Fluoride removal on Fe–Al-impregnated granular ceramic adsorbent from aqueous solution
Tóm tắt
A novel Fe–Al-impregnated granular ceramic adsorbent has been developed for fluoride removal from aqueous solution. Batch experiments were performed to investigate the effect of contact time, initial pH, adsorbent dose, and the presence of competing anions on the adsorption of fluoride. More than 96 % removal of fluoride was achieved within 48 h from 10 mg/L initial fluoride solution at neutral pH. The adsorption process was well explained with pseudo-second-order and pore diffusion models. The maximum adsorption capacity of adsorbent for fluoride removal was 3.56 mg/g according to the Langmuir isotherm model. The optimum fluoride removal efficiency was observed between pH ranged of 4.0–9.0. The fluoride removal efficiency was significantly decreased in the presence of carbonate and phosphate anions. Results from this study demonstrated potential utility of Fe–Al-impregnated granular ceramic adsorbent that could be developed into a viable method for fluoride removal from aqueous solution.
Tài liệu tham khảo
Aharoni C, Ungarish M (1977) Kinetics of activated chemisorptions, Part-2. Theoretical models. J Chem Soc 73(3):456–464
Biswas K, Gupta K, Ghosh UC (2009) Adsorption of fluoride by hydrous iron (III)–tin (IV) bimetal mixed oxide from the aqueous solutions. Chem Eng J 149:196–206
Carrillo-Rivera JJ, Cardona A, Edmunds WM (2002) Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potosi basin, Mexico. J. Hydrol. 261:24–47
Chen N, Zhang ZY, Feng CP, Sugiura N, Li M, Chen RZ (2010a) Fluoride removal from water by granular ceramic adsorption. J Colloid Interface Sci 348:579–584
Chen N, Zhang ZY, Feng CP, Sugiura N, Li M, Chen RZ, Zhu DR (2010b) An excellent fluoride sorption behavior of ceramic adsorbent. J Hazard Mater 183:460–465
China standard for drinking water quality (2006) GB 5749-2006, vol 1
Chubar NI, Samanidou VF, Kouts VS, Gallios GG, Kanibolotsky VA, Strelko VV, Zhuravlev IZ (2005) Adsorption of fluoride, chloride, bromide and bromated ions on a novel ion exchanger. J Colloid Interface Sci 291:67–74
Daifullah AAM, Yakout SM, Elreefy SA (2007) Adsorption of fluoride in aqueous solutions using KMnO4-modified activated carbon derived from stem pyrolysis of rich straw. J Hazard Mater 147:633–643
Das N, Pattanaik P, Das R (2005) Defluoridation of drinking water using activated titanium rich bauxite. J Colloid Interface Sci 292:1–10
Ding WM, Hairet T, Huang X (2008) Primary study of fluoride removal from aqueous solution by activated ferric hydroxide. In 2nd international conference on bioinformatics and biomedical engineering (ICBBE 08), pp. 2911–2913
Ergun E, Tor A, Cengeloglu Y, Kocak I (2008) Electrodialytic removal of fluoride from water: effects of process parameters and accompanying anions. Sep Purif Technol 64:147–153
Eric TK, Véronique A, Nanseu-Njiki CP, Nathalie A, Emmanuel N, André D (2010) Preparation and characterization of charcoals that contain dispersed aluminum oxide as adsorbents for removal of fluoride from drinking water. Carbon 48:333–343
Freundlich HMF (1906) Über die adsorption in losungen. Z Phys Chem 57A:385–470
Ghorai S, Pant KK (2005) Equilibrium, kinetics and breakthrough studies for adsorption of fluoride on activated alumina. Sep Purif Technol 42:265–271
Gupta VK, Ali I, Saini VK (2007) Defluoridation of wastewaters using waste carbon slurry. Water Res 41:3307–3316
Ho YS, Mckay G (1998) Kinetic models for the sorption of dye from aqueous solution by wood. Process Saf Environ Prot 76(B2):183–191
Ho YS, Mckay G (2000) The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Res 34:735–742
Joshi SV, Mehta SH, Rao AP, Rao AV (1992) Estimation of sodium fluoride using HPLC in reverse osmosis experiments. Water Treat 10:307–312
Kagne S, Jagtap S, Dhawade P, Kamble SP, Devotta S, Rayalu SS (2008) Hydrated cement: a promising adsorbent for the removal of fluoride from aqueous solution. J Hazard Mater 154:88–95
Lagergren S (1898) Zur theorie der sogenannten adsorption geloster stoffe. K Sven Vetenskakad Handl 24:1–39
Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295
