Formation of submicrometer-scale gold nanoparticle aggregates and their self-organization into “supracrystals”

Colloid Journal - Tập 69 - Trang 391-393 - 2007
Yonglan Luo1
1School of Chemistry and Chemical Industry, China West Normal University, Nanchong, P. R. China

Tóm tắt

Nearly spherical, submicrometer-scale gold nanoparticle aggregates about 250 nm in diameter are formed directly from an HAuCl4-p-phenylenediamine aqueous solution at room temperature. The as-formed aggregates were characterized by various techniques, including scanning electron microscopy, transmission electron microscopy, and X-ray diffraction, and their formation mechanism is discussed. It is very interesting that “supracrystals” can be produced with the use of such gold aggregated nanoparticles.

Tài liệu tham khảo

Fendler, J.H., Nanoparticles and Nanostructured Films, Wiley-VCH, Weinheim, 1998. Daniel, M.C. and Astruc, D., Chem. Rev., 2004, vol. 104, p. 293. Schmid, G., Chem. Rev., 1992, vol. 1709, p. 92. Roucoux, A., Schulz, J., and Patin, H., Chem. Rev., 2002, vol. 102, p. 3757. Lu, Y., Fan, H., Stump, A., Ward, T.L., Rieker, T., and Brinker, C.T., Nature, 1999, vol. 398, p. 223. Breen, T.L., Tien, J., Oliver, S.R.J., Hadzic, T., and Whitesides, G.M., Science, 1999, vol. 284, p. 948. Shenhar, R. and Rotello, V.M., Acc. Chem. Res., 2003, vol. 36, p. 549. Jin, J., Lyoda, T., Cao, C.S., Song, Y.L., Jiang, L., Li, T.J., and Zhu, D.B., Angew. Chem. Int. Ed., 2001, vol. 40, p. 2135. Maye, M.M., Chun, S.C., Han, L., Rabinovich, D., and Zhong, C.J., J. Am. Chem. Soc., 2002, vol. 124, p. 4958. Boal, A.K., Ilhan, F., DeRouchey, J.E., Thurn-Albrecht, T., Russell, T.P. and Rotello, V.M., Nature, 2000, vol. 404, p. 746. Frankamp, B., Boal, A.K., and Rotello, V.M., J. Am. Chem. Soc., 2002, vol. 124, p. 15146. Goia, D.V. and Matijević, E., New J. Chem., 1998, vol. 22, p. 1203. Velikov, K.P., Zegers, G.E., and van Blaaderen, A., Langmuir, 2003, vol. 19, p. 1384. Sun, X., Jiang, X., Dong, S., and Wang, E., Macromol. Rapid Commun., 2003, vol. 24, p. 1024. Sun, X., Dong, S., and Wang, E., Chem. Commun., 2004, p. 1182. Sun, X., Dong, S., and Wang, E., Angew. Chem. Int. Ed., 2004, vol. 43, p. 6360. Sun, X., Dong, S., and Wang, E., Langmuir, 2005, vol. 21, p. 4710. Sun, X., Dong, S., and Wang, E., Polymer. 2004, vol. 45, p. 2181. Sun, X., Dong, S., and Wang, E., J. Colloid Interface Sci., 2005, vol. 288, p. 301. Privman, V., Goia, D.V., Park, J., and Matijević, E., J. Colloid Interface Sci., 1999, vol. 213, p. 36. Park, J., Privman, V., and Matijević, E., J. Phys. Chem. B. 2001, vol. 105, p. 11630.