Flower-like PdCu catalyst with high electrocatalytic properties for ethylene glycol oxidation

Shao, 2010, Pt monolayer on porous Pd–Cu alloys as oxygen reduction electrocatalysts, J Am Chem Soc, 132, 9253, 10.1021/ja101966a Li, 2014, Synthesis of Cu@ Pd core-shell nanowires with enhanced activity and stability for formic acid oxidation, Electrochim Acta, 143, 44, 10.1016/j.electacta.2014.07.156 Yin, 2012, Pt Cu and Pt Pd Cu concave nanocubes with high-index facets and superior electrocatalytic activity, Chemistry, 18, 777, 10.1002/chem.201102632 Fouda-Onana, 2009, Study of O2 and OH adsorption energies on Pd–Cu alloys surface with a quantum chemistry approach, Electrochim Acta, 54, 1769, 10.1016/j.electacta.2008.10.026 Antolini, 2009, Palladium in fuel cell catalysis, Energy Environ Sci, 2, 915, 10.1039/b820837a Bai, 2017, Highly active and selective hydrogenation of CO2 to ethanol by ordered Pd–Cu nanoparticles, J Am Chem Soc, 139, 6827, 10.1021/jacs.7b03101 Wang, 2009, Pt decorating PdCu/C as highly effective electrocatalysts for methanol oxidation, Electrochem Commun, 11, 1089, 10.1016/j.elecom.2009.03.026 Cai, 2016, Preparation of PdCu alloy nanocatalysts for nitrate hydrogenation and carbon monoxide oxidation, Catalysts, 6, 96, 10.3390/catal6070096 Suo, 2016, Synthesis of carbon supported Au-decorated PdCu nanocatalyst for formic acid oxidation, Ionics, 22, 985, 10.1007/s11581-016-1718-x Fan, 2016, Three-dimensional highly branched Pd3Cu alloy multipods as enhanced electrocatalysts for formic acid oxidation, RSC Adv, 6, 43980, 10.1039/C6RA07560F Kunz, 2017, Seed-mediated co-reduction in a large lattice mismatch system: synthesis of Pd–Cu nanostructures, Nanoscale, 9, 7570, 10.1039/C7NR02918G Serov, 2012, Highly active Pd Cu catalysts for electrooxidation of 2-propanol, Electrochem Commun, 22, 193, 10.1016/j.elecom.2012.06.023 Ma, 2004, Characterization of intermetallic diffusion barrier and alloy formation for Pd/Cu and Pd/Ag porous stainless steel composite membranes, Ind Eng Chem Res, 43, 2936, 10.1021/ie034002e Iqbal, 2017, Continuous mesoporous Pd films by electrochemical deposition in nonionic Micellar solution, Chem Mater., 29, 6405, 10.1021/acs.chemmater.7b01811 Iqbal, 2017, Three‐dimensional super‐branched PdCu nanoarchitectures exposed on controlled crystal facets, Chemistry, 23, 51, 10.1002/chem.201604026 Malgras, 2016, Nanoarchitectures for mesoporous metals, Adv Mater, 28, 993, 10.1002/adma.201502593 Xu, 2011, Nanoporous PdCu alloy with enhanced electrocatalytic performance, Electrochem Commun, 13, 766, 10.1016/j.elecom.2011.04.007 Xu, 2017, PVP-stabilized PdAu nanowire networks prepared in different solvents endowed with high electrocatalytic activities for the oxidation of ethylene glycol and isopropanol, Colloids Surf A: Physicochem Eng Aspects, 522, 335, 10.1016/j.colsurfa.2017.03.015 Zhang, 2015, Ru-assisted synthesis of Pd/Ru nanodendrites with high activity for ethanol electrooxidation, Nanoscale, 7, 12445, 10.1039/C5NR02713F Gu, 2017, Preparation of PdNi nanospheres with enhanced catalytic performance for methanol electrooxidation in alkaline medium, Colloids Surf A: Physicochem Eng Aspects, 529, 651, 10.1016/j.colsurfa.2017.06.044 Wang, 2017, Pd3Cu coupling with nitrogen-doped mesoporous carbon to boost performance in glycerol oxidation, Appl Catal A: Gen, 538, 123, 10.1016/j.apcata.2017.03.027 An, 2015, Hollow palladium–copper bimetallic nanospheres with high oxygen reduction activity, Electrochim Acta, 176, 222, 10.1016/j.electacta.2015.06.135 Saxena, 2003, A case study of IR-drop in structured at-speed testing, IEEE, 42, 1098 Zhang, 2017, Regio-and stereoselective hydrosilylation of alkynes catalyzed by SiO2 supported Pd–Cu bimetallic nanoparticles, Green Chem, 19, 2535, 10.1039/C7GC00818J Kang, 2011, Enhancement of electrochemical properties on Pd–Cu/C electrocatalysts toward ethanol oxidation by atmosphere induced surface and structural alteration, Electrochem Commun, 13, 162, 10.1016/j.elecom.2010.12.003 Goswami, 2017, In situ generation of Pd–Pt core–shell nanoparticles on reduced graphene oxide (Pd@Pt/rGO) using microwaves: applications in dehalogenation reactions and reduction of olefins, ACS Appl Mater Interf, 9, 2815, 10.1021/acsami.6b13138 Mori, 2013, Pd and Pd–Ag nanoparticles within a macroreticular basic resin: an efficient catalyst for hydrogen production from formic acid decomposition, ACS Catal, 3, 1114, 10.1021/cs400148n Yin, 2008, Porous palladium nanoflowers that have enhanced methanol electro-oxidation activity, J Phys Chem C, 113, 1001, 10.1021/jp807456j Xiong, 2013, Three-dimensional