Leofanti G, Padovan M, Tozzola G, Venturelli B (1998) Surface area and pore texture of catalysts. Catal Today 41:207–219
Mahramanlioglu M, Kizilcikli I, Bicer IO (2002) Adsorption of fluoride from aqueous solution by acid treated spent bleaching earth. J Fluorine Chem 115:41–47
Mandal S, Mayadevi S (2009) Defluoridation of water using as-synthesized Zn/Al/Cl anionic clay adsorbent: equilibrium and regeneration studies. J Hazard Mater 167:873–878
Meenakshi V, Garg K, Renuka, Kavita, Malik K (2004) Groundwater quality in some villages of Haryana, India: focus on fluoride and fluorosis. J Hazard Mater 106:85–97
Meenakshi S, Sundaram CS, Sukumar R (2008) Enhanced fluoride sorption by mechanochemically activated kaolinites. J Hazard Mater 153:164–172
Mohan SV, Ramanaiah SV, Rajkumar B, Sarma PN (2007) Removal of fluoride from aqueous phase by biosorption on to algal biosorbent spirogyra sp.-102: sorption mechanism elucidation. J Hazard Mater 141:465–474
Onyango MS, Kojima Y, Aoyi O, Bernardo EC, Matsuda H (2004) Adsorption equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalent-cation-exchanged zeolite F-9. J Colloid Interface Sci 279(2):341–350
Raichur AM, Basu ML (2001) Adsorption of fluoride onto rare earth oxides. Sep Purif Technol 24(1–2):121–127
Ramos RL, Ovalle-Turrubiartes J, Sanchez-Castilli MA (1999) Adsorption of fluoride from aqueous solution on aluminum-impregnated carbon. Carbon 37(4):609–617
Reimann C, Bjorvatn K, Frengsta B, Melaku Z, Tekle-Haimanot R, Siewers U (2003) Drinking water quality in the Ethiopian section of the East African Rift Valley I—data and health aspects. Sci Total Environ 311:65–80
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas solid systems with special reference to the determination of surface-area and porosity (recommendations 1984). Pure Appl Chem 57:603–619
Song D, Liu J, Huang F, Li GL, Meng L, Chen YH, Yu HR, Gao S, Gao WY (2013a) Observation and characterization of micromorphology and microstructure of pyrite synthesized by hydrothermal method. Earth Sci Front 20(3):118–122
Song XL, Zhang Y, Yan CY, Jiang WJ, Chang CM (2013b) The Langmuir monolayer adsorption model of organic matter into effective pores in activated carbon. J Colloid Interface Sci 389:213–219
Sujana MG, Anand S (2010) Iron and aluminum based mixed hydroxides: a novel sorbent for fluoride removal from aqueous solutions. Appl Surface Sci 256:6956–6962
Sujana MG, Thakur RS, Rao SB (1998) Removal of fluoride from aqueous solution by using alum sludge. J Colloid Interface Sci 275:355–359
Suzuki T, Kanesato M, Yokoyama T (1990) Removal of fluorides from aqueous solutions. Japanese Kokai Tokkyo Koho . Patent number 02191543
Tor A (2007) Removal of fluoride from water using anion-exchange membrane under Donnan dialysis condition. J Hazard Mater 141:814–818
Tor A, Danaoglu N, Arslan G, Cengeloglu Y (2009) Removal of fluoride from water by using granular red mud: batch and column studies. J Hazard Mater 164:271–278
Viswanathan N, Meenakshi S (2008) Enhanced fluoride sorption using La(III) incorporated carboxylated chitosan beads. J Colloid Interface Sci 322:375–383
Wang HR, Yang XX, Ding HR, Li Y, Zhu Y, Wang CQ, Lu AH (2013) The reduction effect of Cronobacter sakazakii on crystal structure of goethite. Earth Sci Front 20(3):147–153
Wang XB, Zhang SG, Gu MX, Li YL (2012) Discussions on the property of deep-lying groundwater resources in Hebei plain. Earth Sci Front 19(6):243–247
Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon solution. J Sanit Eng Div Am Soc Civ Eng 89:31–59
WHO (2004) Guidelines for drinking-water quality, Recommendation, 3rd edn, vol 1. WHO, Geneva
Wu X, Zhang Y, Dou X, Yang M (2007) Fluoride removal performance of a novel Fe–Al–Ce trimetal oxide adsorbent. Chemosphere 69(11):1758–1764 Wang XB, Zhang SG, Gu MX, Li YL (2012) Discussions on the property of deep-lying groundwater resources in Hebei plain. Earth Sci Front 19(6): 243-247
Yang M, Hashimoto T, Hoshi N, Myoga H (1999) Fluoride removal in a fixed bed packed with granular calcite. Water Res 33:3395–3402
Zhou JB, Yang SL, Yu JG, Shu Z (2011) Novel hollow microspheres of hierarchical zinc–aluminum layered double hydroxides and their enhanced adsorption capacity for phosphate in water. J Hazard Mater 192:1114–1121