Facile preparation of NiFe2O4/biochar composite adsorbent for efficient adsorption removal of antibiotics in water

Carbon Research - Tập 3 Số 1
Huagen Liang1, Chenxi Zhu1, Anhu Wang2, Fu Chen3
1Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization, Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, China
2School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, 221008, China
3School of Public Administration, Hohai University, Nanjing, 210098, China

Tóm tắt

AbstractThe removal of antibiotics by adsorption was considered to be a cheap and efficient treatment method. Herein, magnetic NiFe2O4/biochar (NFO/BC) composites were prepared by hydrothermal growth of nickel ferrite nanoparticles on sawdust derived biochar. It was found that NFO/BC composites had developed pore structure, rich oxygen-containing functional groups, and strong magnetism. The maximum adsorption capacity of the prepared magnetic composite for tetracycline (TC) was 420.41 mg g−1. The results of adsorption thermodynamics and adsorption kinetics showed that the adsorption process is a spontaneous process, which conforms to Langmuir model and pseudo second-order kinetic model. The influence experiment of pH and ionic strength confirmed that electrostatic interaction and hydrogen bonding are the key factors affecting the adsorption process. Additionally, pore filling and π-π interaction also existed in the adsorption process of tetracycline. This recyclable magnetic composite provides a feasible research idea for the efficient removal of antibiotics from water. Graphical Abstract

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