bimetallic Pd–Cu nanodendrites with superior electrochemical performance for oxygen reduction reaction, Electrochim Acta, 89, 24, 10.1016/j.electacta.2012.10.162 Fu, 2013, One-pot water-based synthesis of Pt–Pd alloy nanoflowers and their superior electrocatalytic activity for the oxygen reduction reaction and remarkable methanol-tolerant ability in acid media, J Phys Chem C, 117, 9826, 10.1021/jp400502y Straumanis, 1969, Lattice parameters, densities, expansion coefficients and perfection of structure of Cu and of Cu–In α phase, Acta Crystallogr Sect A, A25, 676, 10.1107/S0567739469001549 Maya-Cornejo, 2015, Copper–palladium core-shell as an anode in a multi-fuel membraneless nanofluidic fuel cell: toward a new era of small energy conversion devices, Chem Commun, 51, 2536, 10.1039/C4CC08529A Monshi, 2012, Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD, World J Nano Sci Eng, 2, 154, 10.4236/wjnse.2012.23020 Xue, 2016, Structural regulation of PdCu2 nanoparticles and their electrocatalytic performance for ethanol oxidation, ACS Appl Mater Interf, 8, 34497, 10.1021/acsami.6b13368 Li, 2017, One-pot anchoring of Pd nanoparticles on nitrogen-doped carbon through dopamine self-polymerization and activity in the electrocatalytic methanol oxidation reaction, ChemSusChem, 10, 976, 10.1002/cssc.201601732 Feng, 2017, Porous bimetallic PdNi catalyst with high electrocatalytic activity for ethanol electrooxidation, J Colloid Interface Sci, 493, 190, 10.1016/j.jcis.2017.01.035 Bin, 2016, Design of PdAg hollow nanoflowers through galvanic replacement and their application for ethanol electrooxidation, Chemistry, 22, 16642, 10.1002/chem.201601544 Hu, 2014, Activity of Pd/C for hydrogen generation in aqueous formic acid solution, Int J Hydrogen Energy, 39, 381, 10.1016/j.ijhydene.2013.10.067 Xu, 2013, Nanoporous PdNi alloys as highly active and methanol-tolerant electrocatalysts towards oxygen reduction reaction, J Mater Chem A, 1, 13542, 10.1039/c3ta12765f Di Noto, 2007, Pd–Co carbon-nitride electrocatalysts for polymer electrolyte fuel cells, Electrochim Acta, 53, 1604, 10.1016/j.electacta.2007.05.028 Liang, 2016, Ternary Pd–Ni–P hybrid electrocatalysts derived from Pd–Ni core–shell nanoparticles with enhanced formic acid oxidation activity, Chem Commun, 52, 11143, 10.1039/C6CC04382H Yang, 2013, Preparation of Pd-decorated fullerenols on carbon nanotubes with excellent electrocatalytic properties in alkaline media, J Mater Chem A, 1, 8105, 10.1039/c3ta11907f Prabhuram, 1998, Effects of incorporation of Cu and Ag in Pd on electrochemical oxidation of methanol in alkaline solution, J Appl Electrochem, 28, 935, 10.1023/A:1003469616358 Yi, 2011, Fabrication of novel porous Pd particles and their electroactivity towards ethanol oxidation in alkaline media, Fuel, 90, 2617, 10.1016/j.fuel.2011.03.038 Guo, 2017, Enhancement of the catalytic performance in Pd–Cu/NaY catalyst for carbonylation of methyl nitrite to dimethyl carbonate: effects of copper doping, Catal Commun, 88, 94, 10.1016/j.catcom.2016.10.007 Goulas, 2016, Synergistic effects in bimetallic palladium–copper catalysts improve selectivity in oxygenate coupling reactions, J Am Chem Soc, 138, 6805, 10.1021/jacs.6b02247 Song, 2016, Electrocatalytic performance for methanol oxidation on nanoporous Pd/NiO composites prepared by one-step dealloying, Fuel, 181, 269, 10.1016/j.fuel.2016.04.086 Maiyalagan, 2010, Performance of carbon nanofiber supported Pd–Ni catalysts for electro-oxidation of ethanol in alkaline medium, J Power Sour, 195, 5246, 10.1016/j.jpowsour.2010.03.022 Ye, 2007, Electrooxidation of 2-propanol on Pt, Pd and Au in alkaline medium, Electrochem Commun, 9, 2760, 10.1016/j.elecom.2007.09.016 Singh, 2009, Electrocatalytic activity of binary and ternary composite films of Pd, MWCNT, and Ni for ethanol electro-oxidation in alkaline solutions, Carbon, 47, 271, 10.1016/j.carbon.2008.10.006 Wang, 2013, Hollow palladium nanospheres with porous shells supported on graphene as enhanced electrocatalysts for formic acid oxidation, Phys Chem Chem Phys, 15, 19353, 10.1039/c3cp53419g Liu, 2003, Impedance studies on mesocarbon microbeads supported Pt–Ru catalytic anode, J Power Sour, 114, 10, 10.1016/S0378-7753(02)00527-X Krewer, 2006, Impedance spectroscopic analysis of the electrochemical methanol oxidation kinetics, J Electroanal Chem, 589, 148, 10.1016/j.jelechem.2006.01.027 Ren, 2015, Facile synthesis of PtAu nanoparticles supported on polydopamine reduced and modified graphene oxide as a highly active catalyst for methanol oxidation, Electrochim Acta, 153, 175, 10.1016/j.electacta.2014.11.184