Flexibilization of Biorefineries: Tuning Lignin Hydrogenation by Hydrogen Partial Pressure

Wiley - Tập 14 Số 1 - Trang 373-378 - 2021
Zhengwen Cao1, Yun Xu1, Pengbo Lyu2, Michael Dierks1, Ángel Morales‐García2,3, Wolfgang Schräder1, Petr Nachtigall2, Ferdi Schüth1
1Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany
2Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University, 128 43 Prague 2, Czech Republic
3Present Address Departament de Ciència de Materials i Química Física & Institut de Química Teòrica i Computacional (IQTCUB) Universitat de Barcelona c/Martí i Franquès 1–11 08028 Barcelona Spain

Tóm tắt

Abstract

The present study describes an interesting and practical catalytic system that allows flexible conversion of lignin into aromatic or aliphatic hydrocarbons, depending on the hydrogen partial pressure. A combination of experiment and theory shows that the product distribution between aromatics and aliphatics can be simply tuned by controlling the availability of hydrogen on the catalyst surface. Noticeably, these pathways lead to almost complete oxygen removal from lignin biomass, yielding high‐quality hydrocarbons. Thus, hydrogen–lignin co‐refining by using this catalytic system provides high flexibility in hydrogen storage/consumption towards meeting different regional and temporal demands.

Từ khóa


Tài liệu tham khảo

10.1039/c3ee00056g

10.1039/C3CS60396B

Büchele R., 2009, Umwelttechnik-Atlas für Deutschland

10.1002/anie.200604274

10.1002/ange.200604274

10.1002/anie.201403747

10.1002/ange.201403747

10.1002/anie.200604504

10.1002/ange.200604504

10.1126/science.1085597

10.1126/science.1246843

10.1039/C7EE01298E

10.1126/science.1194218

10.1039/C7CS00566K

10.1016/j.joule.2017.10.004

10.1126/science.aaf7810

10.1002/jctb.3799

10.1039/C3GC42589D

10.1002/anie.201607257

2017, Angew. Chem., 129

10.1002/anie.200801476

10.1002/ange.200801476

10.1016/j.joule.2017.11.001

10.1021/ef502779s

10.1038/nchem.1609

10.1038/nchem.2740

10.1126/science.aau1567

10.1126/sciadv.aax6839

https://www.acwapower.com/news/acwa-power-wins-the-first-ever-utility-scale-renewable-energy-project-in-saudi-arabia/.

G. Saur National Renewable Energy Laboratory (NREL) Golden CO. 2008 https://www.osti.gov/biblio/944892.

10.1016/j.ijhydene.2015.01.123

10.1016/j.ijhydene.2015.01.097

Zhu Q.-L., 2015, E. Science, 8, 478

R. B. Gupta Hydrogen Fuel: Production Transport and Storage CRC Press Boca Raton 2008.

Hydrogen: Economics and its role in biorefining F. Schüth 2014.

10.1039/9781782620099

10.1039/c2ee22937d

10.1021/cs400069z

10.1016/j.apcatb.2010.05.031

10.1021/ie501682r

10.1039/C5GC01534K

10.1038/ncomms11162

10.1002/anie.200900404

10.1002/ange.200900404

10.1002/anie.201304776

2013, Angew. Chem., 125

10.1039/C5GC01790D

10.1016/j.cattod.2013.09.044

10.1021/acscatal.5b01554

10.1039/C5GC01583A

10.1039/C3EE43846E

10.1039/C4GC01798F

10.1039/C8CC04969F

10.1016/j.joule.2018.03.012

10.1016/j.apcatb.2014.09.010

10.1016/j.jcat.2005.12.029

10.1039/C6CE00584E

10.1016/j.jcat.2005.12.029

10.1016/j.susc.2004.01.038

10.1039/c2ee21855k

10.1002/anie.201304776

2013, Angew. Chem., 125

10.1002/ceat.201000270

10.1016/0165-2370(94)00846-S

10.1016/j.biortech.2016.11.072

10.1021/ac300133p

10.1002/slct.201601083

10.1002/anie.200803403

10.1002/ange.200803403

10.1002/mas.20058

10.1021/cr900354u

https://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2009:140:0016:0062:en:PDF.

Thông tin
Thông tin xuất bản

Wiley

Tập 14 Số 1

373-378

Thông tin tác giả