Facile synthesis of mesoporous cuprous oxide nanoparticles for enhanced visible-light-driven photodegradation

Han Xiao1, Liwen Lei1, Zhiqiang Wang1, Yuanyuan Chen1
1School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, China

Tóm tắt

The visible-light-active mesoporous cuprous oxide nanoparticles were successfully synthesized via a facile precipitation process with the presence of gelatin, which was demonstrated to play an important role in the formation of mesoporous structure and the grain size control. The nanoscale grain size and mesoporous structure lead to lager specific surface area with the addition of gelatin. Furthermore, the photodegradation of as-prepared catalysts in the presence of gelatin toward the negatively charged methyl orange (MO) was investigated. The cuprous oxide displayed an excellent visible light photocatalytic activity of MO, owing to its exposed active (111) face and large specific surface area. The adsorption of positively charged methyl blue (MB) revealed that the mesoporous cuprous oxide displayed better adsorption of anionic dye MB due to the residual gelatin on the surface of the grains, compared to that in the absence of gelatin.

Tài liệu tham khảo

Zhang J T, Liu J F, Peng Q, et al. Nearly Monodisperse Cu2O and CuO Nanospheres: Preparation and Applications for Sensitive Gas Sensors[J]. Chem. Mater., 2006, 18, 867–871 Molenda J, Nowak I, Jedynak L, et al. Transport and Electrochemical Properties of BiSrCaCuO Superconductors[J]. Mol. Cryst. Liq. Cryst., 2000, 341:199–204 Sun M, Fang Y, Wang Y, et al. Synthesis of Cu2O/graphene/rutile TiO2, Nanorod Ternary Composites with Enhanced Photocatalytic Activity[J]. J. Alloys Compd., 2015, 650:520–527 Liu X Q, Iocozzia J, Wang Y, et al. Noble Metal-metal Oxide Nanohybrids with Tailored Nanostructures for Efficient Solar Energy Conversion, Photocatalysis and Environmental Remediation[J]. Energ. Environ. Sci., 2017, 10: 402–434 Yin H Y, Wang X L, Wang L, et al. Cu2O/TiO2 Heterostructured Hollow Sphere with Enhanced Visible Light Photocatalytic Activity[J]. Mater. Res. Bull., 2015, 72: 176–183 Hung L I, Tsung C K, Huang W, et al. Room-temperature Formation of Hollow Cu2O Nanoparticles[J]. Adv. Mater., 2010, 22: 1910–1914 Huang W C, Yang Y C, Huang M H. Synthesis of Cu2O Nanocrystals from Cubic to Rhombic Dodecahedral Structures and Their Comparative Photocatalytic Activity[J]. J. Am. Chem. Soc., 2011,134: 1261–1267 Wang W Z, Wang G H, Wang X S, et al. Synthesis and Characterization of Cu2O Nanowires by a Novel Reduction Route[J]. Adv. Mater., 2002, 14: 67–69 Raut A B, Tiwari A R, Bhanage B M. Ultrasound-Assisted Preparation of Copper(I) Oxide Nanocubes: High Catalytic Activity in the Synthesis of Quinazolines[J]. Chem. Cat. Chem., 2017, 9: 1292–1297 Xu Y, Wang H, Zhu R J, et al. Conversion of CuO Nanoplates into Porous Hybrid Cu2O/Polypyrrole Nanoflakes through a Pyrrole-Induced Reductive Transformation Reaction[J]. Chem-Asian J, 2013, 8: 1120–1127 Xu H L, Wang W Z, Zhu W. Shape Evolution and Size-controllable Synthesis of Cu2O Octahedra and Their Morphology-dependent Photocatalytic Properties[J]. J. Phys. Chem. B, 2006, 110: 13829–13834 Lu C H, Qi L M, Yang J H, et al. One-pot Synthesis of Octahedral Cu2O Nanocages via a Catalytic Solution Route[J]. Adv. Mater., 2005, 17: 2562–2667 Zhang Z, Che H, Wang Y L, et al. Facile Synthesis of Mesoporous Cu2O Microspheres with Improved Catalytic Property for Dimethyldichlorosilane Synthesis[J]. IEC Research, 2012, 51, 1264–1274 Lei L W, Jin H H, Zhang Q, et al. A Novel Enhanced Visible-lightdriven Photocatalyst via Hybridization of Nanosized BiOCl and Graphitic C3N4[J]. Dalton T., 2015, 44: 795–803 Zeng H, Xie J, Xie H. Bioprocess-inspired Synthesis of Hierarchically Porous Nitrogen-doped TiO2 with High Visible-light Photocatalytic Activity[J]. J. Mater. Chem. A, 2015, 3: 19588–19596 Kumar S, Parlett C M A, Isaacs M A, et al. Facile Synthesis of Hierarchical Cu2O Nanocubes as Visible Light Photocatalysts[J]. Appl. Catal. B-Environ., 2016, 189: 226–232 Chen A, Qian J, Chen Y, et al. Enhanced Sunlight Photocatalytic Activity of Porous TiO2, Hierarchical Nanosheets Derived from Petal Template[J]. Powder Technology, 2013, 249: 71–76 Chen D S, Yu W B, Deng Z, et al. Hollow Cu2O Microspheres with Two Active {111 and {110 Facets for Highly Selective Adsorption and Photodegradation of Anionic Dye[J]. Rsc Adv., 2015, 5(68):55520–55526 Ai Z, Zhang L, Lee S, et al. Interfacial Hydrothermal Synthesis of Cu@Cu2O Core-Shell Microspheres with Enhanced Visible-Light-Driven Photocatalytic Activity[J]. J. Phys. Chem. C, 2009, 113: 20896–20902 Lee W J, Lee Y S, Rha S K, et al. Adhesion and Interface Chemical Reactions of Cu/polyimide and Cu/TiN by XPS[J]. Appl. Surf. Sci., 2003, 205: 128–136