2O3 slags, Izv. Akad. Nauk SSSR. Met., 1986, no. 3, pp. 55–56.

Hongming, W., Tingwang, Z., and Hua, Z., Effect of B2O3 on melting temperature, viscosity and desulfurization capacity of CaO-based refining flux, ISIJ Int., 2011, vol. 51, no. 5, pp. 702–706.  https://doi.org/10.2355/isijinternational.51.702

Zhang, L., Wang, W., Xie, S., Zhang, K., and Sohn, I., Effect of basicity and B2O3 on the viscosity and structure of fluorine-free mold flux, J. Non-Cryst. Solids, 2017, vol. 460, pp. 113–118. https://doi.org/10.1016/j.jnoncrysol.2017.01.031

Benavidez, E., Santini, L., Valentini, M., and Brandaleze, E., Influence of different oxides on the viscosity of fluorine-free mold fluxes, Procedia Mater. Sci., 2012, vol. 1, pp. 389–396. https://doi.org/10.1016/j.mspro.2012.06.052

Li, W. and Xue, X., Effects of Na2O and B2O3 addition on viscosity and electrical conductivity of CaO–Al2O3–MgO–SiO2 system, ISIJ Int., 2018, vol. 58, no. 10, pp. 1751–1760. https://doi.org/10.2355/isijinternational.ISIJINT-2018-212

Liu, L.X., Wang, G., Wang, Sh.J., Dong, Y.C., and Chai, Y.F., Calculation of phase diagram of CaO–SiO2–Al2O3–MgO–B2O3 refining slag without CaF2, Adv. Mater. Res., 2012, vols. 512–515, pp. 1558–1563. doi 10.4028/www.scientific.net/AMR.512-515.1558

Babenko, A.A., Shartdinov, R.R., Upolovnikova, A.G., Smetannikov, A.N., and Mikhailova, L.Yu., Effect of basicity and chromium oxide on the viscosity of boron-containing slags, IOP Conf. Ser.: Mater. Sci. Eng., 2020, vol. 966, p. 012012.  https://doi.org/10.1088/1757-899X/966/1/012012

Kim, V.A., Nikolai, E.N., Akberdin, A.A., and Kulikov, I.S., Planirovanie eksperimenta pri issledovanii fiziko-khimicheskikh svoisv metallurgicheskikh shlakov (Planning an Experiment in Research of Physico-Chemical Properties of Metallurgical Slags), Alma-Ata: Nauka, 1989.

Babenko, A.A., Smirnov, L.A., and Upolovnikova, A.G., Equilibrium boron distribution between Fe–C–Si–Al melt and boron-bearing slag, J. Int. Sci. Publ.: Mater., Methods Technol., 2018, no. 12, pp. 202–208.

Babenko, A.A., Smirnov, L.A., and Upolovnikova, A.G., Theoretical and experimental studies of sulfur and boron distribution between the slag of the CaO–SiO2–B2O3–MgO– Al2O3 system and the metal, Defect Diffusion Forum, 2021, vol. 410, pp. 287–292. doi 10.4028/www.scientific.net/DDF.410.287

Babenko, A.A., Smirnov, L.A., and Upolovnikova, A.G., Fundamental research as a basis for the creation of new technologies in steel ladle metallurgy, Mater. Sci. Forum, 2019, vol. 946, pp. 493–499. doi 10.4028/www.scientific.net/MSF.946.493

Arsent’ev, P.P., Yakovlev, V.V., and Krasheninnikov, M.G., et al., Fiziko-khimicheskie metody issledovaniya metallurgicheskikh protsessov. Uchebnik dlya vuzov (Physicochemical Methods of Metallurgical Processes Research: Textbook for Universities), Moscow: Metallurgiya, 1988.